scholarly journals Poisoning of SCR Catalysts by Alkali and Alkaline Earth Metals

Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1475
Author(s):  
Luciana Lisi ◽  
Stefano Cimino

SCR still represents the most widely applied technique to remove nitrogen oxides from flue gas from both stationary and mobile sources. The catalyst lifetime is greatly affected by the presence of poisoning compounds in the exhaust gas that deactivate the catalysts over time on stream. The progressive and widespread transition towards bio-derived fuels is pushing research efforts to deeply understand and contrast the deactivating effects of some specific poisons among those commonly found in the emissions from combustion processes. In particular, exhaust gases from the combustion of bio-fuels, as well as from municipal waste incineration plants and marine engines, contain large amounts of alkali and alkaline earth metals that can severely affect the acid, redox, and physical properties of the SCR catalysts. This review analyzes recent studies on the effects of alkali and alkaline earth metals on different types of SCR catalysts divided into three main categories (conventional V2O5-WO3/TiO2, supported non-vanadium catalysts and zeolite-based catalysts) specifically focusing on the impact of poisons on the reaction mechanism while highlighting the different type of deactivation affecting each group of catalysts. An overview of the different regeneration techniques aimed at recovering as much as possible the original performance of the catalysts, highlighting the pros and cons, is given. Finally, current research trends aiming to improve the tolerance towards alkali-poisoning of SCR catalysts are reported.

2020 ◽  
Vol 3 (2) ◽  
pp. 396-402
Author(s):  
Maria Florentina Rumba ◽  
Margaretha P.N Rozady ◽  
Theresia W. Mado

Abstrak: Kebiasaan manusia berubah karena adanya wabah COVID-19, hal ini berpengaruh ketika manusia masuk ke dalam fase new normal. New normal diartikan sebagai keadaan yang tidak biasa dilakukan sebelumnya, yang kemudian dijadikan sebagai standar atau kebiasaan baru yang mesti dilakukan manusia untuk dirinya sendiri maupun untuk bersosialisasi dengan orang lain. Kebiasaan baru ini pun menimbulkan pro dan kontra seiring dengan dampak yang timbul. Lembaga pendidikan tinggi merupakan salah satu yang merasakan dampak penerapan new normal. Perkuliahan yang selama ini dilakukan secara online/daring, akan kembali dilakukan secara luring/tatap muka, dengan tetap menerapkan protokol COVID-19 seperti mengenakan masker, menjaga jarak, mengenakan sarung tangan, serta tidak melakukan kontak fisik seperti berjabat tangan. Masalah yang muncul bukan hanya kecemasan orang tua terhadap anak – anaknya, tetapi bagaimana lembaga pendidikan tinggi mengatur segala sumber daya yang dimiliki agar memenuhi standar penerapan new normal. penelitian ini bertujuan untuk mengetahui penerimaan  terhadap kondisi normal yang baru menggunakan Perspektif balance score card. Abstract: Human habits change because of the COVID-19 outbreak, this affects when humans enter the new normal phase. New normal is defined as a condition that is not normally done before, which is then used as a standard or new habits that must be done by humans for themselves or to socialize with others. This new habit also raises the pros and cons along with the impact arising with the new normal. Higher education institutions are the ones who feel the impact of implementing new normal. Lectures that have been conducted online / online will be re-done offline / face to face, while still applying the COVID-19 protocol such as wearing a mask, keeping a distance, wearing gloves, and not making physical contact such as shaking hands. The problem that arises is not only parents' anxiety about their children, but how higher education institutions regulate all available resources to meet new normal implementation standards. This study aims to determine acceptance of new normal conditions using the balance score card Perspective.


2017 ◽  
Vol 68 (1) ◽  
pp. 175-179
Author(s):  
Oana Roxana Chivu ◽  
Augustin Semenescu ◽  
Claudiu Babis ◽  
Catalin Amza ◽  
Gabriel Iacobescu ◽  
...  

Rainfall is a major component of the environment and the main source of the air purification becouse of many pollutants increases who have the most varied sources: various human activities including industry and agriculture, and some household duties. Air purification by means of precipitation is achieved by numerous highly complex mechanisms. The final products of degradation of the pollutant in the air, which are generally harmless, can be reacted with each other in the presence of water, giving rise to the final compounds with a high toxicity. Thus, exhaust, mobile sources of noxious almost identical to those specific activities in the industrial processing of oil, contain lead which is the ideal catalyst for converting SO2 to sulfuric acid in the presence of rainwater, with all the disadvantages that they create. This paper will present an experimental research oabout how rainfall water quality is influenced by the activity of the industrial processing of oil, in a chemical plant in Constanta County.


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