scholarly journals Influence of Cold Rolling Process and Chemical Composition on the Mechanical Properties and Corrosion Behavior of Zr-Based Metallic Glasses

Metals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1514
Author(s):  
Ali Akbarpour ◽  
Daria A. Milkova ◽  
Erzhena N. Zanaeva ◽  
Mark S. Parkhomenko ◽  
Vladimir V. Cheverikin ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Cold Rolling ◽  
Free Volume ◽  
Photoelectron Spectroscopy ◽  
Shear Bands ◽  
Rolling Process ◽  
Sem Images ◽  
Mechanical Properties And Corrosion ◽  
Xrd Patterns ◽  
Alloy Softening

Cold rolling (CR) with thickness reduction of 10%, 30%, and 50% was applied to Zr50Cu44Al6 and Zr49.5Cu44Al6Nb0.5 metallic glassy ribbon samples. The XRD patterns showed the amorphousness of all samples after casting and CR processes. The SEM images indicated the formation of multiple shear bands (SBs) owing to plastic deformation during CR. However, the addition of 0.5 at% Nb to the alloy changed the SBs’ density and spacing characteristics. The characterization of free volume changes caused by CR was carried out by measuring the density of Archimedes. The micro-hardness of samples was studied by investigating SBs and free volume during plastic deformation. Alloy softening occurred due to the formation of free volume during CR. X-ray photoelectron spectroscopy (XPS) confirmed the presence of oxides ZrO2, CuOx, and AlOx on the surface of the ribbons. The anodic polarization curves of the cast and R50 samples in solutions of NaCl and Na2SO4 (0.5 M) were obtained using potentiodynamic polarization measurements. Compared to CR ribbons, melt-spun ribbons after casting showed better corrosion resistance with lower anodic current densities in Na2SO4 solution.

Effect of Structure Relaxation on the Plastic Deformation Behaviour in a Zr-Based BMG under Indenter

2009 ◽  
Vol 618-619 ◽  
pp. 437-441
Author(s):  
Hao Wen Xie ◽  
Peter D. Hodgson ◽  
Cui E Wen
Keyword(s):  
Plastic Deformation ◽  
Shear Band ◽  
Metallic Glass ◽  
Bulk Metallic Glass ◽  
Free Volume ◽  
Cast Alloy ◽  
Deformation Behaviour ◽  
Shear Bands ◽  
Structure Relaxation ◽  
Effect Of Structure

Vickers and nano indentations were performed on a structurally relaxed Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass (BMG), and the evolution of the shear bands in the relaxed BMG was investigated and compared to that in the as-cast alloy. Results indicate that the plastic deformation in the BMG with structure relaxation is accommodated by the semicircular (primary) and radial (secondary) as well as tertiary shear bands. Quantitatively, the shear band density in the relaxed alloy was much lower than that in the as-cast alloy. The annihilation of free volume caused by the annealing was responsible for the embrittlement of the sample with structure relaxation.

Survival of Goss Grains during Cold Rolling of a Silicon Steel Single Crystal

2005 ◽  
Vol 495-497 ◽  
pp. 1061-1066 ◽  
Author(s):  
Dorothée Dorner ◽  
Ludger Lahn ◽  
Stefan Zaefferer
Keyword(s):  
Cold Rolling ◽  
Single Crystal ◽  
High Strain ◽  
Shear Bands ◽  
Rolling Process ◽  
Silicon Steel ◽  
Oriented Crystal ◽  
Cold Rolled ◽  
Goss Orientation ◽  
Crystal Volume

A silicon steel single crystal with initial Goss orientation, i.e. the {110}<001> orientation, was cold rolled up to 89 % thickness reduction. Most of the crystal volume rotates into the two symmetrical equivalent {111}<112> orientations. However, a weak Goss component is still present after high strain, although the Goss orientation is mechanically instable under plane strain loading. Two types of Goss-oriented crystal volumes are found in the highly deformed material. We suggest that their origin is different. The Goss-oriented regions that are observed within shear bands form during the cold rolling process. In contrast, those Goss-oriented crystal volumes that are found inside of microbands survive the cold rolling.

scholarly journals Free-volume dependent pressure sensitivity of Zr-based bulk metallic glass

2009 ◽  
Vol 24 (8) ◽  
pp. 2697-2704 ◽  
Author(s):  
Alban Dubach ◽  
K. Eswar Prasad ◽  
Rejin Raghavan ◽  
Jorg F. Löffler ◽  
Johann Michler ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Metallic Glass ◽  
Bulk Metallic Glass ◽  
Free Volume ◽  
Structural State ◽  
Shear Bands ◽  
Compressive Yield Strength ◽  
Pressure Sensitivity ◽  
Constraint Factor ◽  
Shear Transformation Zones

