scholarly journals Magnetite nanoparticles for reduction of hexavalent chrome in soil of an industrial park, Cerro Colorado - Arequipa [Nanopartículas de magnetita para reducción de cromo hexavalente en suelo de un parque industrial, Cerro Colorado – Arequipa]

2019 ◽  
Vol 3 (1) ◽  
pp. 12
Author(s):  
Mardelly Ruiz Marcelo ◽  
Cecilia Cermeño Castromonte ◽  
Elmer Benites Alfaro

One of the most important contamination problems in receiving bodies due to industrial activities is the presence of chromium (VI). One way to reduce the aggressiveness of said contaminant is its reduction to the form of chromium (III). The investigation determined the efficiency of magnetite nanoparticles in the treatment of soil contaminating with chromium (VI), to reduce it to chromium (III) of an Industrial Park at the district Cerro Colorado, province and department of Arequipa.22 samples of 1 kg of soil were taken, then homogenized according to the extraction distances, considering at the end only 3 samples called “Shore”, “6 Meters” and “9 Meters”, whose concentrations were: 146 mg / kg, 126 mg / kg and 67 mg / kg of Cr (VI) respectively. These samples were subjected to 3 treatments (T1, T2 and T3) with 3 repetitions each using 15, 30 and 45 grams doses of Magnetite nanoparticles for three weeks. At the end of the treatment using the EPA 3060 method, the Chrome (VI) analysis was performed. The 3 treatments “T1”, “T2” and “T3”, had significant differences for the final concentrations of Hexavalent Chromium in the soil; but it was in Treatment 3 in the soil samples "Shore", "6 Meters" and "9 Meters", where a greater effect was achieved in the reduction of Cr (VI) to Chromium (III) with an efficiency of 99.96%, 99.93% and 99.93% respectively, 45 grams of magnetite nanoparticles were used for this treatment.

2009 ◽  
Vol 9 (6) ◽  
pp. 661-670 ◽  
Author(s):  
S. P. Dubey ◽  
K. Gopal

The activated carbon of Eucalyptus globulus was tested for their effectiveness in removing hexavalent chromium from aqueous solution using column experiments. Result revealed that adsorption of chromium(VI) on eucalyptus bark carbon was endothermic in nature. Thermodynamic parameters such as the entropy change, enthalpy change and Gibbs free energy change were found to be 1.39 kJ mol−1 K−1, 1.08 kJ mol−1 and −3.85 kJ mol−1, respectively. Different chromium concentrations were used for the fixed bed adsorption studies. The pre- and post-treated adsorbents were characterized using a FTIR spectroscopic technique. It was concluded that Eucalyptus bark carbon column could be used effectively for removal of hexavalent chromium from aqueous solution at optimal column conditions. This study showed that this biological material is potential adsorbent of Cr(VI) from water.


Author(s):  
Ismael Acosta-Rodriguez ◽  
Juan F. Cardenas-González ◽  
María de Guadalupe Moctezuma-Zárate ◽  
Adriana Rodriguez Perez ◽  
Victor M. Martínez-Juárez

2017 ◽  
Vol 13 (10) ◽  
pp. 5886-5891
Author(s):  
Padmalaya G ◽  
Sreeja BS ◽  
Radha S ◽  
Raamdheep G ◽  
Saranya J

Groundwater contamination with heavy metals is considered as serious environmental hazard that affect the human society. Nano adsorbents incorporating magnetite nanoparticles provides promising alternative to facilitate removal of heavy metal ions from wastewater. The present work focuses on removal of chromium (VI) cationic metals from aqueous media using Polyvinyl Pyrrolidone (PVP)/Magnetite (Fe3O4) Nanocomposite (MNC). Magnetite nanoparticles are synthesized using chemical co-precipitation and grafted using polyvinyl pyrrolidone to form a magnetite nanocomposite. MNC were characterized with X-ray diffraction (XRD) and Infrared absorption spectrum (FT-IR) studies to affirm the formation and presence of polymeric functional groups of PVP/Magnetite nanocomposite. Batch experiments are carried out at exclusive concentration intervals to study about the adsorption efficiency of MNC on chromium (VI) cationic metal using U-Vis spectroscopy. The results obtained through adsorption studies shows the synthesized PVP/Magnetite nanocomposites has a removal efficiency of 94%.


