scholarly journals Intermetallic/Ceramic Composites Synthesized from Al–Ni–Ti Combustion with B4C Addition

Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 873
Author(s):  
Chun-Liang Yeh ◽  
Chih-Yao Ke
Keyword(s):  
Combustion Velocity ◽  
Ceramic Composites ◽  
The Other ◽  
X Ray Diffraction ◽  
Temperature Synthesis ◽  
Reaction Systems ◽  
X Ray ◽  
High Temperature Synthesis ◽  
In Situ Formation

The fabrication of intermetallic/ceramic composites by combustion synthesis in the mode of self-propagating high-temperature synthesis (SHS) was investigated in the Al–Ni–Ti system with the addition of B4C. Two reaction systems were employed: one was used to produce the composites of xNiAl–2TiB2–TiC with x = 2–7, and the other was used to synthesize yNi3Al–2TiB2–TiC with y = 2–7. The reaction mechanism of the Al–Ni–Ti system was strongly influenced by the presence of B4C. The reaction of B4C with Ti was highly exothermic, so the reaction temperature and combustion velocity decreased due to increasing levels of Ni and Al in the reactant mixture. The activation energies of Ea = 110.6 and 172.1 kJ/mol were obtained for the fabrication of NiAl- and Ni3Al-based composites, respectively, by the SHS reaction. The XRD (X-ray diffraction) analysis showed an in situ formation of intermetallic (NiAl and Ni3Al) and ceramic phases (TiB2 and TiC) and confirmed no reactions taking place between Ti and Al or Ni. The microstructure of the product revealed large NiAl and Ni3Al grains and small TiB2 and TiC particles. With the addition of TiB2 and TiC, the hardness of NiAl and Ni3Al was considerably increased and the toughness was also improved.

Study on Microstructure and Mechanical Properties of Ni/TiC Composites by Laser Induced Self-Propagating High-Temperature Synthesis

2011 ◽  
Vol 239-242 ◽  
pp. 1072-1075
Author(s):  
Yu Xin Li ◽  
Pei Kang Bai
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Sintered Density ◽  
Bending Strength ◽  
Micro Hardness ◽  
X Ray Diffraction ◽  
Temperature Synthesis ◽  
X Ray ◽  
High Temperature Synthesis

Ni/TiC composites have been produced using laser induced self-propagating high-temperature synthesis. The chemical composition and microstructure were investigated by means of X-ray diffraction and scanning electron microscope. The sintered density and mechanical properties such as bending strength and micro-hardness were also measured. The results showed that the synthesized products were consisted of TiC and Ni phases, which indicated that the TiC was synthesized by the in-situ reaction. Moreover, the results revealed that the sintered density increased and the micro-hardness and bending strength of the synthesized products gradually decreased with the increasing of Ni contents.

PHASE TRANSITION IN LAYERED PEROVSKITE LIKE MANGANATE Ca3Mn2O7 UNDER HIGH PRESSURE

2001 ◽  
Vol 15 (18) ◽  
pp. 2491-2497 ◽  
Author(s):  
J. L. ZHU ◽  
L. C. CHEN ◽  
R. C. YU ◽  
F. Y. LI ◽  
J. LIU ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Diamond Anvil Cell ◽  
The Other ◽  
Layered Perovskite ◽  
X Ray Diffraction ◽  
Two Phase ◽  
X Ray ◽  
Diamond Anvil

In situ high pressure energy dispersive X-ray diffraction measurements on layered perovskite-like manganate Ca 3 Mn 2 O 7 under pressures up to 35 GPa have been performed by using diamond anvil cell with synchrotron radiation. The results show that the structure of layered perovskite-like manganate Ca 3 Mn 2 O 7 is unstable under pressure due to the easy compression of NaCl-type blocks. The structure of Ca 3 Mn 2 O 7 underwent two phase transitions under pressures in the range of 0~35 GPa. One was at about 1.3 GPa with the crystal structure changing from tetragonal to orthorhombic. The other was at about 9.5 GPa with the crystal structure changing from orthorhombic back to another tetragonal.

Self-Propagating High-Temperature Synthesis of Si-SiC Composite Powder

2016 ◽  
Vol 675-676 ◽  
pp. 623-626 ◽  
Author(s):  
Tawat Chanadee ◽  
Sutham Niyomwas
Keyword(s):  
High Temperature ◽  
Composite Powder ◽  
Rice Husk Ash ◽  
Argon Atmosphere ◽  
Composite Powders ◽  
Temperature Synthesis ◽  
X Ray ◽  
High Temperature Synthesis ◽  
Silicon Silicon

Silicon-silicon carbide (Si-SiC) composite powders were synthesized by in-situ self- propagating high-temperature synthesis using rice husk ash (RHA)/carbon/Mg as precursors in argon atmosphere. The as-SHS powders were leached by two leaching steps. The microstructure and chemical composition of the obtained Si-SiC composite powders were examined using scanning electron microscope (SEM) and x-ray diffractometer (XRD), respectively.

