scholarly journals An Innovative Green Process for the Stabilization and Valorization of Organic Fraction of Municipal Solid Waste (OFMSW): Optimization of the Curing Process II Part

2019 ◽  
Vol 9 (18) ◽  
pp. 3702 ◽  
Author(s):  
Carola Esposito Corcione ◽  
Francesca Ferrari ◽  
Raffaella Striani ◽  
Paolo Visconti ◽  
Antonio Greco

This work is focused on the optimization of an innovative and cheap process for the valorization of the organic fraction of municipal solid waste (OFMSW), through its transformation into an odorless and environmentally compatible material to be employed for building applications or as a thermal and acoustic insulator. The process starts with the grinding of OFMSW, followed by its sterilization in order to obtain a complete removal of the bacterial activity. Afterwards, the incorporation in a catalysed thermosetting matrix is carried out by mixing the OFMSW to a water soluble urea formaldehyde based resin (UF), characterized by a formaldehyde content lower than 1% wt. The OFMSW/UF blends were firstly analysed by the dynamic rheological analyses, as a function of the content of a proper catalyst, that is able to decrease the curing temperature and time. Rheological analyses results allowed the selection of times and temperatures necessary for the polymerization (T = 60 °C, t = 1 h). The effect of the presence of different additives on both the cure process and the mechanical properties of the cured samples was finally analysed, evidencing that the OFMSW/UF composites possess improved mechanical properties in comparison to that of the neat resin.

2019 ◽  
Vol 9 (21) ◽  
pp. 4516 ◽  
Author(s):  
Carola Esposito Corcione ◽  
Francesca Ferrari ◽  
Raffaella Striani ◽  
Stefania Minosi ◽  
Mauro Pollini ◽  
...  

This work is aimed at the development of innovative, easy and cheap methods for the stabilization, inertization and valorisation of the organic fraction of municipal solid waste (OFMSW). For the first time, two original processes for transforming the organic waste into an inert, odorless and sanitized material were here proposed. The first one, called dual step, starts with grinding of the OFMSW, by means of an industrial shredder. After being finely ground, the organic waste was exposed to a sterilization process by means of UV/ozone radiations or thermal treatment (stabilization phase) in order to obtain a complete removal of the OFMSW’s bacterial activity. By means of several microbiological analyses, the best sterilization method was chosen. The incorporation in a thermosetting matrix was, then, carried out through mixing the sterilized and finely ground organic waste into a water soluble urea formaldehyde (UF) based resin, with a formaldehyde content less than 1% wt, followed by a thermal treatment for UF-resin crosslinking (inertization phase). An alternative cheaper and easier process, called one step, was also proposed and investigated, by combining the sterilization with the curing thermal process (at higher temperature) of the thermosetting matrix. The preliminary experimental results reported in this paper suggest that both the proposed methods could be considered suitable for the production of high valorized innovative OFMSW-derived panels or bricks that could find application in several fields, such as building or construction materials. Finally, a brief description of the prototype machinery, properly designed for implementing OFMSW stabilization and valorization processes, is reported.


Author(s):  
Carola Esposito Corcione ◽  
Francesca Ferrari ◽  
RAFFAELLA STRIANI ◽  
Stefania Minosi ◽  
Mauro Pollini ◽  
...  

This work is aimed at the development of innovative, easy and cheap methods for the stabilization, inertization and valorisation of the organic fraction of municipal solid waste (OFMSW). For the first time, two original processes for transforming the organic waste into an inert, odorless and sanitized material were here proposed. The first one, called dual step, starts with grinding of the OFMSW, by means of an industrial shredder. After being finely ground, the organic waste was exposed to a sterilization process by means of UV/ozone radiations or thermal treatment (stabilization phase) in order to obtain a complete removal of the OFMSW’s bacterial activity. By means of several microbiological analyses, the best sterilization method was chosen. The incorporation in a thermosetting matrix was, then, carried out through mixing the sterilized and finely ground organic waste into a water soluble urea formaldehyde (UF) based resin, with a formaldehyde content less than 1% wt, followed by a thermal treatment for UF-resin crosslinking (inertization phase). An alternative cheaper and easier process, called one step, was also proposed and investigated, by combining the sterilization with the curing thermal process (at higher temperature) of the thermosetting matrix. The preliminary experimental results reported in this paper suggest that both the proposed methods could be considered suitable for the production of high valorized innovative OFMSW-derived panels or bricks, that could find application in several fields, such as building or constructions materials. Finally a brief description of the prototype machinery is reported properly designed for implementing OFMSW stabilization and valorisation processes developed in this research work.


