scholarly journals Fifty years of progress in ice physics

1987 ◽  
Vol 33 (S1) ◽  
pp. 52-59
Author(s):  
John W. Glen

AbstractOur understanding of the basic physics underlying the properties of ice has dramatically changed during the last half century. At the beginning of this period it was known that the water molecules in ice were arranged with tetrahedral hydrogen bonding, and it had just been established that the hydrogens were not crystallographically arranged on these bonds; however, the way in which water molecules could re-orient was unknown and the implications of this for the mechanical properties and hence for glacier flow were unexplored. The suggestion of electrical point defects in ice, the L and D defects of Bjerrum and the ionic defects, pointed the way to an understanding first of the dielectric relaxation and electrical conductivity of ice and then to a possible interaction between these electrical properties and the movement of dislocations, and hence the plastic deformation of ice.Menwhile, much work was done to study the behaviour of ice under various physical conditions and to establish more rigorous laws for many physical properties of single crystals of ice and of various forms of polycrystalline ice, and much work was done to find the crystallographic structures of the various phases of ice including those already known to exist at high pressures. The intriguing appearance of a cubic form of ice at low temperatures was also investigated together with vitreous ice formed at even lower temperatures.Many of these properties are of great interest to meteorologists trying to understand cloud physics and the physics of thunderstorm electricity as well as to astronomers thinking about ice in space, comets, the icy satellites of the planets, or even on the planets themselves.

2009 ◽  
Vol 23 (30) ◽  
pp. 5705-5714
Author(s):  
VOJKAN M. ZORIĆ ◽  
VJEKOSLAV SAJFERT ◽  
LJILJANA MAŠKOVIĆ ◽  
JELENA ZORIĆ

In this work the mechanism of resonance is proposed as the way for determining of wall paint age. The method consists in accelerated growing old of wall paint on the basis of resonance. Measuring is concerned with the humidity of wall paint and it is a general method since water molecules are present in every material. Besides, the water molecules are dipoles so that the resonance with them can be achieved by the mechanical as well as the electrical way.


2016 ◽  
Vol 8 (1) ◽  
pp. 197-214 ◽  
Author(s):  
Stefan Schwarzkopf

Purpose – This paper aims to chart the influence of McCarthyism and of FBI surveillance practices on a number of prominent American social scientists, market researchers, opinion pollsters and survey research practitioners during the post-war years. Hitherto disparate sets of historical evidence on how Red Scare tactics influenced social researchers and marketing scientists are brought together and updated with evidence from original archival research. Design/methodology/approach – The paper draws on the existing secondary literature on how social research practitioners and social scientists reacted to the unusually high pressures on academic freedom during the McCarthy era. It supplements this review with evidence obtained from archival research, including declassified FBI files. The focus of this paper is set on prominent individuals, mainly Bernard Berelson, Samuel Stouffer, Hadley Cantril, Robert S. Lynd, Paul F. Lazarsfeld, Herta Herzog, Ernest Dichter, but also the Frankfurt School in exile. Findings – Although some of the historiography presents American social scientists and practitioners in the marketing research sector as victims of McCarthyism and FBI surveillance, it can also be shown that virtually all individuals in focus here also developed strategies of accommodation, compromise and even opportunism to benefit from the climate of suspicion brought about by the prevailing anti-Communism. Social implications – Anyone interested in questions about the morality of marketing, market research and opinion polling as part of the social sciences practiced in vivo will need to pay attention to the way these social-scientific practices became tarnished by the way prominent researchers accommodated and at times even abetted McCarthyism. Originality/value – Against the view of social scientists as harassed academic minority, evidence is presented in this paper which shows American social scientists who researched market-related phenomena, like media, voters choices and consumer behaviour, in a different light. Most importantly, this paper for the first time presents archival evidence on the scale of Paul F. Lazarsfeld’s surveillance by the FBI.


Author(s):  
H. I. Drever ◽  
R. Johnston

SynopsisOne of the writers' main aims has been to help to prepare the way for a new approach to problems in which the natural occurrence of forsteritic olivines is a vital factor. Variation in their shapes and textural relations in minor intrusions, lavas and melts is examined and the historical development of concepts of their growth and resorption, particularly in magmas, is traced. Particular attention is focused on the olivines of picritic, minor intrusions. It is concluded that in the interpretation of olivine shapes there has been discrimination in favour of magmatic resorption rather than skeletal crystallization. From a wide and detailed survey of forsteritic olivines it is established that they tend to grow rapidly and that their phenomenal variation in habit and shape is probably due to a specific growth sensitivity to slight environmental differences. Concepts of the physical conditions leading to skeletal crystallization are briefly reviewed and discussed.