A Study of Fe-Based Composite Coating Fabricated by the Self-Propagating High Temperature Synthesis

2012 ◽  
Vol 626 ◽  
pp. 138-142
Author(s):  
Saowanee Singsarothai ◽  
Vishnu Rachpech ◽  
Sutham Niyomwas
Keyword(s):  
High Temperature ◽  
Composite Coating ◽  
Steel Substrate ◽  
The Self ◽  
X Ray Diffraction ◽  
Temperature Synthesis ◽  
X Ray ◽  
High Temperature Synthesis ◽  
Precursor Powders ◽  
Scanning Electron

The steel substrate was coated by Fe-based composite using self-propagating high-temperature synthesis (SHS) reaction of reactant coating paste. The green paste was prepared by mixing precursor powders of Al, Fe2O3and Al2O3. It was coated on the steel substrate before igniting by oxy-acetylene flame. The effect of coating paste thickness and the additives on the resulted Fe-based composite coating was studied. The composite coating was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) couple with dispersive X-ray (EDS).

Compression and Compressibility Studies of Plutonium and a Plutonium-Gallium Alloy

1980 ◽  
Vol 24 ◽  
pp. 221-230 ◽  
Author(s):  
R. B. Roof
Keyword(s):  
Solid Solution ◽  
The Other ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Foils ◽  
Gallium Alloy

Two metal foils, one pure plutonium and the other being a solid solution of 6.5 a/o gallium In plutonium, were examined, in-situ, by X-ray diffraction techniques while under pressure. The purpose was to determine the compression and compressibility of these materials as a function of pressure and to identify the products of any transformation that may occur due to the action of applied pressures.

Effect of CaF2 in Precursors on Steel Pipe Lined Fe-Al Intermetallic-TiB2-Al2O3 Composite Coating by Centrifugal-SHS Process

2012 ◽  
Vol 488-489 ◽  
pp. 468-472 ◽  
Author(s):  
Pajaree Kerdkool ◽  
Sutham Niyomwas
Keyword(s):  
Energy Minimization ◽  
Standard Gibbs Energy ◽  
Raw Materials ◽  
Steel Pipe ◽  
X Ray Diffraction ◽  
Temperature Synthesis ◽  
Minimization Method ◽  
X Ray ◽  
High Temperature Synthesis ◽  
Centrifugal Shs

Steel pipe lined Fe-Al intermetallic-TiB2-Al2O3composite were prepared by centrifugal-self-propagating high temperature synthesis (centrifugal-SHS) process from FeTiO3, B2O3, Fe2O3, Al and CaF2as raw materials. The standard Gibbs energy minimization method was used to calculate the equilibrium compositions of the reacting species. The effect of adding CaF2to the precursors on the result product were investigated. The phase separation between less porosity Fe-Al intermetallics-TiB2with Al2O3layer were affected greatly by adding CaF2. The phase compositions and morphology were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) couple with energy dispersive X-ray (EDX), respectively.

High-Pressure, High-Temperature Synthesis of Superhard Boron Suboxide

1995 ◽  
Vol 410 ◽  
Author(s):  
H. Hubert ◽  
L. A. J. Garvie ◽  
K. Leinenweber ◽  
P. R. Buseck ◽  
W. T. Petuskeyt ◽  
...  
Keyword(s):  
Pressure Range ◽  
X Ray Diffraction ◽  
Temperature Synthesis ◽  
X Ray ◽  
High Temperature Synthesis ◽  
Transmission Electron ◽  
High Pressure High Temperature ◽  
Boron Suboxide ◽  
Electron Energy Loss ◽  
Rhombohedral Boron

ABSTRACTA multianvil device was used to investigate the formation of BxO phases produced in the 2 to 10 GPa pressure range with temperatures between 1000 and 1800 °C.Amorphous and crystalline B and BP were oxidized using B2O3 and CrO3. Using powder X-ray diffraction and parallel electron energy-loss spectroscopy (PEELS), we were unable to detect graphitic or diamondstructured B2O, reported in previous studies. The refractory boride B6O, which has the α-rhombohedral boron structure, is the dominant suboxide in the P and T range of our investigation. PEELS with a transmission electron microscope was used to characterize the boron oxides.

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