scholarly journals Experimental Study on Water Electrolysis Using Cellulose Nanofluid

Fluids ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 166
Author(s):  
Dongnyeok Choi ◽  
Kwon-Yeong Lee

Hydrogen energy is considered to be a future energy source due to its higher energy density as compared to renewable energy and ease of storage and transport. Water electrolysis is one of the most basic methods for producing hydrogen. KOH and NaOH, which are currently used as electrolytes for water electrolysis, have strong alkalinity. So, it cause metal corrosion and can be serious damage when it is exposed to human body. Hence, experiments using cellulose nanofluid (CNF, C6H10O5) as an electrolyte were carried out to overcome the disadvantages of existing electrolytes and increase the efficiency of hydrogen production. The variables of the experiment were CNF concentration, anode material, voltage applied to the electrode, and initial temperature of the electrolyte. The conditions showing the optimal hydrogen production efficiency (99.4%) within the set variables range were found. CNF, which is not corrosive and has high safety, can be used for electrolysis for a long period of time because it does not coagulate and settle over a long period of time unlike other inorganic nanofluids. In addition, it shows high hydrogen production efficiency. So, it is expected to be used as a next-generation water electrolysis electrolyte.

Hydrogen ◽  
2021 ◽  
Vol 2 (1) ◽  
pp. 122-133
Author(s):  
Aleksey A. Vedyagin ◽  
Ilya V. Mishakov ◽  
Denis V. Korneev ◽  
Yury I. Bauman ◽  
Anton Yu. Nalivaiko ◽  
...  

Owing to the high hydrogen content, hydrocarbons are considered as an alternative source for hydrogen energy purposes. Complete decomposition of hydrocarbons results in the formation of gaseous hydrogen and solid carbonaceous by-product. The process is complicated by the methane formation reaction when the released hydrogen interacts with the formed carbon deposits. The present study is focused on the effects of the reaction mixture composition. Variations in the inlet hydrogen and methane concentrations were found to influence the carbon product’s morphology and the hydrogen production efficiency. The catalyst containing NiO (82 wt%), CuO (13 wt%), and Al2O3 (5 wt%) was prepared via a mechanochemical activating procedure. Kinetics of the catalytic process of hydrocarbons decomposition was studied using a reactor equipped with McBain balances. The effects of the process parameters were explored in a tubular quartz reactor with chromatographic analysis of the outlet gaseous products. In the latter case, the catalyst was loaded piecemeal. The texture and morphology of the produced carbon deposits were investigated by nitrogen adsorption and electron microscopy techniques.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Fu Sun ◽  
Jingshan Qin ◽  
Zhiyu Wang ◽  
Mengzhou Yu ◽  
Xianhong Wu ◽  
...  

AbstractSeawater electrolysis represents a potential solution to grid-scale production of carbon-neutral hydrogen energy without reliance on freshwater. However, it is challenged by high energy costs and detrimental chlorine chemistry in complex chemical environments. Here we demonstrate chlorine-free hydrogen production by hybrid seawater splitting coupling hydrazine degradation. It yields hydrogen at a rate of 9.2 mol h–1 gcat–1 on NiCo/MXene-based electrodes with a low electricity expense of 2.75 kWh per m3 H2 at 500 mA cm–2 and 48% lower energy equivalent input relative to commercial alkaline water electrolysis. Chlorine electrochemistry is avoided by low cell voltages without anode protection regardless Cl– crossover. This electrolyzer meanwhile enables fast hydrazine degradation to ~3 ppb residual. Self-powered hybrid seawater electrolysis is realized by integrating low-voltage direct hydrazine fuel cells or solar cells. These findings enable further opportunities for efficient conversion of ocean resources to hydrogen fuel while removing harmful pollutants.


2019 ◽  
Vol 118 ◽  
pp. 03021 ◽  
Author(s):  
Yanmei Yang ◽  
Geng Wang ◽  
Ling Lin ◽  
Sinan Zhang

Hydrogen energy is becoming more and more blooming because of its diversified sources, eco-friendly and green, easy storage and transportation, high-efficient utilization, etc. The use of hydrogen as an energy carrier is expected to grow over the next decades. Hydrogen, like electricity, is a secondary energy. Hydrogen production is the foundation for all kinds of applications. Based on the resources situation in China, potential of hydrogen production is analysed. China has a large potential of hydrogen production from coal, which is about 2.438 billion tons. Potential of hydrogen production from natural gas is less than that from coal, which is about 501 million tons. According to the average consumption of methanol per year, potential of hydrogen production from methanol is about 690, 000 tons per year. Potential of hydrogen production from industrial gas (coking, petrochemical and chlor-alkali industries) is about 866, 400 tons per year. Potential of hydrogen production from abandoned renewable energy power is about 1798.2 million tons per year. Distribution of resources in China differs among provinces. The deployment of hydrogen industry should pay attention to local hydrogen production potential. A green hydrogen production method, such as water electrolysis by renewable energy power, is a promising and environmental friendly way.


2019 ◽  
Vol 14 (3) ◽  
pp. 645-651 ◽  
Author(s):  
Mitsuru Higa ◽  
Takeshi Watanabe ◽  
Masahiro Yasukawa ◽  
Nobutaka Endo ◽  
Yuriko Kakihana ◽  
...  

Abstract A pilot-scale sustainable hydrogen production system using reverse electrodialysis (RED) technology was launched. The system is based on direct conversion of salinity gradient energy (SGE) between seawater (SW) and sewage treated water (STW) to hydrogen production by water electrolysis. The hydrogen production rate was almost the same as the theoretical value. This indicates that the RED hydrogen production system can convert SGE between SW and STW to hydrogen energy at high current efficiency.


RSC Advances ◽  
2020 ◽  
Vol 10 (48) ◽  
pp. 28848-28855 ◽  
Author(s):  
Wenbo Liu ◽  
Zhendong Zhang ◽  
Deguang Zhang ◽  
Runwei Wang ◽  
Zongtao Zhang ◽  
...  

Curled carbon nitride nanosheets with narrow-band gap for ultra-high hydrogen production efficiency.


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