1972 ◽  
Vol 50 (17) ◽  
pp. 2739-2746 ◽  
Author(s):  
W. E. Jones ◽  
L. R. Carey ◽  
T. W. Swaddle

The logarithm of the pseudo-first-order rate coefficient k for the aquation of Co(NH3)5X(3–n)+ can be represented by a quadratic equation in the pressure P, or, better, by[Formula: see text]where P is in kbar, [Formula: see text] is the volume of activation at P = 0, and x is the increase in the number of water molecules solvating the complex as it goes to the transition state. For [Formula: see text]Cl−, Br−,[Formula: see text] and [Formula: see text] at 25° [Formula: see text] and ionic strength I = 0.1 M LiClO4/HClO4, [Formula: see text] −10.6, −9.2, −6.3, and +16.8 cm3 mol−1, and x = 8.0, 4.1, 3.9, 1.9, and −4.2; for Xn− = NCS−, the mean ΔV* from P = 0.001 to 2.5 kbar at 88° is −4 cm3 mol−1. Detailed consideration of these data, especially their correlation with the molar volume of reaction by a straight line of unit slope for [Formula: see text] Cl−, Br−, NO3−, and H2O, provides strong evidence for a dissociative interchange mechanism. For [Formula: see text] the separating entity is probably HN3 rather than [Formula: see text] For Xn− = NCS−, aquation is incomplete, at practical complex concentrations; at 88.0°, 1 bar, and I = 0.1 M LiClO4/HClO4, k = 3.3 × 10−6 s−1 and the stability constant of Co(NH3)5NCS2+ is 490 M−1.


1958 ◽  
Vol 63 (2) ◽  
pp. 289-315 ◽  
Author(s):  
H. I. Drever ◽  
R. Johnston

SynopsisOne of the writers' main aims has been to help to prepare the way for a new approach to problems in which the natural occurrence of forsteritic olivines is a vital factor. Variation in their shapes and textural relations in minor intrusions, lavas and melts is examined and the historical development of concepts of their growth and resorption, particularly in magmas, is traced. Particular attention is focused on the olivines of picritic, minor intrusions. It is concluded that in the interpretation of olivine shapes there has been discrimination in favour of magmatic resorption rather than skeletal crystallization. From a wide and detailed survey of forsteritic olivines it is established that they tend to grow rapidly and that their phenomenal variation in habit and shape is probably due to a specific growth sensitivity to slight environmental differences. Concepts of the physical conditions leading to skeletal crystallization are briefly reviewed and discussed.


It has long been known that for mixtures of any particular combustible gas and air (or oxygen) there are, under given physical conditions, certain limits of composition within (but not outside of) which self-propagation of flame will occur indefinitely after ignition has once been effected. These limits, usually referred to as the “lower” and “upper” limits of inflammability, respectively, at given temperature and pressure vary somewhat (i) with the position of the source of ignition, since the progress of the flame may be assisted or retarded by convection currents according as it has to pass in an upward, horizontal, or downward direction, and (ii) according to the size and material of the containing vessel. It has also been established during recent years that what may be termed the “range of inflammability” of mixtures of any particular gas and air (oxygen) is widened when the temperature is raised. Thus, for example, according to H. G. White, the “ranges of inflammability” for downward propagation of flame at atmospheric pressure of gas-air mixtures steadily widen with increasing temperature,* e. g . :—


Author(s):  
Viktor Stefov ◽  
Violeta Koleva ◽  
Metodija Najdoski ◽  
Adnan Cahil ◽  
Zuldjevat Abdija

Fourier transform infrared (FT-IR) spectra recorded at room temperature (RT) and at the boiling temperature of liquid nitrogen (LNT), as well as Raman spectra recorded at room temperature for the cubic polymorph of magnesium cesium arsenate hexahydrate (MgCsAsO4·6H2O) and its partially deuterated analogues, were interpreted with respect to the normal modes of the water molecules and the arsenate ions and water librations. The spectral characteristics of MgCsAsO4·6H2O were compared to the cubic form of the phosphate analogue. A spectral similarity between the two isostructural salts was established, except for the obvious differences due to the nature of the anions (AsO43– vs PO43–). The spectroscopic data for the uncoupled OD stretching mode of the matrix-isolated HDO molecules revealed that the hydrogen bonds formed in the arsenate salt were stronger than those in the phosphate. In the Raman spectrum of the protiated compound, only one very intensive band at 811 cm–1 was observed in the region of the stretching vibrations of the AsO43– ion, which was insensitive to deuteration. In accordance with the expectation, one band appeared in the same spectral range in the infrared spectra of the protiated and highly deuterated sample at 792 cm–1 and 810 cm–1, respectively, which can be attributed with certainty to the asymmetric stretching ν3(AsO4) modes.


1965 ◽  
Vol 55 (3) ◽  
pp. 619-625
Author(s):  
L. Don Leet ◽  
Florence J. Leet

Abstract It has been generally accepted for some time that the earth's mantle is “solid” (crystalline). But increasing complications arise as attempts are made to rationalize that state of matter with the growing list of properties of the mantle. We suggest that materials of the earth's mantle are in a fourth state of matter, which we propose calling soliqueous—a combination of solid, liquid, and gaseous. It includes elements for forming water molecules and allows expanding superheated steam to supply the principal force for elevating and distorting land masses. Bridgman's experiments on plastic deformation of materials at very high pressures revealed that spasmodic jerky yielding is characteristic. We propose plastic rupture in shear as the primary mechanism by which energy in the earth is converted to the vibrations of earthquakes.


2018 ◽  
Vol 123 (2) ◽  
pp. 324-348 ◽  
Author(s):  
S. H. Doyle ◽  
B. Hubbard ◽  
P. Christoffersen ◽  
T. J. Young ◽  
C. Hofstede ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document