scholarly journals Preliminary Interpretation of the Induction Period in Hydration of Sodium Hydroxide/Silicate Activated Slag

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4796
Author(s):  
Yibing Zuo ◽  
Guang Ye
Keyword(s):  
Induction Period ◽  
Isothermal Calorimetry ◽  
Action Mechanism ◽  
Alkali Activated Slag ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Calorimetric Studies ◽  
Kinetics Of ◽  
Alkali Activated ◽  
Good Interpretation

Many calorimetric studies have been carried out to investigate the reaction process of alkali-activated slag paste. However, the origin of the induction period and action mechanism of soluble Si in the dissolution of slag are still not clear. Moreover, the mechanisms behind different reaction periods are not well described. In this study, the reaction kinetics of alkali-activated slag paste was monitored by isothermal calorimetry and the effect of soluble Si was investigated through a dissolution test. The results showed that occurrence of the induction period in hydration of alkali-activated slag paste depended on the presence of soluble Si in alkaline activator and the soluble Si slowed down the dissolution of slag. A dissolution theory-based mechanism was introduced and applied to the dissolution of slag, showing good interpretation of the action mechanism of soluble Si. With this dissolution theory-based mechanism, origin of the induction period in hydration of alkali-activated slag was explicitly interpreted.

Properties of Alkli-Activated Slag Cement Compounded with Soluble Glasses with a High Silicate Modulus

2013 ◽  
Vol 712-715 ◽  
pp. 905-908
Author(s):  
Qun Pan ◽  
Bin Zhu ◽  
Xiao Huang ◽  
Lin Liu
Keyword(s):  
Compressive Strength ◽  
Cement Mortar ◽  
Strength Characteristics ◽  
Slag Cement ◽  
Alkali Activated Slag ◽  
Cement Mortars ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Alkali Activated ◽  
High Silicate

Properties of alkali-activated slag cements compounded with soluble glasse with a high silicate modulus Ms=2.6 were detailedly studied in this paper, including compressive strength and flexure strength characterictics at the ages of 3,7,28 days and flow values of fresh cement mixtures on a jolting table. As a result, with the compressive strength at the age of 28 days of 95.6-107.8 MPa has been developed, and the flow values and strength characteristics of alkali-activated slag cement mortars increased with increase in a water to cement (alkaline activator solution to slag) ratio, and the flow value (determined on the cement mortar mixtures) would reach 145 mm. Moreover, the development speed of strength characteristics of mortar specimens would be affected negatively by increasing of water demand (requirement).

scholarly journals Effect of Sodium Aluminate Dosage as a Solid Alkaline Activator on the Properties of Alkali-Activated Slag Paste

2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Bin Chen ◽  
Jun Wang ◽  
Jinyou Zhao
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Setting Time ◽  
Sodium Aluminate ◽  
Hydration Reaction ◽  
Hydration Products ◽  
Alkali Activated Slag ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Alkali Activated

Extensive research into alkali-activated slag as a green gel material to substitute for cement has been done because of the advantages of low-carbon dioxide emissions and recycling of industrial solid waste. Alkali-activated slag usually has good mechanical properties, but the too fast setting time restricted its application and promotion. Changing the composition of alkaline activator could optimize setting time, usually making it by adding sodium carbonate or sodium sulfate but this would cause insufficient hydration reaction power and hinder compressive strength growth. In this paper, the effect of sodium aluminate dosage as an alkaline activator on the setting time, fluidity, compressive strength, hydration products, and microstructures was studied through experiments. It is fair to say that an appropriate amount of sodium aluminate could obtain a suitable setting time and better compressive strength. Sodium aluminate provided enough hydroxyl ions for the paste to promote the hydration reaction process that ensured obtaining high compressive strength and soluble aluminium formed precipitate wrapped on the surface of slag to inhibit the hydration reaction process in the early phase that prolonged setting time. The hydration mechanism research found that sodium aluminate played a key role in the formation of higher cross-linked gel hydration products in the late phase of the process. Preparing an alkali-activated slag with excellent mechanical properties and suitable setting time will significantly contribute to its application and promotion.

scholarly journals The Effect of Reclaimed Asphalt Pavement (RAP) Aggregates on the Reaction, Mechanical Properties and Microstructure of Alkali-Activated Slag

CivilEng ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 794-810
Author(s):  
Juliana O. Costa ◽  
Paulo H. R. Borges ◽  
Flávio A. dos Santos ◽  
Augusto Cesar S. Bezerra ◽  
Johan Blom ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Asphalt Pavement ◽  
Isothermal Calorimetry ◽  
Laser Scanning Microscopy ◽  
Confocal Laser ◽  
Reclaimed Asphalt Pavement ◽  
Reclaimed Asphalt ◽  
Alkali Activated Slag ◽  
Activated Slag ◽  
Alkali Activated

