scholarly journals Spatial Distributions, Sources, Potential Risks of Multi-Trace Metal/Metalloids in Street Dusts from Barbican Downtown Embracing by Xi’an Ancient City Wall (NW, China)

2019 ◽  
Vol 16 (16) ◽  
pp. 2992 ◽  
Author(s):  
Xiaoping Li ◽  
Bin Liu ◽  
Yu Zhang ◽  
Jiwen Wang ◽  
Hameed Ullah ◽  
...  
Keyword(s):  
Trace Metals ◽  
Health Risk ◽  
Trace Metal ◽  
Health Risks ◽  
Ecological Risk ◽  
Carcinogenic Risk ◽  
Anthropogenic Sources ◽  
City Wall ◽  
Ancient City ◽  
Brake Wear

A total of 116 dust samples in downtown within the city wall were collected, and the spatial occurrence, source and health risk status of 19 trace metal/metalloids bound in street dusts (SDs) were systematically investigated. Geochemical maps, associations, risk models and indices were calculated to define levels of distribution, possible natural or anthropogenic sources, ecological and human health risks. It was found that the wide variations of these 19 trace metals would be observed in spatial maps, which indicated strongly anthropogenic activities inputs. Compared to the calculations of the potential ecological risk index of toxic trace metals, Pb (Eri = 20.32) ranked at the level of considerable ecological risk. The non-carcinogenic and carcinogenic risk from most trace metals exposed to children and adults were no significant health risks, except for the non-carcinogenic risk of Cr and As to children, and the carcinogenic risk of Cr to adults. The unacceptable risk locations were observed at traffic conjunctions, which should be given attention. The source apportionment results indicated that the trace metals/metalloids Co, Ga, Nb, As, Ni, and Y, coupled with main elements Al, K, Mg, Ca and Si, would possibly originate from “Soil Re-suspension”, whereas Fe, Cu, Rb, La, Ba, Mn, Ti, Ce and Zr were possibly derived from “Brake Wear”. As regards the Na, no valid assumption was formulated about the presence of this element in brake wear, while Cr, Sr, Zn were possibly associated with “Tire Wear”. Comparatively, V would be suggested as a representative source of fuel consumption, and Pb could possibly belong to “Traffic Pigment”. It was noted that the barbican city, surrounded by the Xi’an Ancient City Wall at 12 m high, would trap the trace metal emissions, and consequently increase the health risk for local residents.

scholarly journals Potential Ecological Risk and Health Risk Assessment of Heavy Metals and Metalloid in Soil around Xunyang Mining Areas

2019 ◽  
Vol 11 (18) ◽  
pp. 4828 ◽  
Author(s):  
Na Wang ◽  
Jichang Han ◽  
Yang Wei ◽  
Gang Li ◽  
Yingying Sun
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Health Risk ◽  
Human Health ◽  
Health Risks ◽  
Ecological Risk ◽  
Potential Ecological Risk ◽  
Carcinogenic Risk ◽  
Mining Areas ◽  
Metals And Metalloid

Xunyang is rich in various metal minerals and is one of the four major metal mining areas in Shaanxi province, China. To explore the effects of soil heavy metals and metalloid pollution on the environment and human health around the mining areas, four places—Donghecun (D), Gongguan (G), Qingtonggou (Q) and Nanshagou (N)—were selected as the sampling sites. Potential ecological risk (PER) and health risk assessment (HRA) models were used to analyze the environmental and health risks around the mining areas. The concentration of heavy metals (Cd, Cr, Pb, Zn, Ni, Cu, Hg) and metalloid (As) in cultivated land in the vicinity of Xunyang mining areas indicated that, except for Cu, the remaining elements detected exceeded the threshold values at some sites. The geo-accumulation index (IGeo) revealed that soils in G and Q could be identified as being extremely contaminated. PER indicated that there was significantly high risk at G and Q for Hg. In N, Pb recorded the highest E r i , which also demonstrates a considerable pre-existing risk. HRA indicated that the hazard index (HI) for both carcinogenic and non-carcinogenic risks was much higher among children than among adults, and the ingestion pathway contributed the greatest risk to human health, followed by the dermal pathway and inhalation. Because the HI values of the metals and metalloid in the study areas were all lower than 1, there was no significant non-carcinogenic risk. However, the carcinogenic risk for Cr is relatively higher, surpassing the tolerable values in G, Q, and N. This study analyzed the ecological risks and human health risks of heavy metals and metalloid in farmland soils near the sampling mining areas, and demonstrated the importance of environmental changes caused by land development in the mining industry.

