scholarly journals Ohmic Contacts on p-Type Al-Implanted 4H-SiC Layers after Different Post-Implantation Annealings

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3468 ◽  
Author(s):  
Monia Spera ◽  
Giuseppe Greco ◽  
Domenico Corso ◽  
Salvatore Di Franco ◽  
Andrea Severino ◽  
...  
Keyword(s):  
Ohmic Contacts ◽  
Device Fabrication ◽  
Electrical Activation ◽  
Specific Contact Resistance ◽  
Emission Model ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type ◽  
Post Implantation

This paper reports on the electrical activation and Ohmic contact properties on p-type Al-implanted silicon carbide (4H-SiC). In particular, the contacts were formed on 4H-SiC-implanted layers, subjected to three different post-implantation annealing processes, at 1675 °C, 1175 °C, and 1825 °C. Under these post-implantation annealing conditions, the electrical activation of the Al dopant species increased from 39% to 56%. The Ti/Al/Ni contacts showed an Ohmic behavior after annealing at 950 °C. The specific contact resistance ρc could be lowered by a factor of 2.6 with the increase of the post-implantation annealing temperature. The result can be useful for application in device fabrication. Moreover, the dependence of ρc on the active acceptor concentration followed the thermionic field emission model, with a barrier height of 0.63 eV.

Study of Ti/Al/Ni Ohmic Contacts to p-Type Implanted 4H-SiC

2018 ◽  
Vol 924 ◽  
pp. 377-380 ◽  
Author(s):  
Marilena Vivona ◽  
Giuseppe Greco ◽  
Corrado Bongiorno ◽  
Salvatore di Franco ◽  
Raffaella Lo Nigro ◽  
...  
Keyword(s):  
Ohmic Contacts ◽  
Annealing Temperature ◽  
Specific Contact Resistance ◽  
Electrical Characteristics ◽  
Key Factors ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type ◽  
Resistance Value

This work reports on the electrical and microstructural properties of Ti/Al/Ni contacts to p-type implanted 4H-SiC obtained by rapid thermal annealing of a metal stack of Ti (70 nm)/Al (200 nm)/Ni (50 nm). The contact characteristics were monitored at increasing value of the annealing temperature. The Ohmic behavior of the contact, with a specific contact resistance value of 2.3×10-4Ω·cm2, is obtained for an annealing at 950 °C. The structural analyses of the contact, carried out by XRD and TEM, reveal the occurrence of reactions, with the detection of the Al3Ni2and AlTi phases in the upper part of the contact and of an epitaxially oriented TiC layer at the interface. These reactions are considered the key factors in the formation of an Ohmic contact in our annealed Ti/Al/Ni system. The temperature-dependence study of the electrical characteristics reveals a predominant thermionic field emission (TFE) mechanism for the current conduction through the contact, with a barrier height of 0.56 eV.

Current Transport Mechanisms in Au-Free Metallizations for CMOS Compatible GaN HEMT Technology

2020 ◽  
Vol 1004 ◽  
pp. 725-730
Author(s):  
Fabrizio Roccaforte ◽  
Monia Spera ◽  
Salvatore Di Franco ◽  
Raffaella Lo Nigro ◽  
Patrick Fiorenza ◽  
...  
Keyword(s):  
Barrier Height ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Large Area ◽  
Si Substrates ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission

Gallium nitride (GaN) and its AlGaN/GaN heterostructures grown on large area Si substrates are promising systems to fabricate power devices inside the existing Si CMOS lines. For this purpose, however, Au-free metallizations are required to avoid cross contaminations. In this paper, the mechanisms of current transport in Au-free metallization on AlGaN/GaN heterostructures are studied, with a focus on non-recessed Ti/Al/Ti Ohmic contacts. In particular, an Ohmic behavior of Ti/Al/Ti stacks was observed after an annealing at moderate temperature (600°C). The values of the specific contact resistance ρc decreased from 1.6×104 Ω.cm2 to 7×105 Ω.cm2 with increasing the annealing time from 60 to 180s. The temperature dependence of ρc indicated that the current flow is ruled by a thermionic field emission (TFE) mechanism, with barrier height values of 0.58 eV and 0.52 eV, respectively. Finally, preliminary results on the forward and reverse bias characterization of Au-free tungsten carbide (WC) Schottky contacts are presented. This contact exhibited a barrier height value of 0.82 eV.

