scholarly journals Nanozyme-Participated Biosensing of Pesticides and Cholinesterases: A Critical Review

Biosensors ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 382
Author(s):  
Hengjia Zhu ◽  
Peng Liu ◽  
Lizhang Xu ◽  
Xin Li ◽  
Panwang Hu ◽  
...  

To improve the output and quality of agricultural products, pesticides are globally utilized as an efficient tool to protect crops from insects. However, given that most pesticides used are difficult to decompose, they inevitably remain in agricultural products and are further enriched into food chains and ecosystems, posing great threats to human health and the environment. Thus, developing efficient methods and tools to monitor pesticide residues and related biomarkers (acetylcholinesterase and butylcholinesterase) became quite significant. With the advantages of excellent stability, tailorable catalytic performance, low cost, and easy mass production, nanomaterials with enzyme-like properties (nanozymes) are extensively utilized in fields ranging from biomedicine to environmental remediation. Especially, with the catalytic nature to offer amplified signals for highly sensitive detection, nanozymes were finding potential applications in the sensing of various analytes, including pesticides and their biomarkers. To highlight the progress in this field, here the sensing principles of pesticides and cholinesterases based on nanozyme catalysis are definitively summarized, and emerging detection methods and technologies with the participation of nanozymes are critically discussed. Importantly, typical examples are introduced to reveal the promising use of nanozymes. Also, some challenges in the field and future trends are proposed, with the hope of inspiring more efforts to advance nanozyme-involved sensors for pesticides and cholinesterases.

Micromachines ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 147
Author(s):  
Kristina A. Malsagova ◽  
Tatyana O. Pleshakova ◽  
Vladimir P. Popov ◽  
Igor N. Kupriyanov ◽  
Rafael A. Galiullin ◽  
...  

Gas-phase etching and optical lithography were employed for the fabrication of a silicon nanoribbon chip (Si-NR chip). The quality of the so-fabricated silicon nanoribbons (Si-NRs) was monitored by optical Raman scattering spectroscopy. It was demonstrated that the structures of the Si-NRs were virtually defect-free, meaning they could be used for highly sensitive detection of biological macromolecules. The Si-NR chips were then used for the highly sensitive nanoelectronics detection of DNA oligonucleotides (oDNAs), which represent synthetic analogs of 106a-5p microRNA (miR-106a-5p), associated with the development of autism spectrum disorders in children. The specificity of the analysis was attained by the sensitization of the Si-NR chip sur-face by covalent immobilization of oDNA probes, whose nucleotide sequence was complementary to the known sequence of miR-106a-5p. The use of the Si-NR chip was demonstrated to al-low for the rapid label-free real-time detection of oDNA at ultra-low (~10−17 M) concentrations.


2017 ◽  
Vol 9 (6) ◽  
pp. 1031-1037 ◽  
Author(s):  
Jingtao Liu ◽  
Yu Ding ◽  
Lifei Ji ◽  
Xin Zhang ◽  
Fengchun Yang ◽  
...  

Hexavalent chromium (Cr(vi)) is one of the most toxic heavy metal pollutants in groundwater, and thus the detection of Cr(vi) with high sensitivity, accuracy, and simplicity and low cost is of great importance.


2021 ◽  
Author(s):  
shenwei he ◽  
Jianming Zhu ◽  
peiyao xie ◽  
Jianfei Liu ◽  
Di Zhang ◽  
...  

Nitroxyl (HNO) as an important reactive nitrogen species (RNS), which plays an important role in multiple physiological process. Therefore, it is urgent to exploit reliable and efficient detection methods for...


ACS Omega ◽  
2020 ◽  
Vol 5 (28) ◽  
pp. 17423-17430
Author(s):  
Piyaporn Matulakul ◽  
Drusawin Vongpramate ◽  
Sirinan Kulchat ◽  
Apiwat Chompoosor ◽  
Raynoo Thanan ◽  
...  

The Analyst ◽  
2020 ◽  
Vol 145 (13) ◽  
pp. 4646-4663
Author(s):  
Xing Ze Wang ◽  
Jing Du ◽  
Nan Nan Xiao ◽  
Yan Zhang ◽  
Ling Fei ◽  
...  

