Assessment on Performance-properties of Asymmetric Nanofiltration Membranes from Polyethersulfone/n-Methyl-2-pyrrolidone/water Blends with Poly(vinyl pyrrolidone) as Additive

Author(s):  
Sabariah Rozali ◽  
Nurul Hannan Mohd Safari ◽  
Abdul Rahman Hassan ◽  
Musa Ahmad ◽  
Rosli Mohd Yunus

In this study, the effect of poly(vinyl pyrrolidone) (PVP) additive on the fabrication of asymmetric nanofiltration (NF) membranes was investigated in terms of performance, structural details and key properties. On addition of PVP ranging from 2 to 10 wt% into the dope solution, the fabricated NF membranes exhibited significantly different in properties and improved performance. In particular, the membranes made from 2 wt% PVP had the highest water flux and salt rejection of about 3.61 × 10–6 m3/m2s and 44.49 %, respectively. Modeling results revealed that small amount of PVP (2–4 wt%) produced finer structural properties. Moreover, the key properties (rp, ∆x/Ak and ζ) of the fabricated NF membranes were found to be within the range of that of commercial NF membranes.

Desalination ◽  
2018 ◽  
Vol 429 ◽  
pp. 119-133 ◽  
Author(s):  
Anisha Anand ◽  
Binesh Unnikrishnan ◽  
Ju-Yi Mao ◽  
Han-Jia Lin ◽  
Chih-Ching Huang

RSC Advances ◽  
2014 ◽  
Vol 4 (99) ◽  
pp. 55773-55780 ◽  
Author(s):  
Raghavendra S. Hebbar ◽  
Arun M. Isloor ◽  
A. F. Ismail

Polyetherimide/hydrolysed PIAM blend NF membranes have been prepared and characterized. The PEI/hydrolysed PIAM composition of 80 : 20 showed very good salt rejection (sodium sulphate) up to 76% with a pure water flux of 11.8 L m−2 h−1. This study provides a simple and effective approach to produce negatively charged NF membranes for water desalination applications with low energy consumption.


RSC Advances ◽  
2017 ◽  
Vol 7 (86) ◽  
pp. 54898-54910 ◽  
Author(s):  
Quanling Xie ◽  
Wenyao Shao ◽  
Shishen Zhang ◽  
Zhuan Hong ◽  
Qiuquan Wang ◽  
...  

In this work, novel thin-film nanocompostie NF membranes were developed through modification with maleic anhydride functionalized graphene oxideviainterfacial polymerization, which showed the enhanced water flux with retaining high salt rejection.


Membranes ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 6 ◽  
Author(s):  
Shouhai Zhang ◽  
Shanshan Guan ◽  
Chengde Liu ◽  
Zhenlin Wang ◽  
Danhui Wang ◽  
...  

This paper discusses the effect of the chemical structure of sulfonated poly(aryl ether sulfone) on the performance of composite nanofiltration membranes. The composite nanofiltration membranes were fabricated by coating sulfonated poly(aryl ether sulfone) solution onto the top surface of poly(phthalazinone ether sulfone ketone) support membranes. Three kinds of sulfonated poly(aryl ether sulfone)s with different amounts of phthalazinone moieties, namely, sulfonated poly(phthalazinone ether sulfone) (SPPES), sulfonated poly(phthalazinone biphenyl ether sulfone) (SPPBES), and sulfonated poly(phthalazinone hydroquinone ether sulfone)s (SPPHES), were used as coating materials. The solvents used in preparing the coating solution were investigated and optimized. The separation properties, thermal stability, and chlorine resistance of composite membranes were determined. The structures and morphologies of membranes were characterized with FTIR and SEM, respectively. The membrane prepared from SPPES with more phthalazinone moiety groups showed high water flux and salt rejection. The salt rejection of composite membranes followed the order SPPES > SPPHES > SPPBES. The rejection of the three composite membranes decreased slightly with the solution temperature rising from 20 to 90 °C, while the composite membrane with SPPES as the active layer showed a higher increase in flux than others. The results indicate that SPPES composite membranes show better thermal stability than others.


RSC Advances ◽  
2016 ◽  
Vol 6 (108) ◽  
pp. 106237-106247 ◽  
Author(s):  
Gongwen Zou ◽  
Wei Wu ◽  
Chuanbo Cong ◽  
Xiaoyu Meng ◽  
Kun Zhao ◽  
...  

To achieve desirable performance of a polymer electrolyte membrane with higher proton conduction and better mechanical strength is a challenging work in the development of the phosphoric acid (PA) doped solid-state membrane.


2021 ◽  
Author(s):  
Martina Rihova ◽  
Oksana Yurkevich ◽  
Martin Motola ◽  
Ludek Hromadko ◽  
Zdeněk Spotz ◽  
...  

This work describes the synthesis of highly photocatalytically active TiO2 tubes (TiTBs) by combining centrifugal spinning and atomic layer deposition (ALD). Poly(vinyl pyrrolidone) (PVP) fibers were first produced by centrifugal...


Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3087
Author(s):  
Rana Smaida ◽  
Luc Pijnenburg ◽  
Silvia Irusta ◽  
Erico Himawan ◽  
Gracia Mendoza ◽  
...  

The treatment of osteochondral defects remains a challenge. Four scaffolds were produced using Food and Drug Administration (FDA)-approved polymers to investigate their therapeutic potential for the regeneration of the osteochondral unit. Polycaprolactone (PCL) and poly(vinyl-pyrrolidone) (PVP) scaffolds were made by electrohydrodynamic techniques. Hydroxyapatite (HAp) and/or sodium hyaluronate (HA) can be then loaded to PCL nanofibers and/or PVP particles. The purpose of adding hydroxyapatite and sodium hyaluronate into PCL/PVP scaffolds is to increase the regenerative ability for subchondral bone and joint cartilage, respectively. Human bone marrow-derived mesenchymal stem cells (hBM-MSCs) were seeded on these biomaterials. The biocompatibility of these biomaterials in vitro and in vivo, as well as their potential to support MSC differentiation under specific chondrogenic or osteogenic conditions, were evaluated. We show here that hBM-MSCs could proliferate and differentiate both in vitro and in vivo on these biomaterials. In addition, the PCL-HAp could effectively increase the mineralization and induce the differentiation of MSCs into osteoblasts in an osteogenic condition. These results indicate that PCL-HAp biomaterials combined with MSCs could be a beneficial candidate for subchondral bone regeneration.


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