scholarly journals Trace Metal Residues in Swimming Warrior Crab Callinectes bellicosus: A Consumption Risk

2021 ◽  
Vol 9 ◽  
Author(s):  
Marisol Castro-Elenes ◽  
G. Durga Rodríguez-Meza ◽  
Ernestina Pérez-González ◽  
Héctor A. González-Ocampo
Keyword(s):  
Trace Metals ◽  
Health Risk ◽  
Trace Metal ◽  
Coastal Lagoon ◽  
Hazard Quotient ◽  
Carcinogenic Risk ◽  
Target Hazard Quotient ◽  
Tissue Samples ◽  
Edible Tissue ◽  
Edible Tissues

This study was carried out in the Navachiste coastal lagoon, Mexico, surrounded by intensive agricultural and aquaculture activities that cause environmental pollution by the deposition of trace metal residues in the sediments of this coastal lagoon. The trace metals are bioaccumulated by benthic organisms such as the blue swimming warrior crab, Callinectes bellicosus, which inhabits this lagoon and is consumed by humans. Ninety-five C. bellicosus edible tissue samples were collected (April 2014–January 2015). The extraction procedure of the trace metals in edible tissue samples was carried out by acid digestion with nitric acid. Based on the Environmental Protection Agency (EPA) of the United States, two indices were used to measure health risk: the estimated daily intake (EDI) and the target hazard quotient (THQ). The hazard index (HI) was used to calculate the probability of adverse carcinogenic risk and the target hazard quotient per sample (MHI) to calculate the probability of developing a carcinogenic or non-carcinogenic risk. The analysis of variance (ANOVA) showed significant differences among trace metal concentrations (p < 0.01), but all trace metal concentrations in the edible tissues of C. bellicosus were higher than the maximum residual limits (MRLs). The highest EDI was for Zn, Fe, and Cu, showing that the consumption of these crabs might represent health risks. The THQ >1 was for Ni, Zn, Cd, and Cu, and the HI = 16 revealed the risk of C. bellicosus for high-level consumers. The MHI showed that 98% of samples presented a THQ >1, implying a high rate of bioaccumulation of trace metals by the crabs independent of the sampling site in the NAV. The presence of trace metals in the edible tissue of crabs reflects contamination by trace metals, and the indices results mean that the NAV lagoon is constantly polluted with trace metal residues by neighboring agriculture and aquaculture activities. These trace metal residues are being bioaccumulated in the edible tissues of C. bellicosus due to its feeding habits, resulting in a health risk if its consumption is high, including carcinogenic and non-carcinogenic risks.

scholarly journals Quantitative analysis of ecological risk and human health risk of potentially toxic elements in farmland soil based on PMF model

2021 ◽  
Author(s):  
Chang-Chen Haung ◽  
Li-mei Cai ◽  
Yao-Hui Xu ◽  
Han-Hui Wen ◽  
Jie Luo ◽  
...  
Keyword(s):  
Health Risk ◽  
Human Health ◽  
Health Risks ◽  
Ecological Risk ◽  
Toxic Elements ◽  
Human Health Risk ◽  
Carcinogenic Risk ◽  
Potentially Toxic Elements ◽  
Human Health Risks ◽  
Farmland Soil

In this research, enrichment factor (EF) and pollution load index (PLI) were utilized to estimate the features of enrichment and contamination of PTEs in farmland soil. Furthermore, combining the spatial distribution characteristics of potentially toxic elements (PTEs) and positive matrix factorization (PMF) to distinguish and quantify the sources of PTEs in farmland soil, and then the potential ecological risk (PER) and human health risk (HHR) model based on PMF are applied to quantify the ecological and human health risks from different sources. Taking Puning District as an example, four sources of PTEs in farmland soil were quantitatively allocated. For ecological risk, the study area is at moderate ecological hazard level, and industrial activities were the greatest contributor. The mean E_r^i of Hg were 69.82, reaching medium ecological risk level. For human health risks, both adults and children have no evident non-carcinogenic risk in the study area. And natural source was the largest contributor to non-carcinogenic risk, followed by agricultural activities. With regard to carcinogenic risk, tolerable risks of soil PTEs in the study area were limited not only for adults but also for children. Furthermore, compared with adults, the health risks of children, whether non-carcinogenic or carcinogenic, were higher than those of adults, and the trends in health risks for children and adults were similar. A comprehensive scheme combining source contribution and risk assessment is conducive to quantitatively assess ecological risks, health risks and priority pollution sources, thereupon provide effective suggestions for protecting human health and preventing and controlling pollution.

