Corrosive-wear behavior of LSP/MAO treated magnesium alloys in physiological environment with three pH values

A laser shock peening (LSP) layer, a micro-arc oxidation (MAO) coating, and an LSP/MAO composite coating were fabricated on the surface of AZ80 magnesium alloy by laser shock and micro-arc oxidation process. The ball-disc grinding method was used to perform wear test on the three treated specimens in simulated body fluids (SBF) with pH values of 4, 7.4 and 9. The morphology and element content of worn surface were investigated by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The results indicated that the wear rates of the three treated specimens in three pH environment in numerical order were pH 4 > pH 7.4 > pH 9, respectively. The wear rates of the three treated specimens in the same pH environment were arranged in the order of MAO > LSP > LSP/MAO, respectively. The main wear mechanisms of the LSP specimen in pH 4 environment were fatigue wear and corrosion wear, while it were corrosion wear and adhesive wear in pH 7.4 and pH 9 environments. Abrasive wear, fatigue wear and corrosion wear were the main wear mechanisms of the MAO specimen in pH 4 environment, while abrasive wear, adhesive wear and corrosion wear were the main wear mechanisms of that in pH 7.4 and pH 9 environments. The corrosion wear resistance of the LSP/MAO specimen in SBF solution with three pH values was improved due to the synergism of LSP fine crystal layer and MAO coating.

Optimization of Corrosion Wear Resistance of the NiCrBSi Laser-Clad Coatings Fabricated on Ti6Al4V

Ni-based alloy powder (NiCrBSi) was applied to prepare coatings on Ti6Al4V by laser cladding to improve the wear resistance of the latter under corrosion. The scanning speed was found to be an essential parameter that could adjust the microstructure of the coatings. Changes in the microstructures of the coatings with the scanning speed were highlighted, and the relationships between the microstructures and microhardness, fracture toughness, corrosion, and corrosion wear resistance of the coatings were established. Results indicated that the matrix changes from Ti2Ni + TiNi to primary γ(Ni) + eutectics (γ(Ni) + Ni3Ti) with increasing scanning speed. Moreover, reinforcement phases changed from TiB2 + TiC (5 mm∙s−1) to TiB2 + TiC + Cr7C3 (11 mm∙s−1) to TiB2 + TiC + Cr7C3 + CrB (17 mm∙s−1). The average microhardness of the coatings first increased and then decreased, and the corresponding fracture toughness showed the opposite trend. The optimum combination of these properties was observed in the coating prepared at 11 mm∙s−1. This coating demonstrated excellent wear resistance in 3.5 wt.% NaCl solution, as well as a high corrosion potential, a low corrosion current density, and a low current density when the electrode initially entered a comparatively stable corrosion state. Moreover, compared with coatings prepared at other scanning speeds, this coating revealed a higher critical potential for oxidation film destruction. The results of this research collectively show that regulating the microstructures of laser-clad coatings by applying different scanning speeds is a feasible strategy to optimize the wear resistance of the coatings under corrosion.

EXCLUSION OF ACCELERATED CORROSION WEAR BY REPLACING THE CONSTRUCTION MATERIAL

A method of eliminating corrosion due to the presence of hydrogen sulfide by re placing the structural material with a material resistant to the effects of particularly aggressive envi ronments is considered