scholarly journals A Numerical Investigation of Electrically-Heated Methane Steam Reforming Over Structured Catalysts

2021 ◽  
Vol 3 ◽  
Author(s):  
Matteo Ambrosetti ◽  
Alessandra Beretta ◽  
Gianpiero Groppi ◽  
Enrico Tronconi
Keyword(s):  
Numerical Investigation ◽  
Steam Reforming ◽  
Catalyst Support ◽  
Electric Energy ◽  
Lower Surface ◽  
Production Method ◽  
Electrical Heating ◽  
Methane Steam Reforming ◽  
Heat Of Reaction ◽  
The Impact

The use of electric energy as an alternative system to provide heat of reaction enables the cut-off of CO2 emissions of several chemical processes. Among these, electrification of steam methane reforming results in a cleaner production method of hydrogen. In this work, we perform for the first time a numerical investigation of a compact steam reforming unit that exploits the electrical heating of the catalyst support. First, for such unit we consider the optimal thermodynamic conditions to perform the power to hydrogen conversion; the process should be run at atmospheric pressure and in a close temperature range. Then, among possible materials currently used for manufacturing structured supports we identify silicon carbide as the best material to run electrified steam reforming at moderate voltages and currents. The temperature and concentration profiles in idealized units are studied to understand the impact of the catalyst geometry on the process performances and open-cell foams, despite lower surface to volume show the best potential. Finally, the impact of heat losses is analyzed by considering different operative conditions and reactor geometries, showing that it is possible to obtain relatively high thermal efficiencies with the proposed methodology.

Ultra-Low Amounts of Palladium (0.005-0.05 Wt% Pd) Supported on Titania: Remarkable Low-Temperature Activity for NO Reduction with CO and Structure-Function Property Relationships in Methane Oxidation

2020 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Libor Kovarik ◽  
Nicholas R. Jaegers ◽  
János Szanyi ◽  
Yong Wang
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Methane Oxidation ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Oxide Reduction ◽  
Water Steam ◽  
Methane Steam ◽  
Anatase Titania ◽  
Nitric Oxide Reduction

<p>Atomically dispersed Pd +2 cations with ultra-dilute loading of palladium (0.005-0.05 wt%) were anchored on anatase titania and characterized with FTIR, microscopy and catalytic tests. CO infrared adsorption produces a sharp, narrow mono-carbonyl Pd(II)-CO band at ~2,130 cm<sup>-1</sup> indicating formation of highly uniform and stable Pd+2 ions on anatase titania. The 0.05 wt% Pd/TiO<sub>2</sub> sample was evaluated for methane combustion under dry and wet (industrially relevant) conditions in the presence and absence of carbon monoxide. Notably, we find the isolated palladium atoms respond dynamically upon oxygen concentration modulation (switching-on and switching off). When oxygen is removed from the wet methane stream, palladium ions are reduced to metallic state by methane and catalyze methane steam reforming instead of complete methane oxidation. Re-admission of oxygen restores Pd<sup>+2</sup> cations and switches off methane steam reforming activity. Moreover, 0.05 wt% Pd/TiO<sub>2</sub> is a competent CO oxidation catalyst in the presence of water steam with 90% CO conversion and TOF ~ 4,000 hr<sup>-1</sup> at 260 ⁰C. </p><p>More importantly, we find that diluting 0.05 wt% Pd/titania sample with titania to ultra-low 0.005 wt% palladium loading produces a remarkably active material for nitric oxide reduction with carbon monoxide under industrially relevant conditions with >90% conversion of nitric oxide at 180 ⁰C (~460 ppm NO and 150 L/g*hr flow rate in the presence of >2% water steam) and TOF ~6,000 hr<sup>-1</sup>. Pd thus outperforms state-of-the-art rhodium containing catalysts with (15-20 times higher rhodium loading; rhodium is ~ 3 times more expensive than palladium). Furthermore, palladium catalysts are more selective towards nitrogen and produce significantly less ammonia relative to the more traditional rhodium catalysts due to lower Pd amount nd lower water-gas-shift activity. Our study is the first example of utilizing ultra-low (0.05 wt% and less) noble metal (Pd) amounts to produce heterogeneous catalysts with extraordinary activity for nitric oxide reduction. This opens up a pathway to study other Pd, Pt and Rh containing materials with ultra-low loadings of expensive noble metals dispersed on titania or titania-coated oxides for industrially relevant nitric oxide abatement.</p>

AN EXPERIMENTAL AND NUMERICAL STUDY OF HEAT TRANSFER IN A SIMULATED COLLECTOR FOR A SOLAR DRYER

1993 ◽  
Vol 17 (2) ◽  
pp. 145-160
Author(s):  
P.H. Oosthuizen ◽  
A. Sheriff
Keyword(s):  
Heat Transfer ◽  
Numerical Study ◽  
Local Heat Transfer ◽  
Lower Surface ◽  
Local Heat ◽  
Electrical Heating ◽  
Temperature Profiles ◽  
Measured Temperature ◽  
Transfer Rates ◽  
Thermocouple Probe

