Mechanical and Electrical Properties of Carbon Nanotubes Based Acrylonitrile Butadiene Styrene Nanocomposite Fabricated Using Fused Deposition Method

Author(s):  
Sachin Kulkarni ◽  
Jitendra Singh ◽  
Dattaji Shinde
2017 ◽  
Vol 898 ◽  
pp. 2384-2391
Author(s):  
Jin Zhu ◽  
Biao Wang

Multi-walled carbon nanotubes (MWCNTs)/acrylonitrile butadiene styrene (ABS) nanocomposites were prepared by melt blending and then filaments were obtained by melt extrusion method. The Scanning electron microscope (SEM) exhibited good dispersion of MWCNTs in the SAN phase of the ABS matrix. The rheological results showed that incorporation of MWCNTs into ABS resulted in higher storage modulus (G′) and loss modulus (G′′) than those of ABS, especially at low frequencies. The tensile strength and modulus of MWCNT/ABS nanocomposite filaments substantially increased with the MWCNTs content while the elongation at break decreased. Additionally, the addition of MWCNTs decreased the coefficient of linear thermal expansion. This study provides a basis for further development of MWCNT/ABS nanocomposites used for FDM process with desirable mechanical properties and good dimension stability.


2021 ◽  
Vol 11 (3) ◽  
pp. 1272
Author(s):  
Bartłomiej Podsiadły ◽  
Piotr Matuszewski ◽  
Andrzej Skalski ◽  
Marcin Słoma

In this publication, we describe the process of fabrication and the analysis of the properties of nanocomposite filaments based on carbon nanotubes and acrylonitrile butadiene styrene (ABS) polymer for fused deposition modeling (FDM) additive manufacturing. Polymer granulate was mixed and extruded with a filling fraction of 0.99, 1.96, 4.76, 9.09 wt.% of CNTs (carbon nanotubes) to fabricate composite filaments with a diameter of 1.75 mm. Detailed mechanical and electrical investigations of printed test samples were performed. The results demonstrate that CNT content has a significant influence on mechanical properties and electrical conductivity of printed samples. Printed samples obtained from high CNT content composites exhibited an improvement in the tensile strength by 12.6%. Measurements of nanocomposites’ electrical properties exhibited non-linear relation between the supply voltage and measured sample resistivity. This effect can be attributed to the semiconductor nature of the CNT functional phase and the occurrence of a tunnelling effect in percolation network. Detailed I–V characteristics related to the amount of CNTs in the composite and the supply voltage influence are also presented. At a constant voltage value, the average resistivity of the printed elements is 2.5 Ωm for 4.76 wt.% CNT and 0.15 Ωm for 9.09 wt.% CNT, respectively. These results demonstrate that ABS/CNT composites are a promising functional material for FDM additive fabrication of structural elements, but also structural electronics and sensors.


2018 ◽  
Vol 24 (6) ◽  
pp. 921-934 ◽  
Author(s):  
Mohammad Abu Hasan Khondoker ◽  
Asad Asad ◽  
Dan Sameoto

Purpose This paper aims to target to print functionally gradient materials (FGM) devices made of immiscible polymers in multi-material fused deposition modelling (FDM) systems. The design is intended to improve adhesion of dissimilar thermoplastics without the need for chemical compatibilization so that filaments from many different sources can be used effectively. Therefore, there is a need to invent an alternative solution for printing multiple immiscible polymers in an FDM system with the desired adhesion. Design/methodology/approach In this study, the authors have developed a bi-extruder for FDM systems which can print two thermoplastics through a single nozzle with a static intermixer to enhance bonding between input materials. The system can also change the composition of extrudates continuously. Findings The uniqueness of this extruder is in its easy access to the internal channel so that a static intermixer can be inserted, enabling deposition of mechanically interlocked extrudates composed of two immiscible polymers. Without this intermixer, the bi-extruder extrudes with simple side-by-side co-extrusion having no mechanical interlocking. The bi-extruder was characterized by printing objects using pairs of materials including polylactic acid, acrylonitrile butadiene styrene and high impact polystyrene. Microscope images of the cross-sections of the extrudates confirm the ability of this bi-extruder to control the composition as desired. It was also found that the mechanically interlocked extrudates composed of two immiscible polymers substantially reduces adhesion failures within and between filaments. Originality/value In this study, the first-ever FDM extruder with a mechanical blending feature next to the nozzle has been designed and used to successfully print FGM objects with improved mechanical properties.


Author(s):  
Dominic Thaler ◽  
Nahal Aliheidari ◽  
Amir Ameli

Additive manufacturing is an emerging method to produce customized parts with functional materials without big investments. As one of the common additive manufacturing methods, fused deposition modeling (FDM) uses thermoplastic-based feedstock. It has been recently adapted to fabricate composite materials too. Acrylonitrile butadiene styrene (ABS) is the most widely used material as FDM feedstock. However, it is an electrically insulating polymer. Carbon Nanotubes (CNTs) on the other hand are highly conductive. They are attractive fillers because of their high aspect ratio, and excellent mechanical and physical properties. Therefore, a nanocomposite of these two materials can give an electrically conductive material that is potentially compatible with FDM printing. This work focuses on the investigation of the relationships between the FDM process parameters and the electrical conductivity of the printed ABS/CNT nanocomposites. Nanocomposite filaments with CNT contents up to 10wt% were produced using a twin-screw extruder followed by 3D printing using FDM method. The starting material was pellets from a masterbatch containing 15 wt% CNT. Compression-molded samples of ABS/CNT were also prepared as the bulk baselines. The effects of CNT content and nozzle size on the through-layer and in-layer electrical conductivity of the printed nanocomposites were analyzed. Overall, a higher percolation threshold was observed in the printed samples, compared to that of the compression-molded counterparts. This resulted in the conductivity of the printed samples that is at least one order of magnitude lower. Moreover, at CNT contents up to 5 wt%, the in-layer conductivity of the printed samples was almost two orders of magnitudes higher than that in the through-layer direction. In ABS/3 wt% CNT samples, the through-layer conductivity continuously decreased as the nozzle diameter was decreased from 0.8 mm to 0.35 mm. These variations in the electrical conductivity were explained in terms of the CNT alignment, caused by the extrusion process during the print, quality of interlayer bonding during deposition, and the voids created due to the discrete nature of the printing process.


2021 ◽  
Vol 19 (2) ◽  
pp. 271
Author(s):  
Yu-Ting Zuo ◽  
Hong-Jun Liu

Graphene and carbon nanotubes have a Steiner minimum tree structure, which endows them with extremely good mechanical and electronic properties. A modified Hall-Petch effect is proposed to reveal the enhanced mechanical strength of the SiC/graphene composites, and a fractal approach to its mechanical analysis is given.  Fractal laws for the electrical conductivity of graphene, carbon nanotubes and graphene/SiC composites are suggested using the two-scale fractal theory. The Steiner structure is considered as a cascade of a fractal pattern. The theoretical results show that the two-scale fractal dimensions and the graphene concentration play an important role in enhancing the mechanical and electrical properties of graphene/SiC composites. This paper sheds a bright light on a new era of the graphene-based materials.


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