scholarly journals Geophagic Clays from Cameroon: Provenance, Metal Contamination and Health Risk Assessment

2021 ◽  
Vol 18 (16) ◽  
pp. 8315
Author(s):  
Georges-Ivo Ekosse ◽  
George Elambo Nkeng ◽  
Nenita Bukalo ◽  
Olaonipekun Oyebanjo
Keyword(s):  
Health Risk ◽  
Inductively Coupled Plasma ◽  
Risk Index ◽  
Human Health Risk ◽  
Carcinogenic Risk ◽  
Anthropogenic Sources ◽  
Contamination Assessment ◽  
X Ray ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

This study assessed the mineralogical and geochemical characteristics of geophagic clays sold in some markets in Cameroon to ascertain their provenance, contamination status and human health risk. To achieve this, 40 samples from 13 markets in Cameroon were purchased and analysed using X-ray diffractometry, X-ray fluorescence and laser ablation inductively coupled plasma mass spectrometry for their mineralogy and geochemistry, respectively. The geophagic clays were dominantly made up of kaolinite and quartz. Their chemistry was dominated by SiO2, Al2O3 and LOI with means of 48.76 wt%, 32.12 wt% and 13.93 wt%, respectively. The major, trace and rare earth elements data showed that these geophagic clays were predominantly derived from felsic rocks. The contamination assessment indicated no enrichment of metals from anthropogenic sources, except for Zn in samples from Acacia, Madagascar and Mfoudi markets. The index of geo-accumulation indicated no contamination to moderate contamination of the clays. The non-carcinogenic index values for Fe, Co, Cr, Cu, Ni, Pb and Zn were generally less than 1, suggesting no non-carcinogenic risk exposure to children and adults consuming the geophagic clays from these metals. The carcinogenic risk index (TCR) for Ni and Cr were above 10−6, which implies that children and adults are vulnerable to minimal carcinogenic health risk. The TCR values from Ni posed the highest risk, especially to children consuming clays from some markets.

scholarly journals Human Health Risk Distribution and Safety Threshold of Cadmium in Soil of Coal Chemical Industry Area

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 678
Author(s):  
Kai Zhang ◽  
XiaoNan Li ◽  
ZhenYu Song ◽  
JiaYu Yan ◽  
MengYue Chen ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Health Risk ◽  
Human Health ◽  
Health Risks ◽  
Chemical Industry ◽  
Human Health Risk ◽  
Oral Intake ◽  
Carcinogenic Risk ◽  
Kriging Interpolation Method ◽  
Industry Area

Cadmium (Cd) is a highly carcinogenic metal that plays an important role in the risk management of soil pollution. In this study, 153 soil samples were collected from a coal chemical plant in northwest China, and the human health risks associated with Cd were assessed through multiple exposure pathways. Meanwhile, by the Kriging interpolation method, the spatial distribution and health risks of Cd were explored. The results showed that the average concentration of Cd in the soil was 0.540 mg/kg, which was 4.821 and 5.567 times that of the soil background value in Ningxia and China, respectively. In comparison, the concentration of Cd in the soil was below the national soil environmental quality three-level standard (1.0 mg/kg). In addition, health risk assessment results showed that the total carcinogenic risk of Cd was 1.269 × 10−6–2.189 × 10−6, both above the acceptable criteria (1 × 10−6), while the hazard quotient was within the acceptable level. Oral intake and ingestion of soil particles were the main routes of exposure, and the carcinogenic risk control value of oral intake was the lowest (0.392 mg/kg), which could be selected as the strict reference of the safety threshold for Cd in the coal chemical soil. From Kriging, a prediction map can be centrally predicted on heavy metal pollution in the area surrounding the coal entrance corridor and pedestrian entrance. This study can provide a theoretical basis for the determination of the heavy metal safety threshold of the coal chemical industry in China.

scholarly journals Health Assessment of Trace Metal Concentrations in Organic Fertilizer in Northern China

2019 ◽  
Vol 16 (6) ◽  
pp. 1031 ◽  
Author(s):  
Qiong Gong ◽  
Peizhen Chen ◽  
Rongguang Shi ◽  
Yi Gao ◽  
Shun-An Zheng ◽  
...  
Keyword(s):  
Trace Metals ◽  
Trace Metal ◽  
Metal Accumulation ◽  
Organic Fertilizer ◽  
Health Assessment ◽  
Simulation Models ◽  
Northern China ◽  
Carcinogenic Risk ◽  
Organic Fertilizers ◽  
Exposure Pathway

