scholarly journals Rheological Properties of Graphene/Polyethylene Composite Modified Asphalt Binder

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3986
Author(s):  
Huan-Yun Zhou ◽  
Huai-Bing Dou ◽  
Xian-Hua Chen
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
High Speed ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Creep Recovery ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Asphalt Modification ◽  
Ft Ir

Aiming to improve the comprehensive road performance of asphalt binders, especially the high-temperature performance, a novel asphalt binder was prepared by compounding high-quality and low-cost polyethylene (PE) with graphene (GNPs) using a high-speed shearing machine. The rheological properties and interaction mechanism of PE/GNPs composite modified asphalt were investigated using temperature sweep (TeS), multiple stress creep recovery (MSCR), linear amplitude sweep (LAS) and Fourier transform infrared spectroscopy (FT-IR) and field emission scanning electron microscopy (FESEM). The experimental results demonstrated that GNPs and PE can synergistically improve the high-temperature performance of asphalt binders and enhance the rutting resistance of pavements; the pre-blended PE/GNPs masterbatch has good medium-temperature fatigue and low-temperature cracking resistance. Meanwhile, PE/GNPs dispersed uniformly in the asphalt matrix, and the microstructure and dispersion of premixed PE/GNPs masterbatch facilitated the asphalt modification. No new absorption peaks appeared in the FT-IR spectra of the composite modified asphalt, indicating that asphalt binders were physically modified with GNPs and PE. These findings may cast light on the feasibility of polyethylene/graphene composite for asphalt modification.

scholarly journals Effect of Recycled Shell Waste as a Modifier on the High- and Low-Temperature Rheological Properties of Asphalt

2021 ◽  
Vol 13 (18) ◽  
pp. 10271
Author(s):  
Yuchen Guo ◽  
Xuancang Wang ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Hao Su ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Low Temperatures ◽  
High Speed ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance

The deteriorating ecological environment and the concept of sustainable development have highlighted the importance of waste reuse. This article investigates the performance changes resulting from the incorporation of shellac into asphalt binders. Seashell powder-modified asphalt was prepared with 5%, 10%, and 15% admixture using the high-speed shear method. The microstructure of the seashell powder was observed by scanning electron microscope test (SEM); the physical-phase analysis of the seashell powder was carried out using an X-ray diffraction (XRD) test; the surface characteristics and pore structure of shellac were analyzed by the specific surface area Brunauer-Emmett-Teller (BET) test; and Fourier infrared spectroscopy (FTIR) qualitatively analyzed the composition and changes of functional groups of seashell powder-modified asphalt. The conventional performance index of seashell powder asphalt was analyzed by penetration, softening point, and ductility (5 °C) tests; the effect of seashell powder on asphalt binder was studied using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR) at high and low temperatures, respectively. The results indicate the following: seashell powder is a coarse, porous, and angular CaCO3 bio-material; seashell powder and the asphalt binder represent a stable physical mixture of modified properties; seashell powder improves the consistency, hardness, and high-temperature performance of the asphalt binder but weakens the low-temperature performance of it; seashell powder enhances the elasticity, recovery performance, and permanent deformation resistance of asphalt binders and improves high-temperature rheological properties; finally, seashell powder has a minimal effect on the crack resistance of asphalt binders at very low temperatures. In summary, the use of waste seashells for recycling as bio-modifiers for asphalt binders is a practical approach.

scholarly journals Application of biochar from crop straw in asphalt modification

PLoS ONE ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. e0247390
Author(s):  
Xinli Gan ◽  
Wenli Zhang
Keyword(s):  
Electron Microscopy ◽  
Particle Size ◽  
High Temperature ◽  
High Speed ◽  
Asphalt Binder ◽  
Crop Straw ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Asphalt Modification ◽  
Scanning Electron

The objective of this study is to verify the feasibility of using biochar made from crop straw as a bitumen additive to improve some properties of bitumen. The differences between crop straw biochar prepared in a laboratory and commercial charcoal were investigated through scanning electron microscopy and laser particle size analyses. Furthermore, biochar-modified asphalt was prepared using the high-speed shear method, and the penetration, softening point, ductility at 15°C, and apparent viscosity of the asphalt binder with 6% biochar were measured at 120, 135, 150, 160, and 175°C. It was found that both the crop straw biochar and the commercial charcoal consist mainly of C, O, Si, and K, but the C content of crop straw biochar is slightly higher than that of commercial charcoal. The particle size of biochar is smaller than that of commercial charcoal, while the specific surface area is larger. It was determined that the addition of crop straw biochar significantly improved the high-temperature performance of asphalt, and that biochar and commercial charcoal have a similar influence on the high temperature performance of asphalt.

