scholarly journals Photocatalytic Degradation of Sulfolane Using a LED-Based Photocatalytic Treatment System

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 624
Author(s):  
Sripriya Dharwadkar ◽  
Linlong Yu ◽  
Gopal Achari
Keyword(s):  
Photocatalytic Degradation ◽  
Oil And Gas ◽  
Light Emitting Diode ◽  
Tap Water ◽  
Aqueous Media ◽  
Ultrapure Water ◽  
Light Emitting ◽  
Degradation Rates ◽  
Reduced Graphene ◽  
The Impact

Sulfolane is an emerging industrial pollutant detected in the environments near many oil and gas plants in North America. So far, numerous advanced oxidation processes have been investigated to treat sulfolane in aqueous media. However, there is only a few papers that discuss the degradation of sulfolane using photocatalysis. In this study, photocatalytic degradation of sulfolane using titanium dioxide (TiO2) and reduced graphene oxide TiO2 composite (RGO-TiO2) in a light-emitting diode (LED) photoreactor was investigated. The impact of different waters (ultrapure water, tap water, and groundwater) and type of irradiation (UVA-LED and mercury lamp) on photocatalytic degradation of sulfolane were also studied. In addition, a reusability test was conducted for the photocatalyst to examine the degradation of sulfolane in three consecutive cycles with new batches of sulfolane-contaminated water. The results show that LED-based photocatalysis was effective in degrading sulfolane in waters even after three photocatalytic cycles. UVA-LEDs displayed more efficient use of photon energy when compared with the mercury lamps as they have a narrow emission spectrum coinciding with the absorption of TiO2. The combination of UVA-LED and TiO2 yielded better performance than UVA-LED and RGO-TiO2 for the degradation of sulfolane. Much lower sulfolane degradation rates were observed in tap water and groundwater than ultrapure water.

scholarly journals Impact of Slope of Growing Trays on Productivity of Wheat Green Fodder by a Nutrient Film Technique System

Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3009
Author(s):  
Andrius Grigas ◽  
Aurelija Kemzūraitė ◽  
Dainius Steponavičius ◽  
Aušra Steponavičienė ◽  
Rolandas Domeika
Keyword(s):  
Light Emitting Diode ◽  
Tap Water ◽  
Slope Angle ◽  
Experimental Studies ◽  
Matter Content ◽  
Light Sources ◽  
Dry Matter Content ◽  
Nutrient Film Technique ◽  
Indoor Lighting ◽  
The Impact

Application of hydroponic systems in feed production has not been extensively studied. Therefore, there is insufficient data on the effect of the slope of hydroponic growing trays used in the nutrient film technique on wheat fodder yield and its qualitative parameters. The slope of the trays has only been studied for food crops. This study conducted experimental research using a nutrient film technique hydroponic fodder growing device to evaluate the impact of growing tray slope angle on hydroponic wheat fodder production. The slope angle of the growing trays was changed from 2.0% (1.15°) to 8.0% (4.57°) with increments of 1.5% (0.86°). This research used two different light sources for wheat sprout illumination: indoor lighting (fluorescent lamps) and light-emitting diode illumination. In addition, two nutrient solutions were used for sprout irrigation: tap water and a solution enriched with macro- and microelements. Experimental studies confirmed the hypothesis that the slope angle of growing trays significantly affects the yield of wheat fodder grown for seven days. Analyzing the results, we found that the highest yield of wheat fodder after seven days of cultivation was achieved with growing trays sloped by 6.5% and using indoor lighting. In addition, we achieved the highest wheat fodder dry matter content using a 6.5% slope angle. Experimental studies also confirmed the hypothesis that using macro- and micronutrients in the nutrient solution does not significantly affect the yield of wheat fodder grown hydroponically for seven days.

Electrospun 3,5-dithienylvinyleneBODIPY embedded polystyrene nanofibers for the photocatalytic degradation of azo dyes in industrial wastewaters

2018 ◽  
Vol 22 (06) ◽  
pp. 501-508 ◽  
Author(s):  
Augustus K. Lebechi ◽  
Lizhi Gai ◽  
Zhen Shen ◽  
Tebello Nyokong ◽  
John Mack
Keyword(s):  
Methyl Orange ◽  
Photocatalytic Degradation ◽  
Azo Dyes ◽  
Solid Phase ◽  
Light Emitting Diode ◽  
Light Emitting ◽  
First Order Kinetics ◽  
Orange G ◽  
Methyl Orange Concentration ◽  
Degradation Properties