2021 ◽  
Vol 8 (1) ◽  
pp. 33-41
Author(s):  
Theodorus Olwyn Innation ◽  
Vincentia Irene Meitiniarti ◽  
Desti Christian Cahyaningrum

Reduksi Cr(VI) pada Tanah Menggunakan Microbacterium sp. Strain SpR3 dengan Bahan Pembawa Vermikompos Kromium hexavalen [Cr(VI)] adalah polutan yang berasal dari kegiatan industri. Microbacterium sp. strain SpR3 dapat digunakan sebagai agen bioremediasi Cr(VI). Kemampuan agen biologi untuk mereduksi Cr(VI) umumnya meningkat bila diinokulasi dalam media pembawa. Tujuan penelitian ini adalah untuk menganalisis kemampuan Microbacterium sp. strain SpR3 dalam mengurangi Cr(VI) serta membandingkannya dengan kondisi ketika diinokulasi dalam media pembawa vermikompos. Pengamatan dilakukan selama tujuh hari pada tiga perlakuan yang berbeda, yakni Microbacterium sp. strain SpR3 dengan dan tanpa media pembawa vermikompos yang diinokulasi pada tanah steril yang mengandung 50 ppm Cr(VI), dan tanah steril tanpa inokulasi bakteri yang mengandung 50 ppm Cr(VI). Variabel yang diamati adalah jumlah bakteri, konsentrasi, dan kecepatan reduksi Cr(VI) oleh bakteri tersebut di dalam tanah pada T0 (hari ke-0) dan T7 (hari ke-7). Hasil penelitian ini menyimpulkan bahwa vermikompos bisa digunakan sebagai media pembawa Microbacterium sp. strain SpR3 karena dapat meningkatkan jumlah bakteri sampai 2 × 1010 CFU g-1 di dalam tanah dan dapat mengurangi Cr(VI) dengan kecepatan 0,095 mg L-1 jam-1. Hexavalent chromium [Cr(VI)] is a pollutant originated from industrial activities. Microbacterium sp. strain SpR3 can be used as Cr(VI) bioremediation agent. The ability of bioagent to reduce Cr(VI) usually improves when inoculated in a carrier. This research aimed to assess the ability of Microbacterium sp. strain SpR3 to reduce Cr(VI) in soil and compare its ability when inoculated in vermicompost carrier. Observations were carried out for seven days on three different treatments, namely Microbacterium sp. strain SpR3 with and without vermicompost inoculated in sterile soils containing 50 ppm Cr(VI), and sterile soils containing 50 ppm Cr(VI) without bacterial inoculation. The observed variables were the number of bacteria, the concentration of Cr(VI) and the rate of Cr(VI) reduction by these bacteria in the soil at T0 (day 0) and T7 (day 7). It was concluded that vermicompost could be used as a carrier of Microbacterium sp. strain SpR3 as it could increase the number of the bacteria to 2 × 1010 CFU g-1 in soil and could reduce Cr(VI) at the rate of 0.095 mg L-1 h-1.


2016 ◽  
Vol 721 ◽  
pp. 143-148 ◽  
Author(s):  
Nora Noureddine ◽  
Samia Benhammadi ◽  
Fouad Kara ◽  
Hakim Aguedal ◽  
Abdelkader Iddou ◽  
...  

A bacterial strain Pseudomonas aeruginosa isolated from an uncontaminated soil has been used for the removal of hexavalent chromium (Cr (VI)). The experiments were carried out in batch system in a culture broth. The results obtained have shown that 100% of Cr (VI) are removed. Contact time, initial concentration of the hexavalent chromium, temperature, as well as the nature of the culture broth have influenced this elimination. To the initial concentration of 20g/L of Cr (VI) the elimination rates are lower, while the reverse occurs for an initial concentration of 8g/L. This study allows considering the use of Pseudomonas aeruginosa in the treatment of water polluted by toxic heavy metals such as Cr (VI).