scholarly journals Research on Rheological Properties of High-Percentage Artificial RAP Binder with WMA Additives

2020 ◽  
Vol 2020 ◽  
pp. 1-24
Author(s):  
Weiying Wang ◽  
Songchang Huang ◽  
Yongchun Qin ◽  
Yiren Sun ◽  
Rui Dong ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Creep Recovery ◽  
Recycled Asphalt ◽  
Reclaimed Asphalt ◽  
Temperature Performance ◽  
Huge Impact ◽  
Polyethylene Wax

With the development of pavement recycling technology, the requirement of reclaimed asphalt pavement (RAP) is substantially increasing. Warm-mix recycled asphalt (WMRA) technology has made great progress, which can effectively decrease the working temperature and improve the RAP content. In this study, the rheological properties of recycled binders with incorporation of high-percentage artificial RAP binder (30–70%) were evaluated using two types of warm-mix asphalt (WMA) additives, i.e., polyethylene wax R and surfactant M. The dynamic shear rheometer (DSR) and beam bending rheometer (BBR) tests were conducted on the recycled binders. The results showed that the temperature and frequency played an important role in determining the complex shear modulus of the high-percentage WMRA binders. The dependency of phase angle on frequency increased after the long-term aging. The WMA additive R had a relatively huge impact on the rheological properties of asphalt, which mainly occurred before the PAV aging of recycled asphalt binder; the WMA additive M had no significant impact on the rheological properties of recycled asphalt binder. The WMA additive R enhanced the low-temperature rheology of recycled asphalt binder, while the WMA additive M enhanced the high-temperature rheology of recycled asphalt binder. Both of these types of WMA additives improved the antifatigue performance of recycled asphalt binder. The increased content of RAP binder improved the high-temperature performance and reduced the low-temperature performance of the recycled asphalt binder. However, it had no obvious impact on the fatigue performance. In addition, there was a good linear relation between the RAP binder content and the two indexes of the multiple stress creep recovery (MSCR) test.

scholarly journals Performance Evaluation of Bone Glue-Modified Asphalt

2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Asif Ali ◽  
Naveed Ahmad ◽  
Muhammad Adeel ◽  
Syed Bilal Ahmed Zaidi ◽  
Muhammad Sohail Jameel ◽  
...  
Keyword(s):  
High Temperature ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Cost Effective ◽  
Sem Analysis ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
And Performance ◽  
Bone Glue

Asphalt is one of the primary materials that are extensively used by the pavement industry throughout the world. Its behaviour is highly dependent on the amount of loading and the level of temperature it is exposed to. Asphalt has been modified in the past with different additives to improve its high- or low-temperature properties. In Pakistan, temperature remains high for most of the time of the year; hence, asphalt binders with less susceptibility to higher temperatures are preferred for flexible pavements. Acids, polymers, fibers, and extenders have been used by the researchers to improve high-temperature performance of asphalt mixture. In the present study, a bio material derived from the animal waste, named as bone glue (BG), has been used with the 60/70 penetration grade binder in dosages of 3%, 6%, 9%, and 12% by weight of asphalt binder. The bone glue is produced from a sustainable source. It is a cost-effective and eco-friendly material. Moreover, it produces a durable and nonhazardous asphalt composite. The influence of addition of bone glue on asphalt binder was evaluated using different testing techniques which include consistency tests, rheological analysis, and adhesion tests. Furthermore, different performance tests were conducted on bone glue-modified asphalt mixtures. Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis were carried out to ensure the homogeneity and proper mixing of bone glue in asphalt binder. The results from the tests reveal that bone glue stiffens the asphalt binder hence enhancing its high temperature performance. Bone glue dosage of 9% by weight of the binder was found to be the optimum dosage based on the rheological and performance analysis.

Preparation and Properties of Nanoclay/TPS/Asphalt Ternary Binders

2009 ◽  
Vol 620-622 ◽  
pp. 497-500 ◽  
Author(s):  
Shao Peng Wu ◽  
Jin Gang Wang ◽  
Yuan Zhang
Keyword(s):  
Rheological Properties ◽  
High Speed ◽  
Complex Modulus ◽  
Preliminary Investigation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Frequency Sweep ◽  
Modified Asphalt ◽  
Aging Resistance ◽  
Before And After