Instrumented indentation experiments on a Zr-based bulk metallic glass (BMG) in as-cast, shot-peened and structurally relaxed conditions were conducted to examine the dependence of plastic deformation on its structural state. Results show significant differences in hardness, H, with structural relaxation increasing it and shot peening markedly reducing it, and slightly changed morphology of shear bands around the indents. This effect is in contrast to uniaxial compressive yield strength, σy, which remains invariant with the change in the structural state of the alloys investigated. The plastic constraint factor, C = H/σy, of the relaxed BMG increases compared with that of the as-cast glass, indicating enhanced pressure sensitivity upon annealing. In contrast, C of the shot-peened layer was found to be similar to that observed in crystalline metals, indicating that severe plastic deformation could eliminate pressure sensitivity. Microscopic origins for this result, in terms of shear transformation zones and free volume, are discussed.

Morphological and structural characterization of Pb:ZnS nanostructure films deposited by simple thermal evaporation

2021 ◽  
Author(s):  
Bassam Abdallah ◽  
M. Kakhia ◽  
W. Zetoune ◽  
M. Alwazzeh
Keyword(s):  
Zinc Sulfide ◽  
Photoelectron Spectroscopy ◽  
Thermal Evaporation ◽  
Hexagonal Structure ◽  
Morphological Development ◽  
Sem Images ◽  
Thermal Evaporation Method ◽  
X Ray ◽  
Morphological Modification ◽  
Xrd Patterns

ZnS nanostructure films were deposited by a thermal evaporation method. Two films were prepared; the first was zinc sulfide (undoped ZnS) and the second was Pb-doped zinc sulfide (Pb:ZnS). X-ray photoelectron spectroscopy (XPS) and energy-dispersive X-ray spectroscopy (EDX) techniques were employed to investigate the element contents of the two films; they were found to be stoichiometric. Surface and growth evolution of films were explored by SEM images and found to have morphological development from spherical forms into nanostructure lookalike Taraxacum erythrospermum (Dandelion) with increasing the Pb from 0 wt.% to 12 wt.%. A structural study was performed using XRD patterns. The films have ZnS hexagonal structure (002) preferential orientation with various Pb percentages. In the doped sample, ZnS nanostructure and pores and nanowires (NWs) were formed with a mean diameter less than 50 nm; the undoped film had dense structure and was thin. This study illustrated the influence of Pb doped on the morphological modification of ZnS films.

Process and Properties on the Precision Forming of Spline Cold Rolling

2010 ◽  
Vol 154-155 ◽  
pp. 191-196 ◽  
Author(s):  
Zhi Qi Liu ◽  
Jian Li Song ◽  
Yong Tang Li ◽  
Xu Dong Li ◽  
Ming Fu Wang
Keyword(s):  
Plastic Deformation ◽  
Cold Rolling ◽  
High Efficiency ◽  
Flow Line ◽  
Metal Flow ◽  
Impact Resistance ◽  
Rolling Process ◽  
Plastic Deformation Zone ◽  
Forming Process ◽  
Involute Spline

Cold rolling precision forming process of spline is one of the high-efficiency, precision and non-chip forming advanced manufacturing technologies. It has the characteristics such as high forming efficiency, energy-saving, low material consumption and better forming properties of components. The principle and the force of involute spline cold rolling precision forming process were analyzed. Forming experiments of involute spline cold rolling were carried out, and the microhardness map of the tooth outline was gained. The rule of the metal flow in the deforming area and the forming mechanics of the microstructure were analyzed. The influence of plastic deformation on the forming properties was also conducted. Experimental results showed that dramatic plastic deformation has taken place on the upper surface of the workpiece during the cold rolling process of spline, while the influence on the inner materials were very small. The grains were distributed as a flow line pattern along the tooth profile, and the grains in the plastic deformation zone presented a fine and long fibrous state. The hardness on the section of the tooth outline is regularly distributed. Compared with the spline components obtained from conventional cutting method, the hardness of the spline was greatly increased, therefore, comprehensive mechanical property such as wear resistance and impact resistance were largely improved. Precision measuring and hardness testing of the tooth outline section showed that the components obtained by the experiments were free of defects, and the application requirement can be satisfied.