2012 ◽  
Vol 430-432 ◽  
pp. 1253-1256 ◽  
Author(s):  
Yu Jie Huang ◽  
Huan Zhen Zhang

In order to improve the removal ability of hexavalent chromium on the synthetic zeolite, the synthetic zeolite was modified by FeSO4, which was used to removal hexavalent chromium in groundwater. The results showed that the concentration of Cr (VI) can be reduced from 5.0mg/l to 0.03 mg/l, which meets the requirements of groundwater standards (0.05mg/l) by using modified zeolite in a liquid-to-solid ratio of 20 ml/g, pH=3 for 120 minutes. The adsorption of Cr (VI) on the modified synthetic zeolite could be described by the Langmuir and Freundlich adsorption isotherm. It is showed that the synthetic zeolite modified by FeSO4 has good treatment effect and after treatment the pH of groundwater can reach around 6.8, which need no more pH adjustment.


Author(s):  
Soumyajit Guha ◽  
Sampa Debnath ◽  
Saswati Gayen

The main objective of this study was to isolate, characterize, and determine chromium (VI) tolerance capacities of fungal strains from tannery effluent of the Kolkata Leather Complex area. Chromium (VI) is a heavy metal that is known to be toxic as well as carcinogenic. It is an important heavy metal widely used in various industries of which the tanning industry deserves special mention. The majority of Cr (VI) waste is discharged into the environment annually as a consequence of industrial and manufacturing activities. Kolkata Leather Complex is an industrial complex intended to serve as a central leather-tanning complex for Kolkata located at Bantala, near East Kolkata, India. Samples (tannery effluent) were collected in sterile capped tubes from Kolkata Leather Complex Area and brought to the laboratory for analysis. The samples were serially diluted and were plated on Czapekdox agar plates and incubated at 300C. After a few days, a number of morphologically different colonies were selected and sequentially subcultured for pure colony isolation on the same medium. They were preserved in the refrigerator at 40 C. Lactophenol cotton blue staining was done to observe and record the fungal morphological characteristics. They were further assessed for their hexavalent chromium tolerance capacities and subsequently the metal tolerance index was derived for each strain respectively. All 16 fungal strains isolated from the Kolkata Leather Complex tannery area were found to be chromium (VI) tolerant starting at 0.1mg/ml Cr (VI) concentration. Maximum chromium (VI) tolerance was displayed by sample S12 (2mg/ml) which was later identified as having 99.82% similarity with Aspergillus nomius strain.Keywords: effluent, fungi, heavy metal, isolation, hexavalent chromium, tannery, tolerance.


2020 ◽  
Vol 4 (2) ◽  
pp. 33
Author(s):  
Hans Portilla ◽  
Aldo Castillo ◽  
César Arévalo ◽  
Fabio Cabrera ◽  
Juan Vega ◽  
...  

The present research evaluated treatment time, electrode area / effluent volume ratio, on the% reduction of hexavalent chromium in artificial chrome plating effluents, was evaluated by the batch electrocoagulation method; Method for which A-36 steel anodes and cathodes of (5.0 x 5.0 x 0.2) cm were used. The number of electrodes and the separation between them was varied in order to vary the ratio of electrode area / effluent volume and; for a batch type electrocoagulation reactor in which 27 tests were carried out; keeping the volume of effluent treated constant. From the results obtained, it was determined that the increase in the electrocoagulation time and the electrode area / effluent volume ratio influence the percentage of hexavalent chromium reduction of the artificial chromium plating, as supported by ANOVA and test F; the maximum reduction percentage achieved was 91.65%, with respect to the initial concentration (20 mg/L), for a test time of 60 minutes and a ratio of electrode area / effluent volume of 0.912 m2/L.


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