scholarly journals Preparation of Magnesia Partially Stabilized Zirconia Nanomaterials from Zirconium Hydroxide and Magnesium Carbonate Precursors Using PEG as a Template

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 635
Author(s):  
Rizky Berliana Wijayanti ◽  
Irna Rosmayanti ◽  
Kristanto Wahyudi ◽  
Eneng Maryani ◽  
Hernawan Hernawan ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Magnesium Carbonate ◽  
Zirconium Hydroxide ◽  
Morphological Properties ◽  
Average Particle ◽  
Stabilized Zirconia ◽  
Zro2 Content ◽  
Partially Stabilized Zirconia ◽  
Stabilizer Concentration ◽  
M Phase

Stabilized zirconia is a promising material due to its great physical and chemical properties, and thermal stability. In this work, MgO was used as a stabilizer in ZrO2 to obtain Magnesia Partially Stabilized Zirconia (MSZ) nanomaterials assisted with PEG as a template through conventional mixing process. Zirconium hydroxides prepared from local zircon and MgCO3 were used as MSZ precursors. Meanwhile, the stabilizer concentration was varied from 1 to 4 wt% of ZrO2. The effect of the stabilizer concentration and the calcination temperature to the crystallinity and the morphological properties of the MSZ nanoparticles were studied using X-ray diffraction and scanning and transmission electron microscopy. The ZrO2 content in the zirconium hydroxides precursors is accounting 89.52 wt% of the total and exhibits the dominant m-phase at 1000 °C. Meanwhile, the tetragonal and the monoclinic phases were formed in all MSZ samples at a temperature of 800–1000 °C. The as-synthesized MSZ samples show typical FT-IR spectra, consisting of the metal–oxygen bonds at below 500 cm−1 and the organic functional groups ranging at 1000–3000 cm−1. The ZrO2 morphologies exhibit spherical-like shapes with elongated agglomeration at 800 °C. In addition, the average particle sizes of the final product ranges from 20 to 50 nm. At a sintering temperature of 1500 °C, MSZ samples show the monoclinic phase of ZrO2 and densities in the range of 3.95–4.14 g/cm3.

Measurement of the Phase Composition of Partially Stabilized Zirconia (PSZ) Test Parts by X-Ray Powder Diffraction

1989 ◽  
Vol 33 ◽  
pp. 467-474
Author(s):  
R. A. Wewman
Keyword(s):  
Zirconium Oxide ◽  
Ceramic Materials ◽  
Processing Conditions ◽  
Corrosion Wear ◽  
Stabilized Zirconia ◽  
Partially Stabilized Zirconia ◽  
X Ray ◽  
M Phase ◽  
Tetragonal Form ◽  
Low Volume

Zirconia(ZrO2) is one of a number of ceramic materials under development both at Dow and other companies for high cost, low-volume applications under severe corrosion/wear conditions. To improve the physical properties of zirconia, much work has been done worldwide in recent years developing partially stabilized zirconia, or PSZ. This is zirconium oxide which has been “stabilized” in the tetragonal form, typically by the addition of calcium or yttrium oxide. The term “partially stabilized” is given to these materials because the proper amount of oxide stabilizer will cause the zirconia to crystallize almost entirely in the tetragonal form under the proper processing conditions. However, the PSZ fabricated part is not completely stabilized, because it will undergo a tetragonal to monoclinic (T → M) phase transformation when subjected to an applied stress.

scholarly journals Influence of Preaging Temperature on the Indentation Strength of 3Y-TZP Aged in Ambient Atmosphere

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2767
Author(s):  
Ki-Won Jeong ◽  
Jung-Suk Han ◽  
Gi-Uk Yang ◽  
Dae-Joon Kim
Keyword(s):  
Residual Stress ◽  
Phase Transformation ◽  
Low Temperature ◽  
Compressive Residual Stress ◽  
Yttria Stabilized Zirconia ◽  
Ambient Atmosphere ◽  
Aged Specimen ◽  
Stabilized Zirconia ◽  
M Phase ◽  
The Relationship

Yttria-stabilized zirconia (3Y-TZP) containing 0.25% Al2O3, which is resistant to low temperature degradation (LTD), was aged for 10 h at 130–220 °C in air. The aged specimens were subsequently indented at loads ranging from 9.8 to 490 N using a Vickers indenter. The influence of preaging temperature on the biaxial strength of the specimens was investigated to elucidate the relationship between the extent of LTD and the strength of zirconia restorations that underwent LTD. The indented strength of the specimens increased as the preaging temperature was increased higher than 160 °C, which was accompanied by extensive t-ZrO2 (t) to m-ZrO2 (m) and c-ZrO2 (c) to r-ZrO2 (r) phase transformations. The influence of preaging temperature on the indented strength was rationalized by the residual stresses raised by the t→m transformation and the reversal of tensile residual stress on the aged specimen surface due to the indentation. The results suggested that the longevity of restorations would not be deteriorated if the aged restorations retain compressive residual stress on the surface, which corresponds to the extent of t→m phase transformation less than 52% in ambient environment.

