scholarly journals Luminescent Electrochromic Devices for Smart Windows of Energy-Efficient Buildings

Energies ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 3513 ◽  
Author(s):  
Mariana Fernandes ◽  
Vânia Freitas ◽  
Sónia Pereira ◽  
Rita Leones ◽  
Maria Silva ◽  
...  
Keyword(s):  
Energy Efficient ◽  
Near Infrared ◽  
Sol Gel ◽  
Average Molecular Weight ◽  
The Novel ◽  
Electrochromic Devices ◽  
Lithium Triflate ◽  
Smart Windows ◽  
Energy Efficient Buildings ◽  
Nir Emission

To address the challenges of the next generation of smart windows for energy-efficient buildings, new electrochromic devices (ECDs) are introduced. These include indium molybdenum oxide (IMO), a conducting oxide transparent in the near-infrared (NIR) region, and a NIR-emitting electrolyte. The novel electrolytes are based on a sol-gel-derived di-urethane cross-linked siloxane-based host structure, including short chains of poly (ε-caprolactone) (PCL(530) (where 530 represents the average molecular weight in g mol−1). This hybrid framework was doped with a combination of either, lithium triflate (LiTrif) and erbium triflate (ErTrif3), or LiTrif and bisaquatris (thenoyltrifluoroacetonate) erbium (III) ([Er(tta)3(H2O)2]). The ECD@LiTrif-[Er(tta)3(H2O)2] device presents a typical Er3+ NIR emission around 1550 nm. The figures of merit of these devices are high cycling stability, good reversibility, and unusually high coloration efficiency (CE = ΔOD/ΔQ, where Q is the inserted/de-inserted charge density). CE values of −8824/+6569 cm2 C−1 and −8243/+5200 cm2 C−1 were achieved at 555 nm on the 400th cycle, for ECD@LiTrif-ErTrif3 and ECD@LiTrif-[Er(tta)3(H2O)2], respectively.

scholarly journals Greyscale and Paper Electrochromic Polymer Displays by UV Patterning

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 267 ◽  
Author(s):  
Robert Brooke ◽  
Jesper Edberg ◽  
Xavier Crispin ◽  
Magnus Berggren ◽  
Isak Engquist ◽  
...  
Keyword(s):  
Uv Light ◽  
Low Cost ◽  
Color Space ◽  
Optical Memory ◽  
Electrochromic Devices ◽  
Smart Windows ◽  
Energy Efficient Buildings ◽  
Oxidant Concentration ◽  
High Resolution Images ◽  
Vapor Phase Polymerization

Electrochromic devices have important implications as smart windows for energy efficient buildings, internet of things devices, and in low-cost advertising applications. While inorganics have so far dominated the market, organic conductive polymers possess certain advantages such as high throughput and low temperature processing, faster switching, and superior optical memory. Here, we present organic electrochromic devices that can switch between two high-resolution images, based on UV-patterning and vapor phase polymerization of poly(3,4-ethylenedioxythiophene) films. We demonstrate that this technique can provide switchable greyscale images through the spatial control of a UV-light dose. The color space was able to be further altered via optimization of the oxidant concentration. Finally, we utilized a UV-patterning technique to produce functional paper with electrochromic patterns deposited on porous paper, allowing for environmentally friendly electrochromic displays.

scholarly journals Sol-Gel Coatings for Electrochromic Devices

1992 ◽  
Vol 276 ◽  
Author(s):  
M. A. Macedo ◽  
L. H. Dall'Antonia ◽  
M. A. Aegerter
Keyword(s):  
Heat Treatment ◽  
Sol Gel ◽  
Radiant Energy ◽  
Electrochromic Devices ◽  
Smart Windows ◽  
Ito Glass ◽  
Sol Gel Process ◽  
Ion Storage ◽  
Potential Applications ◽  
Transmission And Reflection

ABSTRACTAll solid state electrochromic smart windows with the configuration glass/ITO/WO3/electrolyte/TiO2-CeO2/ITO/glass have been realized. These devices have potential applications in architectural and automotive fields to regulate the transmission and reflection of the radiant energy. The ion storage electrode TiO2–CeO2 have been realized by sol-gel process and its electrochemical properties are studied as a function of various parameters (thickness, heat treatment, etc.). The electrochemical and optical performances of two cells are reported.