After a preliminary investigation on the binary asphalt/clay binder, the ternary binder was prepared by adding the nanoclay and TAFPACK-SUPER (TPS) to the original asphalt. The previous research shows that exfoliated/intercalated layers homogeneously are dispersed in the asphalt matrix and the nanocomposite has formed. Rotation Thin Film Oven Test (RTFOT) and Pressure Age Vessel Test (PAV) results indicate that the modified asphalt with 3% organic nano-montmorillonite (OMMT) present better performance of aging resistance. The purpose of this research is to attain ternary asphalt binder with better rheological performance and aging resistance. The ternary modified asphalt binder containing 4% OMMT and 12% TPS by weight were prepared at the laboratory scale using high speed shearing mixer. The rheological properties of OMMT/TPS modified asphalt binders were evaluated before and after aging in present paper. Temperature sweep tests and frequency sweep tests were conducted to characterize the rheological properties of modified asphalt using Dynamic Shear Rheometer (DSR). According to the frequency sweep tests, complex modulus master curves were plotted to analysis the rheological properties. The results indicate that nanoclay/TPS/asphalt ternary binders have more excellent performance of rheological and aging resistance at both high and low temperatures, compared with the virginal bitumen and TPS modified asphalt.

scholarly journals Effect of Biowaste on the High- and Low-Temperature Rheological Properties of Asphalt Binders

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Xuancang Wang ◽  
Yuchen Guo ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Jing Zhao ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Oyster Shell ◽  
Asphalt Binders ◽  
Creep Recovery ◽  
Oyster Shell Powder ◽  
Shell Powder ◽  
Rheological Performance

The growth of aquaculture has increased the production of oysters. However, the increased oyster shell volume has created serious environmental and recycling problems for the society. In order to study the sustainable utilization of waste oyster shells, asphalt binder of waste oyster shell powder was prepared by using modified asphalt material with waste oyster shells. The microstructure of oyster shell powder was analyzed by scanning electron microscopy experiments. The chemical composition of the asphalt binder was observed by Fourier transform infrared spectroscopy tests. The physical properties of the asphalt binder, including softness, high-temperature performance, and plastic deformation capacity, were initially evaluated through three indicators’ tests on asphalt. A preliminary performance evaluation of the asphalt binder was performed. The high-temperature stability of asphalt binders was evaluated using dynamic shear rheometry. The rutting resistance of the material was evaluated by temperature sweep tests, and the shear deformation resistance of the material was evaluated by frequency sweep tests. Multiple stress creep recovery tests determine the material’s ability to resist permanent deformation. The low-temperature rheological properties were evaluated by bending beam rheology tests. The study found that the waste oyster shell powder is a biomass with a porous irregular petal shape. No new characteristic absorption peaks are formed by mixing with asphalt. And, it can improve the viscosity, thermal stability, and temperature-sensitive properties of the material. It significantly improved the high-temperature rheological performance, rutting coefficient, and recovery elasticity of the material. However, it has little effect on low-temperature rheological performance. This study provides a solid foundation for the effective use of biowaste in engineering materials.

scholarly journals Effects of Hydrated Lime on High-Temperature Rheological Properties of High-Viscosity Modified Asphalt

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Wenjing Zhou ◽  
Yihan Sun ◽  
Fengxia Chi ◽  
Qinling Cheng ◽  
Bo Han
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Hydrated Lime ◽  
High Viscosity ◽  
Stress Sensitivity ◽  
Creep Recovery ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Long Time ◽  
Technical Interest

High-viscosity modified asphalt (HVA) is widely used as the binder for permeable asphalt pavement, and hydrated lime (HL) attracts a strong technical interest as an effective moisture additive in asphalt for a long time. However, the application of HL in HVA has been rarely studied. The present study evaluates the influence of HL on the high-temperature rheological properties of HVA and selects the optimum HL content and fineness. The asphalt mortars of HVA and HL of different contents and fineness were prepared. Temperature scanning (DSR-TS), multiple stress creep recovery (MSCR) by using a dynamic shear rheometer, and scanning electron microscope (SEM) tests were carried out to evaluate the high-temperature rheological properties and microstructure morphology characteristics of the asphalt mortars. Based on the DSR-TS and MSCR tests, the results showed that high-temperature performance together with the ability to deformation resistance of HVA was improved apparently with the increase of the HL content. When the HL content is above 1.2, the stress sensitivity of HVA is lower. The SEM results clearly showed that the uniformity of asphalt mortars could be effectively guaranteed when the HL content was 1.2 and the fineness was 800 mesh. The HL fineness has little effect on the high-temperature performance of HVA. In summary, taking into account the high-temperature performance and microstructure of HVA with HL, the optimum HL content and fineness could be finally determined.

scholarly journals Characterization of asphalt binders extracted from field mixtures containing RAP and/or RAS

