scholarly journals Nucleation and Condensation of Magnesium Vapor in Argon Carrier

Metals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1441
Author(s):  
Jibiao Han ◽  
Daxue Fu ◽  
Junhua Guo ◽  
Zonghui Ji ◽  
Zhihe Dou ◽  
...  

The nucleation and condensation of Magnesium (Mg) vapor carried by argon gas (Ar) were examined. The condensation of Mg vapor at a heat source temperature of 1273–1473 K and Ar flow rate of 0.1–0.4 m3/h was analyzed. The result indicated that the condensation temperature is affected by the heat source temperature and Ar flow rate, and the condensation temperature of Mg vapor was 1013.3 K at a heat source temperature of 1473 K and Ar flow rate of 0.2 m3/h. The effects of Mg vapor partial pressure and temperature of the condensation zone on the nucleation and condensation of Mg vapor carried by Ar were calculated and analyzed in terms of atomic collisions and critical nucleation radius. Increased vapor oversaturation and decreased condensation temperature were favorable for liquid nucleation growth. The Mg condensation products in Ar flow rate of 0.2 m3/h at a heat source temperature of 1473 K were analyzed by XRD, SEM, and EDS, which indicated that the condensed product was of high purity and not easily oxidized in Ar flow. In this paper, the quality of Mg vapor condensation was controlled, which provided the theoretical and experimental basis for a continuous Mg production process.

2018 ◽  
Vol 9 (1) ◽  
pp. 49 ◽  
Author(s):  
Peng Li ◽  
Zhonghe Han ◽  
Xiaoqiang Jia ◽  
Zhongkai Mei ◽  
Xu Han ◽  
...  

The organic Rankine cycle (ORC) has been demonstrated to be an effective method for converting low-grade heat energy into electricity. This paper proposes an improved analysis method for the ORC system. A coupling model of the ORC system with a radial-inflow turbine efficiency prediction model is presented. Multi-objective optimization was conducted for a constant turbine efficiency ORC system (ORCCTE) and a predicted turbine efficiency ORC system (ORCDTE), and the optimization results were compared. Additionally, a sensitivity analysis was conducted with respect to the heat source temperature and the ambient temperature. It can be found that the predicted turbine efficiency decreases with the increasing evaporation temperature, and increases with the increasing condensation temperature. The turbine efficiency is not constant and it varies with operating conditions. The distribution of the Pareto frontier for ORCCTE system and ORCCTE system is different. Compared with the ORCCTE system, the ORCDTE system has a lower optimal evaporation temperature, but a higher optimal condensation temperature. The deviation between the predicted turbine efficiency and the constant turbine efficiency increases with the increasing heat source temperature but decreases with the increasing ambient temperature. Thus, the difference in the theoretical analysis results between ORCCTE system and ORCDTE system increases with the increasing heat source temperature but decreases with the increasing ambient temperature.


2011 ◽  
Vol 32 (3) ◽  
pp. 57-70 ◽  
Author(s):  
Dariusz Mikielewicz ◽  
Jarosław Mikielewicz

Utilisation of bleed steam heat to increase the upper heat source temperature in low-temperature ORC In the paper presented is a novel concept to utilize the heat from the turbine bleed to improve the quality of working fluid vapour in the bottoming organic Rankine cycle (ORC). That is a completely novel solution in the literature, which contributes to the increase of ORC efficiency and the overall efficiency of the combined system of the power plant and ORC plant. Calculations have been accomplished for the case when available is a flow rate of low enthalpy hot water at a temperature of 90 °C, which is used for preliminary heating of the working fluid. That hot water is obtained as a result of conversion of exhaust gases in the power plant to the energy of hot water. Then the working fluid is further heated by the bleed steam to reach 120 °C. Such vapour is subsequently directed to the turbine. In the paper 5 possible working fluids were examined, namely R134a, MM, MDM, toluene and ethanol. Only under conditions of 120 °C/40 °C the silicone oil MM showed the best performance, in all other cases the ethanol proved to be best performing fluid of all. Results are compared with the "stand alone" ORC module showing its superiority.


2006 ◽  
Vol 326-328 ◽  
pp. 1275-1278 ◽  
Author(s):  
Chang Oh Kim ◽  
Jin Heung Kim ◽  
Nak Kyu Chung

This study aims to find out cooling characteristics of TMA 25wt%-water clathrate compound with ethanol such as supercooling, phase change temperature and specific heat. For this purpose, ethanol is added as per weight concentration and cooling experiment is performed at -6, -7 and -8, cooling heat source temperature, and it leads the following result. (1) Phase change temperature is decreased due to freezing point depression phenomenon. Especially, it is minimized as 5.1 and 5.0, 3.8 according to cooling source temperature in case that 0.5wt% of ethanol is added. (2) If 0.5wt% of ethanol is added, average supercooling degree is 0.9 and minimum supercooling is 0.8, 0.7 according to cooling heat source temperature. The restraint effect of supercooling is shown. (3) Specific heat shows tendency to decrease if ethanol is added. It is 3.013~3.048 kJ/kgK according to cooling heat source temperature if 0.5wt% of ethanol is added. Phase change temperature higher than that of water and inhibitory effect against supercooling can be confirmed through experimental study on cooling characteristics of TMA 25wt%-water clathrate compound by adding additive, ethanol.


Author(s):  
Rachana Vidhi ◽  
Sarada Kuravi ◽  
Saeb Besarati ◽  
E. K. Stefanakos ◽  
D. Yogi Goswami ◽  
...  

This paper reports on the performance of various organic refrigerants and their mixtures as working fluids for power generation in a supercritical Rankine cycle (SRC) from geothermal sources. Organic fluids that have zero or very low ozone depletion potential and are environmentally safe are selected for this study. Geothermal source temperature is varied from 125–200°C, and the cooling water temperature is changed from 10–20°C. The effect of varying operating conditions on the performance of the thermodynamic cycle has been analyzed. Operating pressure of the cycle has been optimized for thermal efficiency for each fluid at each source temperature. The condensation pressure is determined by the cooling condition and is kept fixed for each condensation temperature. Energy and exergy efficiencies of the cycle have been obtained for the pure fluids as a function of heat source temperature. Mixtures of organic fluids have been analyzed and effect of composition on performance of the thermodynamic cycle has been studied. It is observed that thermal efficiency over 20% can be achieved for 200°C heat source temperature and the lowest cooling temperature. When mixtures are considered as working fluids, the thermal efficiency of the cycle is observed to remain between the thermal efficiencies of the constituent fluids.


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