scholarly journals Ordered Array of Metal Particles on Semishell Separated with Ultrathin Oxide: Fabrication and SERS Properties

Coatings ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 20
Author(s):  
Xianglin Li ◽  
Zhiwei Wang ◽  
Chiew Tan ◽  
Zexiang Shen ◽  
Alfred Tok
Keyword(s):  
Self Assembly ◽  
Field Enhancement ◽  
Atomic Layer ◽  
Metal Particles ◽  
Simple Method ◽  
Solar Water Splitting ◽  
Plasmonic Structure ◽  
Ordered Array ◽  
Order Of Magnitude ◽  
Local Electric Field Enhancement

Metal particles in gap cavities provide an interesting system to achieve hybrid local surface plasmon modes for local field enhancement. Here, we demonstrate a relatively simple method to fabricate Ag nanoparticles positioned on Ag semishells separated by a thin (~5 nm) dielectric layer. The obtained structure can provide strong local electric field enhancement for surface-enhanced Raman scattering (SERS). The fabrication of the ordered array structure was realized by nanosphere self-assembly, atomic layer deposition, and metal thin-film dewetting. Numerical simulation proved that, compared to the conventional metal semishell arrays, the additional Ag particles introduce extra hot spots particularly in the valley regions between adjacent Ag semishells. As a result, the SERS enhancement factor of the metal semishell-based plasmonic structure could be further improved by an order of magnitude. The developed novel plasmonic structure also shows good potential for application in plasmon-enhanced solar water-splitting devices.

Scanning-tunneling spectroscopy on conjugated polymer films

2003 ◽  
Vol 771 ◽  
Author(s):  
M. Kemerink ◽  
S.F. Alvarado ◽  
P.M. Koenraad ◽  
R.A.J. Janssen ◽  
H.W.M. Salemink ◽  
...  
Keyword(s):  
Polymer Films ◽  
Conjugated Polymer ◽  
Three Dimensional ◽  
Field Enhancement ◽  
Direct Consequence ◽  
Scanning Tunneling Spectroscopy ◽  
Tunneling Spectroscopy ◽  
Band Alignment ◽  
Scanning Tunneling ◽  
Order Of Magnitude

AbstractScanning-tunneling spectroscopy experiments have been performed on conjugated polymer films and have been compared to a three-dimensional numerical model for charge injection and transport. It is found that field enhancement near the tip apex leads to significant changes in the injected current, which can amount to more than an order of magnitude, and can even change the polarity of the dominant charge carrier. As a direct consequence, the single-particle band gap and band alignment of the organic material can be directly obtained from tip height-voltage (z-V) curves, provided that the tip has a sufficiently sharp apex.

scholarly journals Ultra-high-Q resonances in plasmonic metasurfaces

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
M. Saad Bin-Alam ◽  
Orad Reshef ◽  
Yaryna Mamchur ◽  
M. Zahirul Alam ◽  
Graham Carlow ◽  
...  
Keyword(s):  
Incident Light ◽  
Reducing Power ◽  
Field Enhancement ◽  
Plasmonic Nanostructures ◽  
High Q ◽  
Alternative Material ◽  
Order Of Magnitude ◽  
Wavelength Scale ◽  
Strong Confinement ◽  
Sub Wavelength

AbstractPlasmonic nanostructures hold promise for the realization of ultra-thin sub-wavelength devices, reducing power operating thresholds and enabling nonlinear optical functionality in metasurfaces. However, this promise is substantially undercut by absorption introduced by resistive losses, causing the metasurface community to turn away from plasmonics in favour of alternative material platforms (e.g., dielectrics) that provide weaker field enhancement, but more tolerable losses. Here, we report a plasmonic metasurface with a quality-factor (Q-factor) of 2340 in the telecommunication C band by exploiting surface lattice resonances (SLRs), exceeding the record by an order of magnitude. Additionally, we show that SLRs retain many of the same benefits as localized plasmonic resonances, such as field enhancement and strong confinement of light along the metal surface. Our results demonstrate that SLRs provide an exciting and unexplored method to tailor incident light fields, and could pave the way to flexible wavelength-scale devices for any optical resonating application.

Chiral Molecular Cavities of Calix[4]Crown on Au(111)

2008 ◽  
Vol 8 (11) ◽  
pp. 5702-5707 ◽  
Author(s):  
Ge-Bo Pan ◽  
Jun Luo ◽  
Qi-Yu Zheng ◽  
Li-Jun Wan
Keyword(s):  
Self Assembly ◽  
Chiral Recognition ◽  
Scanning Tunneling ◽  
Racemic Mixture ◽  
Tunneling Microscopy ◽  
Geometrical Structures ◽  
Simple Method ◽  
Ordered Structures ◽  
Ordered Arrays ◽  
Stm Images

Well-ordered arrays of chiral molecular cavities have been constructed by self-assembly of inherently chiral calix[4]crown on Au(111) in 0.1 M HClO4 solution and investigated by scanning tunneling microscopy (STM). The chiral features are clearly observed in high resolution STM images. It is found that the adsorption of the two enantiomers results in the same ordered structures with upright orientation on Au(111). Moreover, only phase separation has been observed for the racemic mixture of the two enantiomers in the experiment. This is mainly due to the weak molecule-substrate interaction as well as asymmetric geometrical structures of the two enantiomers. The present study provides a simple method for construction of ordered arrays of chiral molecular cavities, which are of potential in chemical sensors, chiral recognition, and nonlinear optics.