Indirect passive solar crop dryers have the potential to considerably reduce the losses that presently occur during drying of some crops in many parts of the “developing” world. The performance so far achieved with such dryers has, however, not proved to be very satisfactory. If this performance is to be improved it is necessary to have an accurate computer model of such dryers to assist in their design. An important element is any dryer model is an accurate equation for the convective heat transfer in the collector. To assist in the development of such an equation, an experimental and numerical study of the collector heat transfer has been undertaken. In the experimental study, the collector was simulated by a 1m long by 1m wide channel with a gap of 4 cm between the upper and lower surfaces. The lower surface of the channel consisted of an aluminium plate with an electrical heating element, simulating the solar heating, bonded to its lower surface. Air was blown through this channel at a measured rate and the temperature profiles at various points along the channel were measured using a shielded thermocouple probe. Local heat transfer rates were then determined from these measured temperature profiles. In the numerical study, the parabolic forms of the governing equations were solved by a forward-marching finite difference procedure.

scholarly journals DFT Benchmark Studies on Representative Species and Poisons of Methane Steam Reforming on Ni(111)

2021 ◽  
Author(s):  
Sai Sharath Yadavalli ◽  
Glenn Jones ◽  
Michail Stamatakis
Keyword(s):  
Steam Reforming ◽  
Graphitic Carbon ◽  
Methane Steam Reforming ◽  
Ni Catalysts ◽  
Methane Steam ◽  
Representative Species ◽  
Industrial Operations ◽  
Major Impediment ◽  
Carbon Based

Ni catalysts used in Methane Steam Reforming (MSR) are highly susceptible to poisoning by carbon-based species, which poses a major impediment to the productivity of industrial operations. These graphitic carbon-like...

scholarly journals Conventional and Organic Honeys as a Source of Water- and Ethanol Soluble Molecules with Nutritional and Antioxidant Characteristics

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3746
Author(s):  
Magdalena Polak-Śliwińska ◽  
Małgorzata Tańska
Keyword(s):  
Antioxidant Activity ◽  
Immune System ◽  
Vitamin C ◽  
Geographical Area ◽  
Production Method ◽  
Climatic Conditions ◽  
Organic Production ◽  
Organoleptic Characteristics ◽  
Nutritional Characteristics ◽  
The Impact

The benefits of natural honeybee products (e.g., honey, royal jelly, beeswax, propolis, beevenom and pollen) to the immune system are remarkable, and many of them are involved in the induction of antibody production, maturation of immune cells and stimulation of the immune system. The type of plants in the geographical area, climatic conditions and production method have a significantly influence on the nutritional quality of honey. However, this variability can influence consumer liking by the sensory attributes of the product. The aim of this work was to compare the most popular honeys from Poland in terms of nutritional value, organoleptic properties and antioxidant activity. In the study, five varieties of honey (honeydew, forest, buckwheat, linden and dandelion) from conventional and organic production methods were tested. The nutritional characteristics of honey samples included acidity, content of water, sugars, vitamin C, HMF and phenolics (total and flavonoids), while honey color, taste, aroma and consistency were investigated in the organoleptic characteristics. The antioxidant activity was determined in water- and ethanol-soluble honey extracts using DPPH and ORAC tests. The results showed that organoleptic and nutritional characteristics of popular Polish honeys differ significantly in relation to plant source and production method. The significant effect of honey variety on the content of HMF, saccharose and phenolics, as well as acidity and antioxidant capacity were noted. The impact of variety and variety × production method interaction was significant in the case of the content of vitamin C, glucose and fructose. A visible difference of buckwheat and forest honeys from other samples was observed. The highest content of total phenolics with antioxidant activity based on the SET mechanism was found in buckwheat honeys, while forest honeys were richer in flavonoids.

scholarly journals Retraction: Computational fluid dynamics modeling of the millisecond methane steam reforming in microchannel reactors for hydrogen production

RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12531-12531
Author(s):  
Junjie Chen ◽  
Xuhui Gao ◽  
Longfei Yan ◽  
Deguang Xu
Keyword(s):  
Fluid Dynamics ◽  
Computational Fluid Dynamics ◽  
Hydrogen Production ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Dynamics Modeling ◽  
Computational Fluid Dynamics Modeling ◽  
Microchannel Reactors ◽  
Methane Steam

Retraction of ‘Computational fluid dynamics modeling of the millisecond methane steam reforming in microchannel reactors for hydrogen production’ by Junjie Chen et al., RSC Adv., 2018, 8, 25183–25200, DOI: 10.1039/C8RA04440F.

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