ThT@Er-MOF has been successfully applied in highly sensitive detection of three main Alzheimer Disease biomarkers through three different low cost and facile detection strategies.


TAPPI Journal ◽  
2012 ◽  
Vol 11 (1) ◽  
pp. 19-26 ◽  
Author(s):  
BILJANA M. BUJANOVIC ◽  
MANGESH J. GOUNDALKAR ◽  
THOMAS E. AMIDON

In conventional pulping technologies, lignin is used mainly as a low-cost source of energy. Small quantities of industrially produced lignin are used for the production of chemicals and materials. Biorefinery technologies are emerging that have an ultimate goal of replacing fossil sources for the production of fuels and other products. To achieve this goal effectively, biorefinery technologies must take advantage of lignin as the most abundant natural aromatic polymer and use it to add higher-value products to product portfolios. Lignin has the potential to be used in making a broad range of high-quality products, including carbon fibers, thermoplastics, and oxygenated aromatic compounds. Existing processes focus primarily on the quality of cellulose and result in a severely modified and contaminated lignin of relatively low value. Lignin produced in more flexible biorefinery operations is more uniform and less contaminated than currently available industrial lignins, opening the door for broader applications of lignin and lignin products. The results of isolation and characterization of lignin dissolved during hot-water extraction and some potential applications of this lignin are discussed.


2018 ◽  
Vol 281 ◽  
pp. 710-715
Author(s):  
Muhammad Shahid ◽  
Tian Jun Li ◽  
Meng Fei Zhang ◽  
Jing Cheng ◽  
Yan Xing ◽  
...  

Ultraviolet photodetectors (PDs) based on low-dimensional (LD) gallium oxide nanofibers were synthesized and assembled by a low cost and scalable electrospinning method. Highly uniaxially aligned nanofibers were used to assemble photodetectors. Photoconductive investigations indicate that the prepared photodetectors (PDs) are highly sensitive to ultraviolet (UV) light. The prepared photodetectors have shown a high photosensitivity (103), fast photoresponse, excellent stability, and reproducibility under the illumination of UV light 254 nm. These electrospun nanofibers have also shown a high transparency (<85%) in the visible light 400-700 nm range. The high transparency of these nanobelts demonstrates their use for invisible UV photosensors.


2014 ◽  
Vol 881-883 ◽  
pp. 169-172 ◽  
Author(s):  
Qian Xiang ◽  
Xiao Dong Yang ◽  
Ying Gao ◽  
Ling Yun Tian ◽  
Juan Tang ◽  
...  

An electrochemiluminescence (ECL) sensor for highly sensitive detection of diphenhydramine was developed by employing tris (2,2-bipyridyl) ruthenium (II) as the detector. The ECL sensor was fabricated by immobilizing ECL reagent Ru (bpy)32+ on the poly-(3,4-ethylene dioxythiophene) and polystyrene sulfonate composite film (PEDOT-PSS) modified indium tin oxides (ITO) electrode by electrostatic attraction strategy. The ECL sensor showed an increased ECL intensity in the presence of diphenhydramine. The increased ECL intensity was direct proportion to the concentration of diphenhydramine over a range from 5.0 ×10-4 to 5.0 ×10-6 mol/L. The detection limit for the detection of diphenhydramine was 1.0 ×10-6 mol/L. Fabrication of the ECL sensor by this method is simple and easy, and hence has potential applications in the field of ECL analysis and detection.


Toxins ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 499
Author(s):  
Krisztina Majer-Baranyi ◽  
Nóra Adányi ◽  
András Székács

Mycotoxin contamination of cereals used for feed can cause intoxication, especially in farm animals; therefore, efficient analytical tools for the qualitative and quantitative analysis of toxic fungal metabolites in feed are required. Current trends in food/feed analysis are focusing on the application of biosensor technologies that offer fast and highly selective and sensitive detection with minimal sample treatment and reagents required. The article presents an overview of the recent progress of the development of biosensors for deoxynivalenol and zearalenone determination in cereals and feed. Novel biosensitive materials and highly sensitive detection methods applied for the sensors and the application of these sensors to food/feed products, the limit, and the time of detection are discussed.


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