2013 ◽  
Vol 871 ◽  
pp. 253-258
Author(s):  
J. Ronald Aseer ◽  
K. Sankaranarayanasamy ◽  
P. Jayabalan

Hybrid composites of municipal solid waste (MSW)/banana fiber reinforced urea formaldehyde are prepared with different filler ratio. Mechanical properties such as tensile, flexural and impact strengths are investigated as a function of total volume fraction (Vf) of filler (MSW and banana fiber) and its chemical modification. The mechanical properties are found to be high at 40% Vf of filler which indicates effective stress transfer between fiber and matrix. It is observed that presence of banana fiber provides better mechanical properties to composites. The chemically treated composites showed higher tensile and flexural strength compared to untreated composites due to the strong interfacial interaction between the resin and fiber.


Author(s):  
John Joseph Raj Ronald Aseer ◽  
Krishnasamy Sankaranarayanasamy ◽  
Perumalsamy Jayabalan ◽  
Ramakrishna Natarajan ◽  
Keereyadath Priya Dasan

AbstractMunicipal solid waste (MSW) generation increased rapidly due to the change in food habits, increasing urbanization and changed lifestyle of people. The aim of the present study was to analyze the possible use of MSW as filler in fiber-reinforced urea formaldehyde composites. The mechanical properties of the composites were investigated as a function of different volume fractions (


2016 ◽  
Vol 2 (2) ◽  
pp. 39-44
Author(s):  
Oscar Cabeza ◽  
◽  
Alfredo Alonso ◽  
Yoel Lastre ◽  
Jorge Medina ◽  
...  

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Jon Kepa Izaguirre ◽  
Leire Barañano ◽  
Sonia Castañón ◽  
José A. L. Santos ◽  
M. Teresa Cesário ◽  
...  

AbstractThe management of municipal solid waste is a major logistic and environmental problem worldwide. Nonetheless, the organic fraction of municipal solid waste (OFMSW) is a valuable source of nutrients which can be used for a variety of purposes, according to the Circular Economy paradigm. Among the possible applications, the bioproduction of a biodegradable polyester, poly(3-hydroxybutyrate) [P(3HB)], using OFMSW as carbon platform is a promising strategy. Here, an economic and environmental assessment of bacterial P(3HB) production from OFMSW is presented based on previously published results. The SuperPro Designer® software was used to simulate P(3HB) production under our experimental parameters. Two scenarios were proposed depending on the fermentation medium: (1) enzymatic hydrolysate of OFMSW supplemented with glucose and plum waste juice; and (2) basal medium supplemented with glucose and plum waste juice. According to our results, both scenarios are not economically feasible under our experimental parameters. In Scenario 1, the low fermentation yield, the cost of the enzymes, the labour cost and the energy consumption are the factors that most contribute to that result. In Scenario 2, the cost of the extraction solvent and the low fermentation yield are the most limiting factors. The possibility of using process waste as raw material for the generation of other products must be investigated to enhance economic feasibility. From an environmental viewpoint, the photochemical oxidation potential (derived from the use of anisole as extraction solvent) and the generation of acid rain and global warming effect (caused by the burning of fuels for power generation) are the most relevant impacts associated to P(3HB) production under our experimental parameters.


2021 ◽  
pp. 0734242X2110134
Author(s):  
Rasangika Thathsaranee Weligama Thuppahige ◽  
Sandhya Babel

The management of organic fraction of municipal solid waste (OFMSW) has continued to be a significant challenge in Sri Lanka. Anaerobic digestion is one of the management options of OFMSW. However, it generates unavoidable environmental impacts that should be addressed. The present study focuses to assess the environmental impact of a full-scale anaerobic digestion plant in Sri Lanka from a life cycle perspective. The inventory data were obtained from direct interviews and field measurements. Environmental burdens were found to be in terms of global warming potential (230 kg CO2 eq) ozone formation on human health (6.15 × 10−6 kg NO x eq), freshwater eutrophication (2.92 × 10−3 kg P eq), freshwater ecotoxicity (9.27 × 10−5 kg 1,4 DCB eq), human carcinogenic toxicity (3.98 × 10−4 kg 1,4 DCB eq), land use (1.32 × 10−4 m2 a crop eq) and water consumption (2.23 × 10−2 m3). The stratospheric ozone depletion, fine particulate matter formation, ozone formation on terrestrial ecosystems, terrestrial acidification, marine eutrophication, ecotoxicity (terrestrial and marine), human non-carcinogenic toxicity, mineral resource scarcity and fossil resource scarcity, were avoided due to electricity production. Results show that the direct gaseous emissions and digestate generation should be addressed in order to reduce the burdens from the anaerobic digestion plant. Finally, the results of the study could help in policy formation and decision-making in selecting future waste management systems in Sri Lanka.


2019 ◽  
Vol 11 (7) ◽  
pp. 3293-3301
Author(s):  
Mingyu Qian ◽  
Ye Zhou ◽  
Yixin Zhang ◽  
Zhenxin Wang ◽  
Ruihua Li ◽  
...  

2012 ◽  
Vol 37 (19) ◽  
pp. 14062-14071 ◽  
Author(s):  
Kathy Bru ◽  
Vincent Blazy ◽  
Catherine Joulian ◽  
Eric Trably ◽  
Eric Latrille ◽  
...  

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