scholarly journals Fabrication of Cellulose Film with Enhanced Mechanical Properties in Ionic Liquid 1-Allyl-3-methylimidaxolium Chloride (AmimCl)

Materials ◽  
2013 ◽  
Vol 6 (4) ◽  
pp. 1270-1284 ◽  
Author(s):  
Jinhui Pang ◽  
Xin Liu ◽  
Xueming Zhang ◽  
Yuying Wu ◽  
Runcang Sun
2021 ◽  
pp. 095400832199676
Author(s):  
Yuting Ouyang ◽  
Qiu Zhang ◽  
Xiukun Liu ◽  
Ruan Hong ◽  
Xu Xu ◽  
...  

Different ionic liquid modified graphene nanosheets (IG) were induced into polyimide (PI) to improve the tribological, thermal, and mechanical properties of shape memory IG/PI composites. The results demonstrated that when using 1-aminoethyl-3-methylimidazole bromide to modify graphene nanosheets (IG-1), the laser-driven shape recovery rate of IG-1/PI composites (IGPI-1) reached 73.02%, which was 49.36% higher than that of pure PI. In addition, the IGPI-1 composite materials reached the maximum shape recovery rate within 15 s. Additionally, under dry sliding, the addition of IG can significantly improve the tribological properties of composite materials. IGPI-1 exhibited the best self-lubricating properties. Compared with pure PI, the friction coefficient (0.19) and wear rate (2.62 × 10–5) mm3/Nm) were reduced by 44.1% and 24.2%, respectively, and the T10% of IGPI-1 increased by 32.2°C. The Tg of IGPI-1 reached 256.5°C, which was 8.4°C higher than that of pure PI. In addition, the tensile strength and modulus of IGPI-1 reached 82.3 MPa and 1.18 GPa, which were significantly increased by 33.6% and 29.8%, respectively, compared with pure PI. We hope that this work will be helpful for the preparation of shape memory materials with excellent tribological, thermal, and mechanical properties.


Soft Matter ◽  
2021 ◽  
Author(s):  
Fengjin Xie ◽  
Xinpei Gao ◽  
Yang Yu ◽  
Fei Lu ◽  
Liqiang Zheng

Gel electrolytes have aroused extensive interest for diverse flexible electronics due to their high ionic conductivity and inherent stretchability. However, gel electrolytes still face challenges in terms of mechanical properties,...


Materials ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3249 ◽  
Author(s):  
Satoshi Idenoue ◽  
Yoshitaka Oga ◽  
Daichi Hashimoto ◽  
Kazuya Yamamoto ◽  
Jun-ichi Kadokawa

In this study, we have performed the preparation of reswellable amorphous porous celluloses through regeneration from hydrogels. The cellulose hydrogels were first prepared from solutions with an ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl), in different concentrations. Lyophilization of the hydrogels efficiently produced the regenerated celluloses. The powder X-ray diffraction and scanning electron microscopic measurements of the products suggest an amorphous structure and porous morphology, respectively. Furthermore, the pore sizes of the regenerated celluloses, or in turn, the network sizes of cellulose chains in the hydrogels, were dependent on the concentrations of the initially prepared solutions with BMIMCl, which also affected the tensile mechanical properties. It was suggested that the dissolution states of the cellulose chains in the solutions were different, in accordance with the concentrations, which representatively dominated the pore and network sizes of the above materials. When the porous celluloses were immersed in water, reswelling was observed to regenerate the hydrogels.


2019 ◽  
Vol 223 ◽  
pp. 115058 ◽  
Author(s):  
Muhammad Abdul Haq ◽  
Yasuhiro Habu ◽  
Kazuya Yamamoto ◽  
Akihiko Takada ◽  
Jun-ichi Kadokawa
Keyword(s):  

2016 ◽  
Vol 7 (43) ◽  
pp. 6608-6616 ◽  
Author(s):  
H. Srour ◽  
M. Leocmach ◽  
V. Maffeis ◽  
A. C. Ghogia ◽  
S. Denis-Quanquin ◽  
...  

We describe the preparation as well as the electrochemical and mechanical properties of a series of novel well-defined poly(ionic liquids) (PILs) featuring a finely tuned cross-linking ratio.


2012 ◽  
Vol 499 ◽  
pp. 80-84
Author(s):  
Huai Fang Wang ◽  
Wei Han Huang ◽  
Zhi Kai Wang

A series of blend films of cellulose and chitosan were prepared from 1-ethyl-3-methyl imidazole acetate ([Emim] Ac) by coagulating with ethanol. Structure, mechanical properties, thermal stability and antibacterial properties were investigated. The results showed that there were strong interactions and good compatibility between cellulose and chitosan in blend films. The blend films possess good mechanical properties and thermal stability, and the existence of chitosan endows blend films with antimicrobial property.


2020 ◽  
Vol 861 ◽  
pp. 383-387
Author(s):  
Nantharat Phruksaphithak ◽  
Nophadon Goomuang ◽  
Nattawut Jaema

The effect of cellulose from oil palm trunk (OPT) concentrations (1, 3, 5, and 7 wt %), which were treated various times with urea mixed in NaOH aqueous solution on fabricating cellulose film, were studied. The results showed cellulose from OPT film was successfully prepared through cellulose was dissolved in 7wt% NaOH/12wt% urea aqueous solution at 4°C. The function group was evaluated by FTIR, whereas the physical properties were observed by a camera. The photographs of cellulose film concluded that 5wt% cellulose from OPT had a smoother surface than other ratios. The FTIR result showed that the vibration peak confirmed that cellulose from OPT successfully produced cellulose film. The mechanical properties result showed that urea mixed into cellulose/NaOH suspension after 24 hr presented better mechanical properties than urea mixed immediately. This research provided a friendly environmental system for the preparation of the packaging films.


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