Lowering the Carbon Footprint of Concrete by Reducing Clinker Content of Cement

2012 ◽  
Vol 2290 (1) ◽  
pp. 99-104 ◽  
Author(s):  
Michael Thomas ◽  
Laurent Barcelo ◽  
Bruce Blair ◽  
Kevin Cail ◽  
Anik Delagrave ◽  
...  

Significant efforts have been made to reduce carbon dioxide (CO2) emissions associated with the manufacture of portland cement, primarily by making the process more energy efficient and increasing the use of alternative fuels. Further reductions in CO2 can be achieved by lowering the clinker component of the cement because the pyroprocessing used to manufacture clinker produces approximately 1 tonne of CO2 for every tonne of clinker. Traditionally reductions in the clinker content of cement have been achieved by producing blended cement consisting of portland cement combined with a supplementary cementing material (SCM). In Canada, it is now permitted to intergrind up to 15% limestone with cement clinker to produce portland limestone cement or blended portland limestone cement. Recent trials were conducted at the Brookfield cement plant in Nova Scotia to evaluate the performance of a blended cement containing 15% ground, granulated blast furnace slag (an SCM) with that of a blended portland limestone cement containing the same amount of slag plus 12% interground limestone. Performance was evaluated by the construction of a section of concrete pavement using concrete mixtures produced with the two cements and various amounts of fly ash (another SCM). A wide range of laboratory tests were performed on the concrete specimens cast on site during the placement of the concrete pavement. The results indicated that the cements were of equivalent performance.

1986 ◽  
Vol 86 ◽  
Author(s):  
Micheline Regourd

ABSTRACTThe hydration of a blended cement through hydraulic or pozzolanic reactions results in heterogeneous polyphase materials. Because portland cement clinker is the major component in most cement blends, the microstructural development of portland cement hydrates, including C-S-H and pore structures, is first discussed. Slag, fly ash, silica fume and limestone filler cements are then compared to portland cement with regards to C-S-H morphology and composition, aluminate crystallization, cement paste interfaces and pore size distribution.


2015 ◽  
Vol 2015 ◽  
pp. 1-5 ◽  
Author(s):  
Mark Bediako ◽  
Eric Opoku Amankwah

The performance of Portland cement in concrete or mortar formation is very well influenced by chemical compositions among other factors. Many engineers usually have little information on the chemical compositions of cement in making decisions for the choice of commercially available Portland cement in Ghana. This work analyzed five different brands of Portland cement in Ghana, namely, Ghacem ordinary Portland cement (OPC) and Portland limestone cement (PLC), CSIR-BRRI Pozzomix, Dangote OPC, and Diamond PLC. The chemical compositions were analyzed with X-Ray Fluorescence (XRF) spectrometer. Student’st-test was used to test the significance of the variation in chemical composition between standard literature values and each of the commercial cement brands. Analysis of variance (ANOVA) was also used to establish the extent of variations between chemical compositions and brand name of the all commercial Portland cement brands. Student’st-test results showed that there were no significant differences between standard chemical composition values and that of commercial Portland cement. The ANOVA results also indicated that each brand of commercial Portland cement varies in terms of chemical composition; however, the specific brands of cement had no significant differences. The study recommended that using any brand of cement in Ghana was good for any construction works be it concrete or mortar formation.


2020 ◽  
Vol 13 (6) ◽  
pp. 679-685
Author(s):  
Hung-Wen Chung ◽  
Thanachart Subgranon ◽  
Mang Tia

AbstractA high cementitious paste volume (CPV) can increase the early cracking tendency of the concrete and reduce the durability of concrete pavement. This study investigated the effects of minimized CPV in slipformed pavement concrete (SPC) with blended aggregates (BA). Based on the laboratory results, the performance of pavement concrete with different CPV was evaluated. The CPV of standard SPC can be reduced to 25.0% without affecting its properties as evaluated by compressive strength, drying shrinkage and surface resistivity tests However, the CPV of SPC with optimized aggregate gradation (OAG) using BA technique can be further reduced to 22.5% with satisfactory properties. The SPC mixes with OAG was noted to have better potential performance as a pavement concrete. SPC concrete using Portland limestone cement can give similar properties as those of the conventional concrete using ordinary Portland cement.