2022 ◽  
Vol 13 (1) ◽  
pp. 140-152
Author(s):  
Eslam Deef-Allah ◽  
Magdy Abdelrahman
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Asphalt Mixtures ◽  
Asphalt Binders ◽  
Creep Recovery ◽  
Recycled Asphalt ◽  
Reclaimed Asphalt ◽  
Multiple Stress Creep Recovery ◽  
Pavement Construction

The use of reclaimed asphalt pavement (RAP) and/or recycled asphalt shingles (RAS) in the asphalt mixtures is a common practice in the U.S.A. However, there is a controversy to date on how RAP/RAS interact with virgin asphalt binders (VABs) in asphalt mixtures. For mixtures containing RAP/RAS, the aged asphalt binders in RAP and air-blown asphalt binders in RAS alter the performances of the extracted asphalt binders (EABs). Thus, the rheological properties of EABs from these mixtures require more investigation. The focus of this paper was relating the high-temperature properties of EABs from field cores to the corresponding rolling thin film oven aged virgin asphalt binders (RTFO AVABs). Furthermore, a comparison of the effect of RAP and RAS on the high-temperature rheological properties of EABs was another objective. Different asphalt cores were collected from the field within two weeks after the pavement construction process in 2016. These cores represented eight asphalt mixtures with different asphalt binder replacement percentages by RAP, RAS, or both. The asphalt binders were extracted from these mixtures and considered as RTFO AVABs. The high-temperature rheological properties included the temperature sweep and frequency sweep testing and the multiple stress creep recovery testing. The EABs had higher stiffnesses and elasticates than the corresponding RTFO AVABs because of the aged binders in RAP/RAS. The binders in RAP interacted more readily with VABs than RAS binders.

scholarly journals Carbon Nanomaterials for Enhancing the Thermal, Physical and Rheological Properties of Asphalt Binders

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2585
Author(s):  
Zhelun Li ◽  
Xin Yu ◽  
Yangshi Liang ◽  
Shaopeng Wu
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Carbon Nanomaterials ◽  
Asphalt Binders ◽  
Snow Melting ◽  
Temperature Performance ◽  
Unique Nature ◽  
Application Potential ◽  
Urban Heat ◽  
Two Parameters

Effective thermal conduction modification in asphalt binders is beneficial to reducing pavement surface temperature and relieving the urban heat island (UHI) effect in the utilization of solar harvesting and snow melting pavements. This study investigated the performance of two nanometer-sized modifiers, graphene (Gr) and carbon nanotubes (CNTs), on enhancing the thermal, physical and rheological properties of asphalt binders. Measurements depending on a transient plant source method proved that both Gr and CNTs linearly increased the thermal conductivity and thermal diffusivity of asphalt binders, and while 5% Gr by volume of matrix asphalt contributed to 300% increments, 5% CNTs increased the two parameters of asphalt binders by nearly 72% at 20 °C. Meanwhile, a series of empirical and rheological properties experiments were conducted. The results demonstrated the temperature susceptibility reduction and high-temperature properties promotion of asphalt binders by adding Gr or CNTs. The variation trends in the anti-cracking properties of asphalt binders modified by Gr and CNTs with the modifier content differed at low temperatures, which may be due to the unique nature of Gr. In conclusion, Gr, whose optimal content is 3% by volume of matrix asphalt, provides superior application potential for solar harvesting and snow melting pavements in comparison to CNTs due to its comprehensive contributions to thermal properties, construction feasibility, high-temperature performance and low-temperature performance of asphalt binders.

scholarly journals Effects of WMA Additive on the Rheological Properties of Asphalt Binder and High Temperature Performance Grade

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Jiupeng Zhang ◽  
Guoqiang Liu ◽  
Li Xu ◽  
Jianzhong Pei
Keyword(s):  
Critical Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Aging Effect ◽  
Asphalt Binders ◽  
Short Term ◽  
Performance Grade ◽  
Temperature Performance ◽  
Effects Of Temperature ◽  
Increasing Temperature

Sasobit additives with different dosages were added into 70# and 90# virgin asphalt binders to prepare WMA binders. The rheological properties, includingG∗andδ, were measured by using DSR at the temperature ranging from 46°C to 70°C, and the effects of temperature, additive dosage and aging onG∗/sin⁡δ, critical temperature, and H-T PG were investigated. The results indicate that WMA additive improvesG∗but reducesδ, and the improvement on 70# virgin binder is more significant.G∗/sin⁡δexponentially decreases with the increasing temperature but linearly increases with the increasing additive dosage. Aging effect weakens the interaction between binder and additive but significantly increases the binder’s viscosity; that is whyG∗/sin⁡δis higher after short-term aging. In addition, the critical temperature increases with the increasing additive dosage, and the additive dosage should be more than 3% and 5% to improve H-T PG by one grade for 70# and 90# virgin binder, respectively.

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