A mode of deformation in partially stabilized zirconia

1981 ◽  
Vol 16 (5) ◽  
pp. 1428-1431 ◽  
Author(s):  
R. H. J. Hannink ◽  
M. V. Swain
Keyword(s):  
Stabilized Zirconia ◽  
Partially Stabilized Zirconia

A ceramic based on partially stabilized zirconia: Synthesis, structure, and properties under dynamic load

2011 ◽  
Vol 49 (5) ◽  
pp. 685-689 ◽  
Author(s):  
V. V. Milyavskii ◽  
A. S. Savinykh ◽  
F. A. Akopov ◽  
L. B. Borovkova ◽  
T. I. Borodina ◽  
...  
Keyword(s):  
Dynamic Load ◽  
Structure And Properties ◽  
Stabilized Zirconia ◽  
Partially Stabilized Zirconia

Nitriding of yttria-stabilized zirconia in atmospheric pressure microwave plasma

2009 ◽  
Vol 24 (6) ◽  
pp. 2021-2028 ◽  
Author(s):  
R. Milani ◽  
R.P. Cardoso ◽  
T. Belmonte ◽  
C.A. Figueroa ◽  
C.A. Perottoni ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Atmospheric Pressure ◽  
Microwave Plasma ◽  
Plasma Nitriding ◽  
Nitrided Layer ◽  
Zirconium Nitride ◽  
Stabilized Zirconia ◽  
Partially Stabilized Zirconia ◽  
X Ray ◽  
Yttria Partially Stabilized Zirconia

High temperature plasma nitriding of yttria-partially-stabilized zirconia in atmospheric pressure microwave plasma was investigated. The morphological, mechanical, and physicochemical characteristics of the resulting nitrided layer were characterized by different methods, such as optical and scanning electron microscopy, microindentation, x-ray diffraction, narrow resonant nuclear reaction profiling, secondary neutral mass spectrometry, and x-ray photoelectron spectroscopy, aiming at investigating the applicability of this highly efficient process for nitriding of ceramics. The structure of the plasma nitrided layer was found to be complex, composed of tetragonal and cubic zirconia, as well as zirconium nitride and oxynitride. The growth rate of the nitrided layer, 4 µm/min, is much higher than that obtained by any other previous nitriding process, whereas a typical 50% increase in Vickers hardness over that of yttria-partially-stabilized zirconia was observed.

scholarly journals Commercial Cokes and Graphites as Anode Materials for Lithium - Ion Cells

1997 ◽  
Vol 496 ◽  
Author(s):  
David J. Derwin ◽  
Kim Kinoshita ◽  
Tri D. Tran ◽  
Peter Zaleski
Keyword(s):  
Electron Microscopy ◽  
Ethylene Carbonate ◽  
Average Particle Size ◽  
Chemical Properties ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Bet Surface Area ◽  
Average Particle ◽  
Electrochemical Characteristics ◽  
Wide Range

AbstractSeveral types of carbonaceous materials from Superior Graphite Co. were investigated for lithium ion intercalation. These commercially available cokes, graphitized cokes and graphites have a wide range of physical and chemical properties. The coke materials were investigated in propylene carbonate based electrolytes and the graphitic materials were studied in ethylene carbonate / dimethyl solutions to prevent exfoliation. The reversible capacities of disordered cokes are below 230 mAh / g and those for many highly ordered synthetic (artificial) and natural graphites approached 372 mAh / g (LiC6). The irreversible capacity losses vary between 15 to as much as 200 % of reversible capacities for various types of carbon. Heat treated cokes with the average particle size of 10 microns showed marked improvements in reversible capacity for lithium intercalation. The electrochemical characteristics are correlated with data obtained from scanning electron microscopy (SEM), high resolution transmission electron microscopy (TAM), X - ray diffraction (XRD) and BET surface area analysis. The electrochemical performance, availability, cost and manufacturability of these commercial carbons will be discussed.

Research on Predicting the Stability of Partially Stabilized Zirconia Based on SVM

2010 ◽  
Vol 146-147 ◽  
pp. 460-465 ◽  
Author(s):  
Sheng Hui Guo ◽  
Dong Bo Li ◽  
Li Jun Liu ◽  
Jin Hui Peng ◽  
Li Bo Zhang ◽  
...  
Keyword(s):  
Relative Error ◽  
Influence Factors ◽  
Commercial Application ◽  
Support Vector ◽  
Stabilized Zirconia ◽  
Partially Stabilized Zirconia ◽  
Typical Data ◽  
Svm Model ◽  
Commercial Process ◽  
The Stability

The stability is one most important product performance index, which can directly determine the quality of the partially stabilized zirconia (PSZ), and the stability of PSZ is always fluctuating in the commercial process, so how to accurately, quickly and easily predict the stability of PSZ in the preparation process is very important. In the present paper, a new mathematical model to predict the stability of PSZ was proposed, based on statistical theory (SLT) and support vector machine (SVM) theory, which relates the stability of PSZ and the influence factors, such as the holding temperature, rising rate of temperature, holding time, decreasing rate of temperature and hardening temperature. Typical data collected from commercial process were collected for the training samples and test samples. Then testing and analyzing was done. The results showed that the max relative error was 1.80%, the least relative error was 0%, and the average relative error was 0.58%. It is accurate and reliable to predict the stability of PSZ by SVM model. Besides, multiple influence factors can be comprehensively considered in the SVM model, thus a new highly effective method for predicting the stability of PSZ is provided for commercial application.

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