Process and In-Service Residual Stresses in Thermal Barrier Systems

Author(s):  
J. Wigren ◽  
L. Pejryd ◽  
B. Gudmundsson ◽  
R.T.R. McGrann ◽  
D.J. Greving ◽  
...  

Abstract Thermal barrier coatings are used in several industries to improve thermal efficiency, for example, of gas turbine engines. The performance and life of thermal barrier coated components depend on many factors. One important factor is the residual stresses in the coating and substrate. Residual stresses can be influenced by the parameters of the application process. Parameters affecting residual stresses include the condition of the substrate, the type of spray application process, and the prespray heat treatment of the substrate. Residual stresses can also change significantly during the life of a thermal barrier coated material. The goal of this work is to quantitatively evaluate the changes in residual stresses of the thermal barrier coating and the substrate during the stages of processing and during simulated in-service testing. Through-thickness residual stresses distributions of the coating and the substrate material were determined using a destructive laboratory method, called the "Modified Layer Removal Method." Thin thermal barrier coatings (less than 0.5 mm) were evaluated in this work. Residual stresses in thermal barrier coated specimens were evaluated at three stages of the processing history: (1) after grit blasting of the Hastelloy substrate, (2) after application of the bond coat, and (3) after spraying the top coat. The effect on residual stresses of substrate temperature during spraying is examined. Changes in the residual stresses for thin thermal barrier coatings are shown at selected stages during the processing history of the coated materials. Differences between residual stresses at the selected stages are identified and discussed. Changes to residual stress distribution due to in-service conditions are examined. The effect of bond coat oxidation is examined by long-term, high-temperature exposure. Also, residual stresses are evaluated for thick thermal barrier coatings after thermal shock testing.

1998 ◽  
Vol 65 (2) ◽  
pp. 346-353 ◽  
Author(s):  
S. Q. Nusier ◽  
G. M. Newaz

Thermal barrier coatings (TBCs) provide thermal insulation to high-temperature superalloys. Residual stresses develop in TBCs during cool-down from processing temperatures due to the thermal expansion mismatch between the different layers (substrate, bond coat, and the ceramic TBC). These residual stresses can initiate microcracks at the bond coat/TBC interface which can lead to debonding at the bond coat/TBC interface. Elasticity-based modeling was used to determine the transient stresses in the TBC, bond coat, and the superalloy substrate with specific attention to the interfaces. For the steady-state case, finite element modeling was undertaken as well. Closed-form elasticity solutions correlated well with the finite element results for the steady-state case. The highest residual stresses occurred at the interface between the bond coat and the TBC. An important result of this investigation was that the TBC/bond coat interface was under biaxial stress field. An important result was that the residual stresses developed in the substrate are higher for the case of partly cooled specimen compared to the fully cooled specimen which can be rationalized due to the presence of higher temperature gradients at earlier times during cool-down from processing temperature.


2010 ◽  
Vol 66 ◽  
pp. 74-79
Author(s):  
Jana Schloesser ◽  
Martin Bäker ◽  
Joachim Rösler ◽  
Robert Pulz

In rocket engine combustion chambers, the cooling channels experience extremely high temperatures and environmental attack. Thermal protection can be provided by Thermal Barrier Coatings. Due to the need of good heat conduction, the inner combustion liner is made of copper. The performance of a standard coating system for nickel based substrates is investigated on copper substrates. Thermal cycling experiments are performed on the coated samples. Due to temperature limitations of the copper substrate material, no thermally grown oxide forms at the interface of the thermal barrier coating and the bond coat. Delamination of the coatings occurs at the interface between the substrate and the bond coat due to oxide formation of the copper at uncoated edges. In real service a totally dense coating can probably not be assured which is the reason why this failure mode is of importance. Different parameters are used for thermal cycling to understand the underlying mechanisms of delamination. Furthermore, laser heating experiments account for the high thermal gradient in real service. Pilot tests which led to a delamination of the coating at the substrate interface were performed successfully.


2000 ◽  
Vol 645 ◽  
Author(s):  
Michael L. Glynn ◽  
K.T. Ramesh ◽  
P.K. Wright ◽  
K.J. Hemker

ABSTRACTThermal barrier coatings (TBCs) are known to spall as a result of the residual stresses that develop during thermal cycling. TBC's are multi-layered coatings comprised of a metallic bond coat, thermally grown oxide and the ceramic top coat, all on top of a Ni-base superalloy substrate. The development of residual stresses is related to the generation of thermal, elastic and plastic strains in each of the layers. The focus of the current study is the development of a finite element analysis (FEA) that will model the development of residual stresses in these layers. Both interfacial roughness and material parameters (e.g., modulus of elasticity, coefficient of thermal expansion and stress relaxation of the bond coat) play a significant role in the development of residual stresses. The FEA developed in this work incorporates both of these effects and will be used to study the consequence of interface roughness, as measured in SEM micrographs, and material properties, that are being measured in a parallel project, on the development of these stresses. In this paper, the effect of an idealized three-dimensional surface roughness is compared to residual stresses resulting from a grooved surface formed by revolving a sinusoidal wave about an axis of symmetry. It is shown that cylindrical and flat button models give similar results, while the 3-D model results in stresses that are significantly larger than the stresses predicted in 2-D.