The application of organic fertilizer could be accompanied by potential hazards to soil and humans caused by trace metals. A wide survey of organic fertilizers was carried out in northern China. A total of 117 organic fertilizer samples were collected to analyze the concentrations of seven trace metals. Simulation models were used to estimate the trace metal accumulation risk in soil and non-carcinogenic and carcinogenic risks to the human body. The concentrations of trace metals varied widely (Cr: 2.74–151.15; Ni: 2.94–49.35; Cu: 0.76–378.32; Zn: 0.50–1748.01; As: 1.54–23.96; Cd: 2.74–151.15; and Pb: 1.60–151.09 mg·kg−1). Chinese organic fertilizer standard limits were exceeded by0.85% for Cr, 5.98% for As, 1.71% for Cd, and 4.27% for Pb. Monte Carlo simulations showed that repeated application of organic fertilizer likely significantly increased the concentrations of Zn, Cd, and As in soil compared with the soil background levels according to the Soil Environmental Quality Standards of China. As and Cr pose high risks to human health, especially as carcinogenic risk factors with a skin exposure pathway. Reducing the content of Cr, Cu, Zn, As, and Cd in organic fertilizer would be of great significance for minimizing the damage caused by trace metals.

scholarly journals Simultaneous Health Risk Assessment of Potentially Toxic Elements in Soils and Sediments of the Guishui River Basin, Beijing

2019 ◽  
Vol 16 (22) ◽  
pp. 4539
Author(s):  
Jiankang Wang ◽  
Bo Gao ◽  
Shuhua Yin ◽  
Dongyu Xu ◽  
Laisheng Liu ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Health Risk ◽  
River Basin ◽  
Health Risk Assessment ◽  
Health Risks ◽  
Ecological Risk ◽  
Toxic Elements ◽  
Potentially Toxic Elements ◽  
Soils And Sediments ◽  
Basin Scale

Simultaneous ecological and health risk assessments of potentially toxic elements in soils and sediments can provide substantial information on their environmental influence at the river-basin scale. Herein, soil and sediment samples were collected from the Guishui River basin to evaluate the pollution situation and the ecological and health risk of potentially toxic elements. Various indexes were utilized for quantitatively assessing their health risks. Pollution assessment by geo-accumulation index showed that Cd had “uncontaminated to moderately polluted” status in the soils and sediments. Potential ecological risk index showed that the Guishui River basin was at low risk in general, but Cd was classified as “moderate or considerable ecological risk” both in the soils and sediments. Health risk assessment calculated human exposure from soils and indicated that both non-carcinogenic and carcinogenic risks of the selected potentially toxic elements were lower than the acceptable levels. Health risks posed by potentially toxic elements bio-accumulated in fish, stemming from sediment resuspension, were also assessed. Non-carcinogenic hazard index indicated no adverse health effects on humans via exposure to sediments; however, in general, Cr contributed largely to health risks among the selected potentially toxic elements. Therefore, special attention needs to be paid to the Guishui River basin in the future.

Application of two different health risk assessment approaches to detect soil potentially toxic element induced risk

2020 ◽  
Author(s):  
Gevorg Tepanosyan ◽  
Lilit Sahakyan ◽  
Armen Saghatelyan
Keyword(s):  
Risk Assessment ◽  
Health Risk ◽  
Health Risk Assessment ◽  
Pollution Index ◽  
Copper Smelter ◽  
Carcinogenic Risk ◽  
Soil Samples ◽  
Anthropogenic Sources ◽  
Us Epa ◽  
The City

