scholarly journals Selectively UV-Blocking and Visibly Transparent Adhesive Films Embedded with TiO2/PMMA Hybrid Nanoparticles for Displays

Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5273
Author(s):  
Jin-Wook Choi ◽  
Jun Hyup Lee
Keyword(s):  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Light Transmittance ◽  
Hybrid Nanoparticles ◽  
Display Device ◽  
Adhesive Film ◽  
Inorganic Particles ◽  
Uv Blocking ◽  
Display Performance ◽  
Protection Property

To simultaneously achieve the high visible transparency and enhance the ultraviolet (UV)-blocking performance of displays, inorganic–organic hybrid nanoparticles, comprising TiO2 as a core and poly(methyl methacrylate) (PMMA) as a shell, were uniformly incorporated into the optically clear adhesive (OCA) used in the front of a display device. The highly refractive TiO2 nanocore could selectively scatter UV rays, which degrade the display performance, owing to the differences in the refractive indices between the inorganic particles and PMMA matrix, thereby offering an improved UV protection property to the adhesive film. Moreover, the organic PMMA nanoshell maintained the high visible light transmittance of the pristine OCA film via the prevention of particle agglomeration. To examine the effect of the PMMA nanoshell and nanoparticle size on the optical properties of the adhesive films, the OCA films embedded with only TiO2 nanoparticles or hybrid nanoparticles with different particle sizes were prepared using a roll-to-roll process, and characterized in the range of UV and visible lights using UV-visible spectroscopy. It is experimentally revealed that the adhesive film including small TiO2/PMMA hybrid nanoparticles at an extremely low content exhibited enhanced UV-blocking properties and increased visible light transmittance compared to that with only TiO2 nanoparticles.

Visible Light Active Ce-doped TiO2 Nanoparticles for Photocatalytic Degradation of Methylene Blue

2016 ◽  
Vol 13 (1) ◽  
pp. 110-116 ◽  
Author(s):  
Rani P. Barkul ◽  
Farah-Naaz A. Shaikh ◽  
Sagar D. Delekar ◽  
Meghshyam K. Patil
Keyword(s):  
Methylene Blue ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
Tio2 Nanoparticles ◽  
Doped Tio2 ◽  
Visible Light Active

scholarly journals Windblown Sand-Induced Degradation of Glass Panels in Curtain Walls

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 607
Author(s):  
Yuxi Zhao ◽  
Rongcheng Liu ◽  
Fan Yan ◽  
Dawei Zhang ◽  
Junjin Liu
Keyword(s):  
Visible Light ◽  
Mass Loss ◽  
Effective Area ◽  
Area Ratio ◽  
Light Transmittance ◽  
Relative Mass ◽  
Impact Time ◽  
Windblown Sand ◽  
Glass Panels ◽  
The Impact

The windblown sand-induced degradation of glass panels influences the serviceability and safety of these panels. In this study, the degradation of glass panels subject to windblown sand with different impact velocities and impact angles was studied based on a sandblasting test simulating a sandstorm. After the glass panels were degraded by windblown sand, the surface morphology of the damaged glass panels was observed using scanning electron microscopy, and three damage modes were found: a cutting mode, smash mode, and plastic deformation mode. The mass loss, visible light transmittance, and effective area ratio values of the glass samples were then measured to evaluate the effects of the windblown sand on the panels. The results indicate that, at high abrasive feed rates, the relative mass loss of the glass samples decreases initially and then remains steady with increases in impact time, whereas it increases first and then decreases with an increase in impact angle such as that for ductile materials. Both visible light transmittance and effective area ratio decrease with increases in the impact time and velocities. There exists a positive linear relationship between the visible light transmittance and effective area ratio.

scholarly journals Green Synthesis of N/Zr Co-Doped TiO2 for Photocatalytic Degradation of p-Nitrophenol in Wastewater

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 235
Author(s):  
Hayette Benkhennouche-Bouchene ◽  
Julien G. Mahy ◽  
Cédric Wolfs ◽  
Bénédicte Vertruyen ◽  
Dirk Poelman ◽  
...  
Keyword(s):  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Sol Gel ◽  
Visible Region ◽  
Chemical Properties ◽  
Pure Tio2 ◽  
Molar Ratio ◽  
Xps Spectra ◽  
Doped Tio2 ◽  
Co Doped

TiO2 prepared by a green aqueous sol–gel peptization process is co-doped with nitrogen and zirconium to improve and extend its photoactivity to the visible region. Two nitrogen precursors are used: urea and triethylamine; zirconium (IV) tert-butoxide is added as a source of zirconia. The N/Ti molar ratio is fixed regardless of the chosen nitrogen precursor while the quantity of zirconia is set to 0.7, 1.4, 2, or 2.8 mol%. The performance and physico-chemical properties of these materials are compared with the commercial Evonik P25 photocatalyst. For all doped and co-doped samples, TiO2 nanoparticles of 4 to 8 nm of size are formed of anatase-brookite phases, with a specific surface area between 125 and 280 m2 g−1 vs. 50 m2 g−1 for the commercial P25 photocatalyst. X-ray photoelectron (XPS) measurements show that nitrogen is incorporated into the TiO2 materials through Ti-O-N bonds allowing light absorption in the visible region. The XPS spectra of the Zr-(co)doped powders show the presence of TiO2-ZrO2 mixed oxide materials. Under visible light, the best co-doped sample gives a degradation of p-nitrophenol (PNP) equal to 70% instead of 25% with pure TiO2 and 10% with P25 under the same conditions. Similarly, the photocatalytic activity improved under UV/visible reaching 95% with the best sample compared to 50% with pure TiO2. This study suggests that N/Zr co-doped TiO2 nanoparticles can be produced in a safe and energy-efficient way while being markedly more active than state-of-the-art photocatalytic materials under visible light.

scholarly journals Green synthesis of mesoporous anatase TiO2 nanoparticles and their photocatalytic activities

RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 48083-48094 ◽  
Author(s):  
Sunderishwary S. Muniandy ◽  
Noor Haida Mohd Kaus ◽  
Zhong-Tao Jiang ◽  
Mohammednoor Altarawneh ◽  
Hooi Ling Lee
Keyword(s):  
Low Temperature ◽  
Green Chemistry ◽  
Visible Light ◽  
Green Synthesis ◽  
Tio2 Nanoparticles ◽  
Soluble Starch ◽  
Anatase Tio2 ◽  
Photocatalytic Activities ◽  
Visible Light Active

Mesoporous anatase TiO2 nanoparticles are produced by employing a facile green chemistry approach at low temperature with soluble starch as the template in this work. The obtained TiO2 photocatalyst is visible-light active with good photocatalytic activities.

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