The potential utility of electrospun polystyrene (PS) nanofibers embedded with 2,6-diiodo-8-phenyl-1,7-dimethyl-3,5-di-2-thienylvinyleneBODIPY for the photocatalytic degradation of azo dyes is investigated. A comparison of the singlet oxygen quantum yield of the [Formula: see text]-extended BODIPY dye in solution and in the PS nanofibers demonstrates that its photosensitizer properties are retained when it is embedded in the solid phase. The photocatalytic degradation properties of the PS nanofibers for Methyl Orange and Orange G were determined by using a Thorlabs 625 nm light emitting diode. The rate of photodegradation increases with the Orange G and Methyl Orange concentration and follows pseudo-first order kinetics at pH 6.7.

The impact of LED illumination on antioxidant properties of sprouted seeds

2011 ◽  
Vol 6 (1) ◽  
pp. 68-74 ◽  
Author(s):  
Giedrė Samuolienė ◽  
Akvilė Urbonavičiūtė ◽  
Aušra Brazaitytė ◽  
Gintarė Šabajevienė ◽  
Jurga Sakalauskaitė ◽  
...  
Keyword(s):  
Light Emitting Diode ◽  
Antioxidant Properties ◽  
Radical Scavenging ◽  
Triticum Aestivum L ◽  
Alpha Tocopherol ◽  
Antioxidant Compounds ◽  
Light Emitting ◽  
Radish Sprouts ◽  
Sprouted Seeds ◽  
The Impact

AbstractThe objective of this study was to evaluate the effect of the light emitting diode (LED) spectra on the antioxidant properties of sprouted wheat (Triticum aestivum L.), radish (Raphanus sativus L.), and lentil (Lens esculenta Moenh.) seeds. Lighting experiments were performed under controlled conditions (PPFD - 100 μmol m−2 s−1; 12 h photoperiod; 27°C). The LED conditions used were: L1 - 638 nm; L2 - 455 nm, 638 nm, 669 nm, 731 nm (basal components); L3 - basal + 385 nm; L4 - basal + 510 nm and L5 - basal + 595 nm. Wheat and lentil sprouts were shown to accumulate less phenolic compounds and were more sensitive to light spectral differences when compared to radish sprouts. The antioxidant properties and contents of antioxidant compounds in seeds germinated in the dark were significantly lower than LED treated seeds. The higher content of total phenols and significant increase in alpha-tocopherol and vitamin C concentration resulted in altered DPPH free-radical scavenging capacity. Therefore we conclude that the LED spectra, based on basal components supplemented with green (510 nm) light can improve the antioxidant properties of sprouted seeds of lentil and wheat. The highest antioxidant properties of radish seeds were caused by radiation with supplemental amber (595 nm) light.

Photocatalytic Degradation of Indigo Carmine Dye Using Hydrothermally Synthesized Anatase TiO2 Nanotubes under Ultraviolet Light Emitting Diode Irradiation

2016 ◽  
Vol 855 ◽  
pp. 45-57 ◽  
Author(s):  
Kalithasan Natarajan ◽  
Rukshana I. Kureshy ◽  
Hari C. Bajaj ◽  
Rajesh J. Tayade
Keyword(s):  
Photocatalytic Degradation ◽  
Band Gap ◽  
Organic Dyes ◽  
Light Emitting Diode ◽  
Indigo Carmine ◽  
Order Kinetic ◽  
Light Emitting ◽  
Order Kinetic Model ◽  
Different Temperatures ◽  
Adsorption Desorption

Anatase TiO2 nanotubes (ATNT) was synthesised by hydrothermal method using anatase TiO2 nanoparticles (AT) as precursor and calcined at two different temperatures (250 & 450 °C) for 2 h. The AT and synthesized ATNT photocatalysts were characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption-desorption measurements, UV-vis diffuse reflectance and Fourier Transform Infra-red spectroscopy techniques for their structural, textural and electronic properties. The photocatalytic degradation of Indigo carmine (IC) dye aqueous solution has carried out using ATNT-250 and ATNT-450 photocatalysts under UVLED irradiation. The kinetic analysis has also revealed that the degradation of IC dye solution follows first order kinetic model. The overall study demonstrates the appropriate band gap of the photocatalysts used and the suitable irradiation source which could accelerate the rate of photocatalytic degradation. The band gap of the synthesised ATNT is not much affected due to the change in morphology from nanoparticle to nanotube. The results demonstrated that the irradiation of UV-LED could be utilised for the degradation of organic dyes

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