<p>Soils of urbanized and mining areas succeeded the main geochemical features of parent materials, as well as accumulate potentially toxic elements (PTE) from different anthropogenic sources. The latter resulted in the change of soil chemical composition and high level of PTE which may have negative reflection on people’s health. In this study 207 soil samples were collected from the entire territory of the city of Alaverdi hosting Alaverdi copper smelter. After the determination of Fe, Ba, Mn, Co, V, Pb, Zn, Cu, Cr, As and Mo concentrations by XRF the established data set was subjected for the PTE induced health risk assessment. In this study two commonly used health risk assessment approaches - Summary pollution index (Zc) [1]–[3] and Hazard Index (HI, US EPA) [4] were used to assess human health risk posed by the content of studied PTE in soil of Alaverdi city. The result showed that the detected concentrations are mainly the result of superposition of PTE contents introduced into the environment from natural mineralization processes and Alaverdi copper smelter related activities. The health risk assessment showed that the Zc values belonging to the extremely hazardous level has point-like shape and are surrounded by the hazardous and moderately hazardous levels, respectively. Summary pollution index showed that approximately 53 % of the city territory including the residential part is under the risk suggesting the increase in the overall incidence of diseases among frequently ill individuals, functional disorders of the vascular system and children with chronic diseases [1]. The US EPA method were in line with the results of the Zc and indicated that the observed contents of elements are posing non-carcinogenic risk to adult mainly near the copper smelter. In the case of children single-element non-carcinogenic risk values greater than 1 were detected for As, Fe, Co, Cu, Mn, Pb and Mo in 122, 95, 86, 10, 10, 9 and 6 samples out of 207 soil samples and the mean HQ values decrease in the following order: As(2.41)>Fe(1.14)>Co(1.09)> Mn(0.61)>Pb(0.41)>Cu(0.32)>V(0.19)>Mo(0.11)>Cr(0.05)>Ba(0.03)>Zn(0.02). The multi-elemental non-carcinogenic risk observed in the entire territory of the city indicating an adverse health effect to children. The results of this study suggesting the need of immediate risk reduction measures with special attention to arsenic.</p><p><strong>References:</strong></p><p>[1]         E. K. Burenkov and E. P. Yanin, “Ecogeochemical investigations in IMGRE: past, present, future,” Appl. Geochemistry, vol. 2, pp. 5–24, 2001.</p><p>[2]         C. C. Johnson, A. Demetriades, J. Locutura, and R. T. Ottesen, Mapping the Chemical Environment of Urban Areas. 2011.</p><p>[3]         Y. E. Saet, B. A. Revich, and E. P. Yanin, Environmental geochemistry. Nedra, 1990.</p><p>[4]         RAIS, “Risk Exposure Models for Chemicals User’s Guide,” The Risk Assessment Information System, 2020. [Online]. Available: https://rais.ornl.gov/tools/rais_chemical_risk_guide.html. [Accessed: 01-Jan-2020].</p><p> </p>

scholarly journals Ecological and Health Risk Studies of Heavy Metals in Soils around an Abandoned Battery Factory in Ibadan, Southwestern Nigeria

2020 ◽  
Vol 1 (4) ◽  
Author(s):  
Romanus A. Obasi ◽  
Henry Y. Madukwe
Keyword(s):  
Heavy Metals ◽  
Health Risk ◽  
Enrichment Factor ◽  
Health Risks ◽  
Ecological Risk ◽  
Risk Index ◽  
Hazard Index ◽  
Contamination Factor ◽  
Southwestern Nigeria ◽  
High Enrichment

Heavy metals on the soil around an abandoned battery site at Wofun, Ibadan, Southwestern, Nigeria were studied for their ecological and health risks. Ten soil samples collected from the soil around the abandoned battery sites were analyzed using Inductively Coupled Plasma –Mass spectrometry (ICP-MS). The data were evaluated using indices such as contamination factor, enrichment factor, geo-accumulation index and pollution index to determine the ecological and health risks posed by the heavy metals. The results showed an average concentration of Pb (7274.4), V (190.63), Cu (77.52), Zn (53.08) and Co (53) in a decreasing order. The enrichment factor revealed high enrichment for Co (12.30) at site one (S1), and extreme enrichment of Pb (61.12). Zn, Rb and Mo showed no enrichment in the soil. All the sites exhibited extremely high enrichment of Pb except at S10 where the enrichment of Pb was only severe. The results of Igeo indicated that all the sites were strongly to extremely polluted by Pb while S6 is moderately polluted by Co. The rest of the metals do not constitute any pollution threats. An evaluation of the ecological risk index (RI) revealed that the mean Er for Co (13.95), Cu (8.61), and Zn (0.56) indicate low ecological risk as they are less than 40 (Er <40).  Lead (Pb) with Er value of 1818.60 has a very high ecological risk and accounts for most of the ecological risks in the study area. Lead (Pb) being the most toxic and abundant of all the heavy metals analyzed in the study areas was used to evaluate the potential  non-carcinogenic health risk for both children and adults. The hazard index which is the sum of the hazard quotients for children is 26.64 suggesting that non-carcinogenic health risk may occur if there is any form of exposure to the soil. The hazard index for the adult (2.87) indicated a significant potential non-carcinogenic health risk in the study area.

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