scholarly journals Edge-Drop Control Behavior for Silicon Strip Cold Rolling with a Sendzimir Mill

Metals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 783 ◽  
Author(s):  
Hongbo Li ◽  
Zhenwei Zhao ◽  
Dawei Dong ◽  
Guomin Han ◽  
Jie Zhang ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Cold Rolling ◽  
Process Parameters ◽  
Work Roll ◽  
Rolling Process ◽  
Transverse Flow ◽  
Control Behavior ◽  
Strip Profile ◽  
Sendzimir Mill ◽  
Edge Drop

Edge-drop control is important for silicon strip cold rolling, as the silicon strip is mainly used as a laminated core. Moreover, cold rolling is the key process for the thin strip edge-drop control, and a Sendzimir mill is one of the most popular cold rolling mills for silicon strips. Thus, the mastery of edge-drop control behavior for silicon strip cold rolling with a Sendzimir mill is beneficial for the improvement of the strip profile quality. With the finite element method, two models are built to analyze the edge-drop control behavior, one is the roll system and strip integrated elastic-plastic deformation statics model, and the other is the strip plastic deformation dynamics model. The first model provides the roll gap contour for the second model, then the strip profile can be calculated in the second model, which considers the transverse flow of the metal. Firstly, the compositions of edge-drop for the silicon strip are analyzed systematically, which are the edge-drop for work roll bending, the edge-drop for work roll flattening, and the edge-drop for transverse flow of the metal. Secondly, the influence of different rolling process parameters on the three parts are analyzed, such as the entrance thickness, the rolling reduction, the rolling tension, and so on; further, the influence of the roll contours are also analyzed. Finally, the edge-drop control behavior of the different rolling process parameters and roll contours are obtained. The research results provide theoretical guidance for edge drop control in the Sendzimir mill.

Studying Temperature Variations that Occurred during Cold and Hot Rolling of AA5454-O Alloy

2017 ◽  
Vol 267 ◽  
pp. 45-51
Author(s):  
Sinan Sezek ◽  
Bunyamin Aksakal
Keyword(s):  
Plastic Deformation ◽  
Temperature Distribution ◽  
Cold Rolling ◽  
Temperature Variation ◽  
Hot Rolling ◽  
Rolling Process ◽  
Laboratory Equipment ◽  
Temperature Variations ◽  
Average Temperature ◽  
Hot And Cold Rolling

In this study, temperature distribution that occurred during cold and hot rolling of AA5454-O alloy has been investigated. Temperature variation taking place in the aluminium alloy that has undergone plastic deformation between the rollers during hot and cold rolling process is of major importance in terms of determining the positive and negative characteristics or features which such temperature variation adds to the formation of the internal structure of the material concerned. Temperature distribution has been measured by use of the installed laboratory equipment and respective data recorded has been presented in the form of graphic charts. Temperature distribution has varied depending on the application of hot or cold rolling process and it has been noted that variations in terms of temperature reduction took place depending on the number of roll passes. While average temperature variation has occurred as a 16°C increase in the case of cold rolling, it has been observed that such variation appeared as a 100°C decrease on the average in the case of hot rolling.

Plastic Deformation and Mechanical Softening of Pd40Cu30Ni10P20 Bulk Metallic Glass During Nanoindentation

2005 ◽  
Vol 20 (10) ◽  
pp. 2719-2725 ◽  
Author(s):  
A. Concustell ◽  
J. Sort ◽  
G. Alcalá ◽  
S. Mato ◽  
A. Gebert ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Metallic Glass ◽  
Bulk Metallic Glass ◽  
Free Volume ◽  
Loading Rate ◽  
Shear Bands ◽  
Control Mode ◽  
Displacement Control ◽  
Softening Effect ◽  
Wide Range

Nanoindentation tests of Pd40Cu30Ni10P20 bulk metallic glass were performed over a wide range of indentation rates (from 0.04 up to 6.4 mN s−1) under the standard load control mode. New results using the feedback displacement control mode are also presented. The dependence of the pop-in formation on the loading rate is investigated. Variations in hardness and reduced elastic modulus as a function of the indentation rate are observed. A softening effect occurs when increasing the loading rate. This is explained by the differences in plastic deformation achieved at different indentation rates. The displacement control mode was used to avoid the shear localization of the free volume, leading to the almost complete absence of pop-ins along the loading curve. The obtained results suggest that plastic flow in bulk metallic glasses is governed by the rate of creation of free volume, which depends on the strain rate and its localization into shear bands.

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