Sustainable Dual-Mode Smart Windows for Energy-Efficient Buildings

2019 ◽  
Vol 2 (3) ◽  
pp. 1951-1960 ◽  
Author(s):  
Sílvia C. Nunes ◽  
Sofia M. Saraiva ◽  
Rui F. P. Pereira ◽  
Sónia Pereira ◽  
Maria Manuela Silva ◽  
...  
Keyword(s):  
Energy Efficient ◽  
Dual Mode ◽  
Smart Windows ◽  
Energy Efficient Buildings

scholarly journals A Mini-Review: Pyridyl-Based Coordination Polymers for Energy Efficient Electrochromic Application

2021 ◽  
Vol 9 ◽  
Author(s):  
Shiyou Liu ◽  
Ping Zhang ◽  
Jianjian Fu ◽  
Congyuan Wei ◽  
Guofa Cai
Keyword(s):  
Energy Efficient ◽  
High Performance ◽  
Active Material ◽  
Cycling Stability ◽  
Electrochromic Devices ◽  
Switching Speed ◽  
Smart Windows ◽  
Coloration Efficiency ◽  
Fast Switching ◽  
Application Prospects

Electrochromic devices (ECDs) have a broad range of application prospects in many important energy efficient optoelectronic fields, such as smart windows, anti-glare rearview mirrors, low-energy displays, and infrared camouflage. However, there are some factors restricting their development, such as low coloration efficiency, slow switching speed, and poor cycling stability. Coordination polymer (CP) is a promising active material for the fabrication of high-performance ECD because of its ultrahigh coloration efficiency, fast switching speed, and excellent cycling stability. In this review, current advances of CP in energy efficient ECDs are comprehensively summarized and evaluated. Specifically, the effects of composition, coordination bonding, and microstructure of the bipyridine- and terpyridine-based CP on EC performances are introduced and discussed in detail. Then, the challenges and prospects of this booming field are proposed. Finally, the broad application prospects of the CPs-based EC materials and the corresponding devices are also demonstrated, which hold numerous revolutionary effects over our daily life. Hopefully, this review would provide useful guidance and further promote progress on the electrochromic and other optoelectronic fields.

Improvement of Near-Infrared Persistent Luminescence in Lithium Substituted MgGa2O4:Cr3+ Nanocrystals

2020 ◽  
Vol 15 (5) ◽  
pp. 630-636
Author(s):  
Yue Xu ◽  
Cuiwei Xue ◽  
Shengnan Xue ◽  
Qi Zhu
Keyword(s):  
Oxygen Vacancies ◽  
Near Infrared ◽  
Uv Light ◽  
Sol Gel ◽  
Persistent Luminescence ◽  
Tetrahedral Sites ◽  
Uv Light Irradiation ◽  
Nir Emission ◽  
Gel Processing

Near infrared (NIR) persistent phosphors can exhibit NIR emission for a long period of time after the remove of irradiation, and they have attracted much attention since the demonstration that NIR persistent luminescent nano-sized particles can be used for in vivo imaging. Here, a new NIR persistent luminescence material of lithium substituted MgGa2O4:Cr3+ (termed as MGO:Cr3+, Li+) has been successfully synthesized by sol–gel processing. The MGO:Cr3+, Li+ mainly consists of ∼40–100 nm nanocrystals, which are of single crystalline with excellent crystallinity. Li+ ions occupying the tetrahedral sites (Mg site) does not significantly affect the crystal structure, but it induces a broader band gap. In the processing of substitution for the Mg2+ site by Li+, oxygen vacancies appear that can efficiently store the excited electrons by UV light irradiation and contribute to the improved persistent luminescence. Mg vacancy arising from a higher calcination temperature tends to store visible light, which also contributes to the enhanced afterglow intensity.

Highly Fluorescent Au25-xAgx Nanoclusters Protected with Poly(ethylene glycol) - and Zwitterion-Modified Thiolate Ligands

2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi
Keyword(s):  
Quantum Yield ◽  
Near Infrared ◽  
Small Diameter ◽  
Binding Energies ◽  
Thiolate Ligands ◽  
Nir Emission ◽  
Thiolate Complexes ◽  
Long Lifetime ◽  
Poly Ethylene

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>

THE ASSESSMENT OF NOISE GENERATED BY HEAT PUMPS INSTALLED OUTDOORS

Akustika ◽  
2020 ◽  
pp. 2-7
Author(s):  
Marián Flimel
Keyword(s):  
Present Article ◽  
Energy Efficient ◽  
Heat Pumps ◽  
Assessment Methods ◽  
Secondary Effect ◽  
Renewable Sources ◽  
Time Exposure ◽  
Energy Efficient Buildings ◽  
Important Position

Energy-efficient buildings utilise the potential of renewable sources, among which heat pumps hold an important position. As this technology has a secondary effect on the environment through its noise immission, locations of outdoor units in the exterior should be subjected to the assessment. The present article deals with the options of placing heat pumps in the exterior and the placement assessment methods. The noise burden identification through the assessment of the time exposure is presented in the example of an in situ measurement.

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