Self-Assembly Based Plasmonic Arrays Tuned by Atomic Layer Deposition for Extreme Visible Light Absorption

Nano Letters ◽  
2013 ◽  
Vol 13 (7) ◽  
pp. 3352-3357 ◽  
Author(s):  
Carl Hägglund ◽  
Gabriel Zeltzer ◽  
Ricardo Ruiz ◽  
Isabell Thomann ◽  
Han-Bo-Ram Lee ◽  
...  
Keyword(s):  
Atomic Layer Deposition ◽  
Visible Light ◽  
Light Absorption ◽  
Self Assembly ◽  
Atomic Layer ◽  
Visible Light Absorption ◽  
Layer Deposition

scholarly journals Switchable reflection/transmission utilizing polarization on a plasmonic structure consisting of self-assembly polystyrene spheres with silver patches

2017 ◽  
Vol 25 (8) ◽  
pp. 9502 ◽  
Author(s):  
Rong-Yuan Zou ◽  
Jun-Xian Shi ◽  
Hong-Kai Dai ◽  
Hong-Feng Wang ◽  
Lin-Yong Qian ◽  
...  
Keyword(s):  
Self Assembly ◽  
Polystyrene Spheres ◽  
Plasmonic Structure

Impurity and Stoichiometry Control in Atomic Layer Epitaxy

1992 ◽  
Vol 262 ◽  
Author(s):  
H. Yokoyama ◽  
K. Ikuta ◽  
N. Inoue
Keyword(s):  
Point Defects ◽  
Resonant Tunneling ◽  
Room Temperature ◽  
Defect Density ◽  
Atomic Layer ◽  
Negative Resistance ◽  
Atomic Layer Epitaxy ◽  
Tunneling Diode ◽  
Order Of Magnitude ◽  
Stoichiometry Control

ABSTRACTWe investigate the intrinsic point defects in epilayers grown by atomic layer epitaxy (ALE). Ga vacancies and antisite As atoms in the epilayers are detected by photoluminescence spectroscopy. This shows that the ALE epilayer was grown under As-rich conditions. We propose increasing the TMG flux to reduce the number of point defects. With this method, the number of point defects in ALE epilayers can be decreased to less than that in conventionally grown epilayers. Moreover, it is'found that these point defects are formed by the incomplete Ga coverage, not by the steric hindrance as previously suggested. The carbon concentration is decreased by one order of magnitude by using nitrogen instead of hydrogen as the carrier gas. As an application of this low defect density, we fabricated a GaAs/AlAs resonant tunneling diode and observed the negative resistance at room temperature.

Water Droplet Self-Assembly to Au Nanoporous Films with Special Light Trapping and Surface Electromagnetic Field Enhancement

Langmuir ◽  
2018 ◽  
Vol 34 (47) ◽  
pp. 14124-14133 ◽  
Author(s):  
Vanessa H. Fragal ◽  
Elizângela H. Fragal ◽  
Adley F. Rubira ◽  
Rafael Silva
Keyword(s):  
Electromagnetic Field ◽  
Self Assembly ◽  
Water Droplet ◽  
Light Trapping ◽  
Field Enhancement ◽  
Nanoporous Films

scholarly journals Large-area printing of ferroelectric surface and super-domains for efficient solar water splitting

2020 ◽  
Author(s):  
Yu Tian ◽  
Yaqing Wei ◽  
Minghui Pei ◽  
Rongrong Cao ◽  
Zhenao Gu ◽  
...  
Keyword(s):  
Water Splitting ◽  
Electric Fields ◽  
Electronic Structures ◽  
Active Sites ◽  
Large Area ◽  
Solar Water Splitting ◽  
High Efficient ◽  
Catalytic Sites ◽  
Order Of Magnitude ◽  
Magnitude Increase

Abstract Surface electronic structures of the photoelectrodes determine the activity and efficiency of the photoelectrochemical water splitting, but the controls of their surface structures and interfacial chemical reactions remain challenging. Here, we use ferroelectric BiFeO3 as a model system to demonstrate an efficient and controllable water splitting reaction by large-area constructing the hydroxyls-bonded surface. The up-shift of band edge positions at this surface enables and enhances the interfacial holes and electrons transfer through the hydroxyl-active-sites, leading to simultaneously enhanced oxygen and hydrogen evolutions. Furthermore, printing of ferroelectric super-domains with microscale checkboard up/down electric fields separates the distribution of reduction/oxidation catalytic sites, enhancing the charge separation and giving rise to an order of magnitude increase of the photocurrent. This large-area printable ferroelectric surface and super-domains offer an alternative platform for controllable and high-efficient photocatalysis.

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