High Quality Non-Alloyed Pt Ohmic Contacts to P-Type GaN Using Two-Step Surface Treatment

1999 ◽  
Vol 595 ◽  
Author(s):  
Ja-Soon Jang ◽  
Seong-Ju Park ◽  
Tae-Yeon Seong
Keyword(s):  
Surface Treatment ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Transport Mechanisms ◽  
High Quality ◽  
Ammonium Sulfide ◽  
Current Voltage ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

AbstractTwo-step surface-treatment is introduced to obtain low resistance Pt contacts to ptype GaN. The first step is performed after the mesa etching process using buffered oxide etch (BOE) and ammonium sulfide [(NH4)2Sx]. This is followed by the second step using BOE. The Pt contact, which was treated sequentially using ultrasonically boiled BOE (10 min) and boiled (NH4)2Sx (10 min), produces a specific contact resistance of 3.0 (±3.8)×10-5 Ωcm2. However, the contact, that was simply BOE-treated, yields 3.1 (±1.1)×10-2 Ωcm2. This indicates that the two-step surface treatment is promising technique for obtaining high quality ohmic contacts to p-GaN. Investigation of the electronic transport mechanisms using current-voltage-temperature (I-V-T) data indicates that thermionic field emission is dominant in the surface-treated Pt contacts.

Effects of Different Post-Implantation Annealing Conditions on the Electrical Properties of Interfaces to p-Type Implanted 4H-SiC

2012 ◽  
Vol 717-720 ◽  
pp. 825-828
Author(s):  
Alessia Frazzetto ◽  
Fabrizio Roccaforte ◽  
Filippo Giannazzo ◽  
R. Lo Nigro ◽  
M. Saggio ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Electrical Parameters ◽  
Capping Layer ◽  
Annealing Conditions ◽  
Specific Contact ◽  
Activation Annealing ◽  
P Type ◽  
Post Implantation

This paper reports on the effects of different post-implantation annealings on the electrical properties of interfaces to p-type implanted 4H-SiC. The morphology of p-type implanted 4H-SiC was controlled using a capping layer during post-implantation activation annealing of the dopant. Indeed, the surface roughness of Al-implanted regions strongly depends on the use of the protective capping layer during the annealing. However, while the different morphological conditions do not affect the macroscopical electrical properties of the implanted SiC (such as the sheet resistance), they led to an improvement of the morphology and of the specific contact resistance of Ti/Al Ohmic contacts formed on the implanted regions. These electrical and morphologic improvements were associated with a lowering of Schottky barrier height. Preliminary results showed that the different activation annealing conditions of p-type implanted SiC can affect also the electrical parameters (like threshold voltage and mobility) of lateral MOSFETs.

scholarly journals Comparison of Electrical Properties of Ohmic Contact Realized on p-Type 4H-SiC

2008 ◽  
Vol 600-603 ◽  
pp. 639-642
Author(s):  
Duy Minh Nguyen ◽  
Christophe Raynaud ◽  
Mihai Lazar ◽  
Heu Vang ◽  
Dominique Planson
Keyword(s):  
Surface Roughness ◽  
Electrical Properties ◽  
Contact Resistance ◽  
Carrier Mobility ◽  
Ohmic Contacts ◽  
Series Resistance ◽  
Specific Contact Resistance ◽  
Specific Contact ◽  
P Type ◽  
Post Implantation