Author(s):  
L. Pejyrd ◽  
J. Wigren ◽  
D.J. Greving ◽  
R.T.R. McGrann ◽  
J.R. Shadley ◽  
...  

Abstract Tungsten carbide cobalt thermal spray coatings are used in the aircraft industry to reduce wear damage of lightweight metals such as titanium The performance and life of tungsten carbide (WC-Co) coated titanium materials depend on many factors. An important factor that has received increased attention in thermal spray research is the residual stresses in the coating and substrate. Residual stresses depend on the parameters of the application process. Parameters affecting residual stresses include the prespray treatment of the substrate material (grit blasting, shot peening) and the type of spray application process (HVOF, plasma arc) During the in-service life of a WC-Co coated material, residual stresses can change significantly. The goal of this work is to quantitatively evaluate the changes in residual stresses of the substrate and the WC-Co coating during various stages of processing. A destructive laboratory method, called the "Modified Layer Removal Method," was used to evaluate the through-thickness residual stresses of the WC-Co coating and the titanium substrate material. Residual stresses are determined for three conditions: (1) shot peened, (2) shot peened and grit blasted, and (3) shot-peened, grit blasted and thermal spray coated. The changes in the residual stresses are shown at selected stages during the processing history of the coated materials. Differences between residual stress levels at selected stages are identified and discussed. The effect of coating thickness and HVOF application process on the residual stress in the coating is also examined.


2007 ◽  
Vol 14 (05) ◽  
pp. 935-943 ◽  
Author(s):  
L. YANG ◽  
Y. C. ZHOU ◽  
W. G. MAO ◽  
Q. X. LIU

In this paper, the impedance spectroscopy technique was employed to examine nondestructively the isothermal oxidation of air plasma sprayed (APS) thermal barrier coatings (TBCs) in air at 800°C. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also used to characterize the microstructure evolution of TBCs. After oxidation, the thermally grown oxide (TGO), which was mainly composed of alumina as confirmed by EDX, formed at the upper ceramic coat/bond coat interface, the lower bond coat/substrate interface, and the bond coat. Impedance diagrams obtained from impedance measurements at room temperature were analyzed according to the equivalent circuit model proposed for the TBCs. Various observed electrical responses relating to the growth of oxides and the sintering of YSZ were explained by simulating the impedance spectra of the TBCs.


Metals ◽  
2014 ◽  
Vol 4 (4) ◽  
pp. 503-518 ◽  
Author(s):  
Torben Fiedler ◽  
Tatiana Fedorova ◽  
Joachim Rösler ◽  
Martin Bäker

2008 ◽  
Vol 203 (1-2) ◽  
pp. 160-170 ◽  
Author(s):  
U. Schulz ◽  
O. Bernardi ◽  
A. Ebach-Stahl ◽  
R. Vassen ◽  
D. Sebold

2021 ◽  
Vol 320 ◽  
pp. 31-36
Author(s):  
Marek Góral ◽  
Tadeusz Kubaszek ◽  
Barbara Kościelniak ◽  
Marcin Drajewicz ◽  
Mateusz Gajewski

Thermal barrier coatings are widely used for protection of gas turbine parts against high temperature oxidation and hot corrosion. In present work the microstructural assessment of TBCs produced by atmospheric plasma spray (APS) method was conducted. Three types of ceramic powders were used: magnesia- stabilized zirconia oxide (Metco 210), yttria stabilized zirconia oxide (YSZ -Metco 204) and fine-grained YSZ – Metco 6700. As a base material the Inconel 713 was used as well and CoNiCrAlY was plasma sprayed (APS) as a bond coat. The thickness of all ceramic layers was in range 80 – 110 μm. The elemental mapping of cross-section of magnesia-stabilized zirconia showed the presence of Mg, Zr and O in outer layer. In the YSZ ceramic layer the Y, Zr and O were observed during elemental mapping. The isothermal oxidation test was conducted at 1100 °C for 500 h in static laboratory air. On all samples the delamination and spallation of ceramic layers was observed. Chemical composition analysis of coatings showed the presence of two areas: the first one contained elements from bond coats: Ni, Cr, Al, Co and second area contained O, Cr Co and O that suggest the scale formation. The obtained results showed the total degradation of all ceramic layers as a result of internal stresses in bond-coat. Microscopic analysis showed the areas with complete degradation of bond coats and formation of thick oxides layer.


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