2010 ◽  
Vol 33 (1) ◽  
pp. 1-8
Author(s):  
Alex Lyatonga Mrema

A study was made in a cement factory in Dar es Salaam, Tanzania, where OrdinaryPortland Cement (CEM I 42.5N) and Portland-limestone cement (PLC) which has thebrand name Twiga Cement Extra (CEM II/A-L/32.5R) are produced and conforming to theTanzania Standard TZS 727 (Part1): 2002, which is equivalent to EN 197 published by thecommittee for European normalization (CEN). A comparison was made between the twotypes of cements in terms of physical, chemical and mechanical properties. It was foundout that they all complied with the standards, that there was no significant difference intheir setting times and that the Portland cement had higher strengths than the PLC. It was also observed that there was a slightly lower water demand for the same consistency when compared to OPC and hence there is an improvement of the cohesiveness of a concrete mix when PLC is used. It was concluded, however, that the two cements are different and that using the two cements interchangeably as is done in Tanzania is wrong because they donot have equivalent strengths and therefore equivalent performance since the PLC is not ptimized. Portland-limestone cement (PLC) is known to offer significant energy savings and green house gas (GHG) reduction (up to 10% GHG savings) over conventional Portland cement while at the same time providing comparable performance if optimized.


2020 ◽  
Vol 857 ◽  
pp. 83-88
Author(s):  
Ikram F. Ahmed Al-Mulla ◽  
Ammar S. Al-Rihimy ◽  
Mushriq F. Al-Shamaa

From the sustainability point of view a combination of using water absorption polymer balls in concrete mix produce from Portland limestone cement (IL) is worth to be perceived. Compressive strength and drying shrinkage behavior for the mixes of concrete prepared by Ordinary Portland Cement (O.P.C) and Portland limestone cement (IL) were investigated in this research. Water absorbent polymer balls (WAPB) are innovative module in producing building materials due to the internal curing which eliminates autogenous shrinkage, enhances the strength at early age, improve the durability, give higher compressive strength at early age, and reduce the effect of insufficient external curing. Polymer balls (WAPB) had been used in the mixes of this research to provide good progress in compressive strength with time. Water absorption polymer balls have the ability to absorb water and after usage in concrete it will spill it out and shrink leaving voids of their own diameter before shrinking that lead to provide internal curing. The required quantity of water for the mixes were reduced due to the addition of water from the absorption polymers. Mixes produced from Portland limestone cement in this research show drying shrinkage results and compressive strength results lower than mixes made from ordinary Portland cement.


2011 ◽  
Vol 261-263 ◽  
pp. 431-435
Author(s):  
Jia Chun Wang

The hydration of slag in Portland cement is studied by considering the interaction between the hydrations of slag and Portland cement clinker. The slag hydration heat value that the different dosage of slag is in Portland cement is measured with isothermal calorimetry method as quartz sand sample contrast. The kinetic analysis was used to obtain parameters, which were employed to find out the influence of the slag content on the reaction rate constant value. The reaction stages have been analyzed and explained in accordance with kinetic models. The model predictions show that as the slag proportions in the blended cement changes, water retention in the hydration products changes only slightly if compared to that of Portland cement, The investigations have shown that the addition of silica fume of more than 30 mass% reduces the duration of the phase boundary interaction as a rate-determined process resulting in the fast diffusion rate-determining process. The results of this study have also revealed evidence of the accelerator effect of slag during the first 24 h of hydration when it still exists as chemically inert filler.


2011 ◽  
Vol 343-344 ◽  
pp. 322-326 ◽  
Author(s):  
Pailyn Thongsanitgarn ◽  
Watcharapong Wongkeo ◽  
Sakprayut Sinthupinyo ◽  
Arnon Chaipanich

In this study limestone powders with different particle sizes of 5, 10 and 20 μm were used to replace a part of Portland cement in different replacement levels to produce Portland-limestone cement pastes. The percentages of limestone replacement are 0, 5, 7.5, 10, 12.5, 15 and 20% by weight. The effect of fineness and the amount of limestone powders on compressive strength and setting time are investigated. It has been established that limestone replacement causes reduce the compressive strength due to the dilution effect, but it can reduce energy consumption and CO2 emission in cement manufacturing. The fineness of limestone powder used has influence on the observed compressive strength values. From the standard consistency results, it seems that limestone has no effect on water requirement compared to Portland cement. Moreover, the increase in level of fine particles would require much water. Both initial and final setting times were decreased with an increase in the amount of limestone. Furthermore, at the same level replacement, the cement pastes using 5 μm of limestone show lower setting time than those using 10 and 20 μm, respectively.


1986 ◽  
Vol 85 ◽  
Author(s):  
Micheline Regourd

ABSTRACTThe hydration of a blended cement through hydraulic or pozzolanic reactions results in heterogeneous polyphase materials. Because portland cement clinker is the major component in most cement blends, the microstructural development of portland cement hydrates, including C-S-H and pore structures, is first discussed. Slag, fly ash, silica fume and limestone filler cements are then compared to portland cement with regards to C-S-H morphology and composition, aluminate crystallization, cement paste interfaces and pore size distribution.


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