N+ 4H-SiC commercial substrates with n-type epilayers have been used to realize bipolar diodes and TLM structures. The p-type emitter of diodes was realized by Al implantations followed by a post-implantation annealing with or without a graphite capping layer. Ohmic contacts were formed by depositing Ti/Ni on the backside and Ni/Al on the topside of the wafer. It appears that capping the sample during the annealing reduces considerably the surface roughness and the specific contact resistance. Sheet resistance and specific contact resistance as low as 2kΩ/□ and respectively 1.75×10-4 Ωcm² at 300 K have been obtained. I-V measurements as a function of temperature have been performed from ~100 to ~500 K. The variations of the series resistance vs. temperature can be explained by the freeze-out of carriers and by the variation of carrier mobility.

scholarly journals High Quality Non-Alloyed Pt Ohmic Contacts to P-Type GaN Using Two-Step Surface Treatment

2000 ◽  
Vol 5 (S1) ◽  
pp. 521-527
Author(s):  
Ja-Soon Jang ◽  
Seong-Ju Park ◽  
Tae-Yeon Seong
Keyword(s):  
Surface Treatment ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Transport Mechanisms ◽  
High Quality ◽  
Ammonium Sulfide ◽  
Current Voltage ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

Two-step surface-treatment is introduced to obtain low resistance Pt contacts to p-type GaN. The first step is performed after the mesa etching process using buffered oxide etch (BOE) and ammonium sulfide [(NH4)2Sx]. This is followed by the second step using BOE. The Pt contact, which was treated sequentially using ultrasonically boiled BOE (10 min) and boiled (NH4)2Sx (10 min), produces a specific contact resistance of 3.0 (±3.8)×10−5 Ωcm2. However, the contact, that was simply BOE-treated, yields 3.1 (±1.1)×10−2 Ωcm2. This indicates that the two-step surface treatment is promising technique for obtaining high quality ohmic contacts to p-GaN. Investigation of the electronic transport mechanisms using current-voltage-temperature (I-V-T) data indicates that thermionic field emission is dominant in the surface-treated Pt contacts.

Titanium Tungsten (TiW) for Ohmic contacts to n-and p-type 4H-SiC

2000 ◽  
Vol 640 ◽  
Author(s):  
S.-K. Lee ◽  
C.-M. Zetterling ◽  
M. Östling
Keyword(s):  
High Temperature ◽  
Contact Resistance ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Term Stability ◽  
Long Term Stability ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
P Type

ABSTRACTIn the present work, we investigated sputtered titanium tungsten (TiW) contacts for Ohmic contacts to both n- and p-type 4H-SiC with long-term stability under high temperature (500°C).. Epitaxial layers with a doping concentration of 1.3×1019 and 6×1018 cm−3 were used. After high temperature annealing (>950°C) sputtered TiW contacts showed Ohmic behavior with good uniform distribution of the specific contact resistance. We obtained an average specific contact resistance (pc) of 4×10−5 Ωcm2 and 1.2 ∼ 1.7×10−4 Ωcm2 for p- and n-type, respectively from linear TLM measurement. We also found some variation of the specific contact resistance and the sheet resistance from our TLM measurement for p-type contacts. We will discuss this behavior with the measurement of SIMS. Long-term stability with a top-cap layer is also discussed

scholarly journals Thermally Stable Ohmic Contact to p-Type 4H-SiC Based on Ti3SiC2 Phase

2016 ◽  
Vol 858 ◽  
pp. 553-556 ◽  
Author(s):  
Tony Abi-Tannous ◽  
Maher Soueidan ◽  
Gabriel Ferro ◽  
Mihai Lazar ◽  
Christophe Raynaud ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Properties ◽  
Magnetron Sputtering ◽  
Ohmic Contact ◽  
Room Temperature ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Specific Contact ◽  
Thermionic Field Emission ◽  
P Type