Reclaimed asphalt pavement (RAP) is a recyclable aggregate produced during the demolition of old flexible pavements and consists of natural aggregates (NA) coated with aged bitumen. The detrimental effect caused by the bitumen coating on strength and porosity has limited the use of RAP on traditional cementitious systems. This study investigates the potential use of fine RAP to substitute NA in the production of alkali-activated slag mortars (AAM). The effect of different activator dosages was assessed, i.e., either 4% or 6% Na2O (wt. slag) combined with a modulus of silica equal to 0, 0.5 and 1.0. The characterisation of 100% RAP-AAM consisted of hydration kinetics (Isothermal Calorimetry), pore size distribution (Mercury Intrusion Porosimetry), mechanical performance (Compressive and Flexural strength), and microstructure analysis (Scanning Electron Microscopy and Confocal Laser Scanning Microscopy). The results show that RAP aggregates do not compromise the reaction of the matrices; however, it causes a significant strength loss (compressive strength of RAP-mortars 54% lower than reference NA-mortar at 28 days). The higher porosity at the interface transition zone of RAP-AAM is the main responsible for the lower strength performance. Increasing silicate dosages improves alkaline activation, but it has little impact on the adhesion between aggregate and bitumen. Despite the poorer mechanical performance, 100% RAP-AAM still yields enough strength to promote this recycled material in engineering applications.

scholarly journals Effect of Dosage of Alkaline Activator on the Properties of Alkali-Activated Slag Pastes

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Zhenzhen Jiao ◽  
Ying Wang ◽  
Wenzhong Zheng ◽  
Wenxuan Huang
Keyword(s):  
Compressive Strength ◽  
Room Temperature ◽  
Setting Time ◽  
Drying Shrinkage ◽  
Engineering Properties ◽  
Alkali Activated Slag ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Good Workability ◽  
Alkali Activated

This study focused on the engineering properties of alkali-activated slag (AAS) pastes prepared by mixing an activator consisting of sodium silicate and sodium hydroxide at room temperature. The water-to-slag ratio of AAS paste was kept constant at 0.35 by mass. AAS pastes were prepared using the activator with five different silicate moduli of 1, 1.2, 1.4, 1.6, and 1.8 and three different Na2O contents of 6%, 8%, and 10%. The results showed that both the silicate moduli and Na2O contents had significant effects on the engineering properties of AAS pastes. All the AAS pastes exhibited properties such as fast setting, good workability, and high early compressive strength. The final setting time varied from 9 to 36 min, and the fluidity was in the range of 147–226 mm. The 1 d compressive strength of all the AAS pastes, which could be easily achieved, had values above 55 MPa, whereas the highest strength obtained was 102 MPa with the silicate modulus of 1 and Na2O content of 8% at room temperature. The drying shrinkage increased as the silicate modulus increased. Furthermore, the hydration products and microstructures of AAS pastes were explained according to the microanalysis methods.

scholarly journals Durability of alkali activated slag in a marine environment: Influence of alkali ion

2018 ◽  
Vol 83 (10) ◽  
pp. 1143-1156 ◽  
Author(s):  
Irena Nikolic ◽  
Milena Tadic ◽  
Ivona Jankovic-Castvan ◽  
Vuk Radmilovic ◽  
Velimir Radmilovic
Keyword(s):  
Compressive Strength ◽  
Marine Environment ◽  
Alkali Activated Slag ◽  
Lower Porosity ◽  
Seawater Environment ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Electric Arc Furnace Slag ◽  
Strength And Durability ◽  
Alkali Activated

The durability of alkali-activated steel electric arc furnace slag (EAFS) in a marine environment was evaluated with respect to the chemical composition of the alkaline activator. Two different alkaline activators have been used: a mixture of NaOH and Na2SiO3 solutions (Na-activator), as well as a mixture of KOH and K2SiO3 solutions (K-activator). The obtained results gave the insight into the influence of alkaline activator chemistry on the compressive strength and durability of alkali-activated slag (AAS), which was exposed to the damaging seawater environment. The porosity of AAS was found to be the most important factor with regards to the strength and durability of these materials in marine environment. Sodium based alkali-activated slag (Na-AAS) displayed lower porosity and higher compressive strength compared to potassium based AAS (K- -AAS). Lower porosity and thus a lower rate of water uptake by AAS matrix, i.e., the lower sorptivity was exhibited by the Na-AAS when compared to K-AAS. Hence, Na-AAS exhibited better durability in a marine environment.

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