scholarly journals Fabrication of PDMS@Fe3O4/MS Composite Materials and Its Application for Oil-Water Separation

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 115
Author(s):  
Jiaqi Wang ◽  
Zhenzhong Fan ◽  
Qingwang Liu ◽  
Qilei Tong ◽  
Biao Wang

The discharge of oily wastewater and oil spills at sea are the current difficulties in water pollution control. This problem often leads to terrible disasters. Therefore, the effective realization of oil-water separation is a very challenging problem. Superhydrophobic sponge is a promising oil-absorbing material. In this article, we reported a superhydrophobic sponge with nano-Fe3O4 for oil-water separation. The addition of nano-Fe3O4 allows the sponge to be recycled under the action of magnetic force. The sponge has the advantages of low cost, simple preparation and efficient oil-water separation. This kind of sponge is very worthy of promotion for the treatment of oily wastewater and marine oil spill accidents.

Soft Matter ◽  
2021 ◽  
Author(s):  
Caimei Zhao ◽  
Lei Chen ◽  
Chuanming Yu ◽  
Binghua Hu ◽  
Haoxuan Huang ◽  
...  

Super-hydrophobic porous absorbent is a convenient, low-cost, efficient and environment-friendly material in the treatment of oil spills. In this work, a simple Pickering emulsion template method was employed to fabricate...


2020 ◽  
Vol 8 ◽  
Author(s):  
Usama Zulfiqar ◽  
Andrew G. Thomas ◽  
Allan Matthews ◽  
David J. Lewis

Oil/water mixtures are a potentially major source of environmental pollution if efficient separation technology is not employed during processing. A large volume of oil/water mixtures is produced via many manufacturing operations in food, petrochemical, mining, and metal industries and can be exposed to water sources on a regular basis. To date, several techniques are used in practice to deal with industrial oil/water mixtures and oil spills such as in situ burning of oil, bioremediation, and solidifiers, which change the physical shape of oil as a result of chemical interaction. Physical separation of oil/water mixtures is in industrial practice; however, the existing technologies to do so often require either dissipation of large amounts of energy (such as in cyclones and hydrocyclones) or large residence times or inventories of fluids (such as in decanters). Recently, materials with selective wettability have gained attention for application in separation of oil/water mixtures and surfactant stabilized emulsions. For example, a superhydrophobic material is selectively wettable toward oil while having a poor affinity for the aqueous phase; therefore, a superhydrophobic porous material can easily adsorb the oil while completely rejecting the water from an oil/water mixture, thus physically separating the two components. The ease of separation, low cost, and low-energy requirements are some of the other advantages offered by these materials over existing practices of oil/water separation. The present review aims to focus on the surface engineering aspects to achieve selectively wettability in materials and its their relationship with the separation of oil/water mixtures with particular focus on emulsions, on factors contributing to their stability, and on how wettability can be helpful in their separation. Finally, the challenges in application of superwettable materials will be highlighted, and potential solutions to improve the application of these materials will be put forward.


Author(s):  
Xianhang Yan ◽  
Xiao Xiao ◽  
Christian Au ◽  
Shaurya Mathur ◽  
Linjun Huang ◽  
...  

Offshore oil spills, industrial oily wastewater, and domestic oil pollution are some of the most serious global challenges, leading environmental causes of morbidity and mortality. Nanofiber membrane materials manufactured via...


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Dong-hyun Kim ◽  
Rodolphe Mauchauffé ◽  
Jongwoon Kim ◽  
Se Youn Moon

AbstractFor decades, oil and water separation has remained a challenge. Not only oil spills but also industrial oily wastewaters are threatening our environment. Over the years, oil–water separation methods have been developed, however, there are still considerable hurdles to overcome to provide a low cost and efficient process able to treat a large amount of liquid. In this work, we suggest a continuous, simultaneous and effective oil–water separation method based on the antagonistic functionalization of meshes using atmospheric pressure cold plasmas. Using this robust plasma method, superhydrophobic/underwater-superoleophilic or superhydrophilic/underwater-superoleophobic functionalized meshes are obtained. Antagonistically functionalized meshes can simultaneously separate oil and water and show continuous separation flow rates of water (900 L m−2 h−1) and oil (400 L m−2 h−1) with high purities (> 99.9% v/v). This fast, low-cost and continuous plasma-based process can be readily and widely adopted for the selective functionalization of membranes at large scale for oil-spill cleanup and water purification.