In this study, the electrical properties of Ti3SiC2 based ohmic contacts formed on p-type 4H-SiC(0001) 4°-off substrates were studied. The Ti3SiC2 thin films were grown by thermal annealing (from 900°C to 1200°C) of Ti50Al50 layer deposited by magnetron sputtering. XRD analyzes were performed on the samples to further investigate the compounds formed after annealing. Using TLM structures, the Specific Contact Resistance (SCR) at room temperature of all contacts was measured. The temperature dependence (up to 600°C) of the SCR was studied to understand the current mechanisms at the interface and to determine the barrier height value by fitting the experimental results using the thermionic field emission theory. Aging tests showed that Ti3SiC2 based contacts were stable up to 200h at 600°C under Ar.

scholarly journals Metal/Semiconductor Barrier Properties of Non-Recessed Ti/Al/Ti and Ta/Al/Ta Ohmic Contacts on AlGaN/GaN Heterostructures

Energies ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2655 ◽  
Author(s):  
Spera ◽  
Greco ◽  
Nigro ◽  
Scalese ◽  
Bongiorno ◽  
...  
Keyword(s):  
Contact Resistance ◽  
Barrier Height ◽  
Ohmic Contacts ◽  
Barrier Properties ◽  
Specific Contact Resistance ◽  
Conductive Atomic Force Microscopy ◽  
Force Microscopy ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission

This paper compares the metal/semiconductor barrier height properties of non-recessed Ti/Al/Ti and Ta/Al/Ta contacts on AlGaN/GaN heterostructures. Both contacts exhibited a rectifying behavior after deposition and after annealing at temperatures up to 550 °C. The ohmic behavior was reached after annealing at 600 °C. High-resolution morphological and electrical mapping by conductive atomic force microscopy showed a flat surface for both contacts, with the presence of isolated hillocks, which had no significant impact on the contact resistance. Structural analyses indicated the formation of the Al3Ti and Al3Ta phases upon annealing. Furthermore, a thin interfacial TiN layer was observed in the Ti/Al/Ti samples, which is likely responsible for a lower barrier and a better specific contact resistance (c = 1.6 10−4 Ωcm2) with respect to the Ta/Al/Ta samples (c = 4.0 10−4 Ωcm2). The temperature dependence of the specific contact resistance was described by a thermionic field emission mechanism, determining barrier height values in the range of 0.58–0.63 eV. These results were discussed in terms of the different microstructures of the interfaces in the two systems.

Al+ Implanted 4H-SiC: Improved Electrical Activation and Ohmic Contacts

2013 ◽  
Vol 740-742 ◽  
pp. 767-772 ◽  
Author(s):  
Roberta Nipoti ◽  
Anders Hallén ◽  
Antonella Parisini ◽  
Francesco Moscatelli ◽  
Salvatore Vantaggio
Keyword(s):  
Contact Resistance ◽  
Field Effect ◽  
Ohmic Contacts ◽  
Electrical Activation ◽  
Specific Contact Resistance ◽  
Mobility Data ◽  
Specific Contact ◽  
P Type ◽  
Band Conduction ◽  
Thickness Sheet

The p-type doping of high purity semi-insulating 4H-SiC by Al+ ion implantation and a conventional thermal annealing of 1950 °C/5 min has been studied for implanted Al concentration in the range of 1 x1019 - 8 x 1020 cm-3 (0.36 μm implanted thickness). Sheet resistance in the range of 1.6 x 104 to 8.9 x102 Ω, corresponding to a resistivity in the range of 4.7 x 10-1 to 2.7 x 10-2 Ωcm for increasing implanted Al concentration have been obtained. Hall carrier density and mobility data in the temperature range of 140–600 K feature the transition from a valence band to an intra-band conduction for increasing implanted Al concentration. The specific contact resistance of Ti/Al contacts on the 5 x1019 cm-3 Al implanted specimen features a thermionic field effect conduction with a specific contact resistance in the 10-6 Ωcm2 decade.

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