NANO ◽  
2021 ◽  
pp. 2150061
Author(s):  
Yuntian Wan ◽  
Xue Lin ◽  
Zhongshuai Chang ◽  
Xiaohui Dai ◽  
Jiangdong Dai

Currently, with the increasingly serious pollution problem of oily wastewater, it is urgent to develop advanced materials and methods. In this work, a Fe(III)-CMC@Ni(OH)2@Ni composite foam with superhydrophilic and underwater superoleophobicity was fabricated by an in situ growth of flower-like Ni(OH)2 nanoparticles and chelated assembly of Fe(III)-CMC nanohydrogel via a layer-by-layer self assembly using Fe[Formula: see text] ion and carboxymethyl cellulose (CMC). The composite foam could separate various oil/water mixtures and exhibited excellent efficiency over 99%. This foam possessed ultrahigh water flux (220000[Formula: see text]L m[Formula: see text] h[Formula: see text] and better resistant to penetration pressure (1.3[Formula: see text]kPa). After 30 cycles, the oil–water separation performance reduced only 0.5%, but the foam structure was still stable that guarantees a better lifetime. Besides, this composite foam showed anti-fouling, unique durability and excellent corrosion resistance performance. Taking into account all good properties, Fe(III)-CMC@Ni(OH)2@Ni composite foam was expected to be a potential candidate for responding to all kinds of complex oily wastewater conditions.


Coatings ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 659 ◽  
Author(s):  
Sheng Lei ◽  
Xinzuo Fang ◽  
Fajun Wang ◽  
Mingshan Xue ◽  
Junfei Ou ◽  
...  

The mixture of insoluble organics and water seriously affects human health and environmental safety. Therefore, it is important to develop an efficient material to remove oil from water. In this work, we report a superhydrophobic Cu2O mesh that can effectively separate oil and water. The superhydrophobic Cu2O surface was fabricated by a facile chemical reaction between copper mesh and hydrogen peroxide solution without any low surface reagents treatment. With the advantages of simple operation, short reaction time, and low cost, the as-synthesized superhydrophobic Cu2O mesh has excellent oil–water selectivity for many insoluble organic solvents. In addition, it could be reused for oil–water separation with a high separation ability of above 95%, which demonstrated excellent durability and reusability. We expect that this fabrication technique will have great application prospects in the application of oil–water separation.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5714
Author(s):  
Ha-Jin Lee ◽  
Won San Choi

Air and water pollution pose an enormous threat to human health and ecosystems. In particular, particulate matter (PM) and oily wastewater can cause serious environmental and health concerns. Thus, controlling PM and oily wastewater has been a great challenge. Various techniques have been reported to effectively remove PM particles and purify oily wastewater. In this article, we provide a review of the recent advancements in air filtration and oil/water separation using two- and three-dimensional (2D and 3D) bulk materials. Our review covers the advantages, characteristics, limitations, and challenges of air filters and oil/water separators using 2D and 3D bulk materials. In each section, we present representative works in detail and describe the concepts, backgrounds, employed materials, fabrication methods, and characteristics of 2D and 3D bulk material-based air filters and oil/water separators. Finally, the challenges, technical problems, and future research directions are briefly discussed for each section.


2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.


2017 ◽  
Vol 224 ◽  
pp. 117-124 ◽  
Author(s):  
Chuqi Zhang ◽  
Yanmei Li ◽  
Ningning Bai ◽  
Cui Tan ◽  
Peng Cai ◽  
...  

2015 ◽  
Vol 73 (5) ◽  
pp. 1098-1103 ◽  
Author(s):  
Jun Liu ◽  
Wanxia He ◽  
Peng Li ◽  
Siying Xia ◽  
Xiaomeng Lü ◽  
...  

Oil–water separation has recently become a worldwide challenge due to the frequent occurrence of oil spill accidents and increasing industrial oily wastewater. In this work, the multifunctional mesh films with underwater oleophobicity and certain bacteriostatic effects are prepared by layer-by-layer assembly of graphene oxide-silica coatings on stainless steel mesh. The mesh film exhibits excellent environmental stability under a series of harsh conditions. The new, facile and reusable separation system is proposed to achieve deep treatment of oily wastewater, and the oil collection rate can reach over 99%.


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