scholarly journals Crystallization Conditions and Petrogenetic Characterization of Metaluminous to Peraluminous Calc-Alkaline Orogenic Granitoids from Mineralogical Systematics: The Case of the Cambrian Magmatism from the Sierra de Guasayán (Argentina)

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 166
Author(s):  
Priscila S. Zandomeni ◽  
Juan A. Moreno ◽  
Sebastián O. Verdecchia ◽  
Edgardo G. Baldo ◽  
Juan A. Dahlquist ◽  
...  
Keyword(s):  
Mineral Chemistry ◽  
Quartz Diorite ◽  
Common Mechanism ◽  
Chemical Compositions ◽  
Magmatic Arc ◽  
Hybrid Nature ◽  
Eastern Sierras Pampeanas ◽  
Microgranular Enclaves ◽  
Mafic Microgranular Enclaves ◽  
Crystallization Conditions

The Sierra de Guasayán (Eastern Sierras Pampeanas, Argentina) is formed by low to medium grade metamorphic rocks intruded by Cambrian metaluminous (La Soledad quartz-diorite), slightly peraluminous (Guasayán, El Escondido and El Martirizado granodiorite plutons), and strongly peraluminous (Alto Bello granodiorite) granitoids of the Pampean magmatic arc. Chemical compositions of amphibole, plagioclase, biotite, and titanite indicate that these granitoids were emplaced at low pressure (mostly <3 kbar) and temperature (<770 °C) under oxidizing conditions (QFM + 1 and QFM + 2), which are similar to the emplacement conditions reported for other granites of the Pampean magmatic arc. Mineral assemblages and whole-rock and mineral chemistry of the granitoids from the Sierra de Guasayán indicate an I-type affinity for the La Soledad quartz-diorite (amphibole, biotite, and titanite), S-type affinity for the Alto Bello granodiorite (biotite, muscovite, cordierite, and sillimanite), and a hybrid nature for the main Guasayán and El Escondido plutons (biotite, monazite, and magnetite). This hybrid nature is supported by the presence of abundant mafic microgranular enclaves and rapakivi texture and by published zircon Hf-isotope data (εHfi ranging from −4.76 to −0.12). This suggests, in turn, the involvement of hybridization in the genesis of these granitoids, which seems to be a common mechanism operating in the Pampean magmatic arc.

scholarly journals Mineralogy, mineral chemistry and thermobarometry of post-mineralization dykes of the Sungun Cu–Mo porphyry deposit (Northwest Iran)

2020 ◽  
Vol 12 (1) ◽  
pp. 764-790
Author(s):  
Amin Allah Kamali ◽  
Mohsen Moayyed ◽  
Nasir Amel ◽  
Fadaeian Mohammad ◽  
Marco Brenna ◽  
...  
Keyword(s):  
Active Continental Margin ◽  
Mineral Chemistry ◽  
Quartz Diorite ◽  
Alkaline Magmatism ◽  
Porphyry Deposit ◽  
Average Percentage ◽  
The North ◽  
Northwestern Iran ◽  
Subduction System ◽  
Late Stages

AbstractThe Sungun copper–molybdenum porphyry deposit is located in the north of Varzaghan, northwestern Iran. The Sungun quartz-monzonite is the oldest mineralized intrusive body in the region and was emplaced during the Early Miocene. Eight categories of the late and unmineralized dykes, which include quartz diorite, gabbrodiorite, diorite, dacite, microdiorite and lamprophyre (LAM), intrude the ore deposit. The main mineral phases in the dykes include plagioclase, amphibole and biotite, with minor quartz and apatite and secondary chlorite, epidote, muscovite and sericite. The composition of plagioclase in the quartz diorite dykes (DK1a, DK1b and DK1c) varies from albite-oligoclase to andesine and oligoclase to andesine; in the diorite, it varies from andesine to labradorite; in the LAM, from albite to oligoclase; and in the microdiorite (MDI), it occurs as albite. Amphibole compositions are consistent with classification as hornblende or calcic amphibole. Based on their AlIV value (less than 1.5), amphibole compositions are consistent with an active continental margin affinity. The average percentage of pistacite (Ps) in epidotes formed from alteration of plagioclase and ferromagnesian minerals is 27–23% and 25–30%, respectively. Thermobarometric studies based on amphibole and biotite indicate approximate dyke crystallization temperature of 850–750℃, pressure of 231–336 MPa and high fO2 (>nickel-nickel-oxide buffer). The range of mineral compositions in the postmineralization dyke suite is consistent with a genetic relationship with the subduction of the Neotethys oceanic crust beneath the continental crust of the northwest part of the Central Iranian Structural Zone. Despite the change from calc-alkaline to alkaline magmatism, the dykes are likely related to the late stages of magmatic activity in the subduction system that also generated the porphyry deposit.

scholarly journals Geochemical signatures of mineralizing events in the Juomasuo Au–Co deposit, Kuusamo belt, northeastern Finland

2021 ◽  
Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  
Keyword(s):  
Trace Element ◽  
Sulfur Isotope ◽  
Mineral Chemistry ◽  
Chemical Compositions ◽  
Metasedimentary Rocks ◽  
Metavolcanic Rocks ◽  
Icp Ms ◽  
Stage 1 ◽  
Host Rocks ◽  
Relationship Of

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.

scholarly journals Petrogenetic and Compositional Features of Rare Metal Pan-African Post-Collisional Pegmatites of Southwestern Nigeria; A Status Review

2018 ◽  
Vol 7 (2) ◽  
pp. 166-187
Author(s):  
Abiola Oyebamiji ◽  
Adeniyi JohnPaul Adewumi ◽  
Tehseen Zafar ◽  
Adegbola Odebunmi ◽  
Philips Falae ◽  
...  
Keyword(s):  
Mineral Chemistry ◽  
Rare Metal ◽  
Border Zone ◽  
Chemical Compositions ◽  
Molten Material ◽  
Southwestern Nigeria ◽  
Pan African ◽  
Opening And Closing ◽  
High Degree ◽  
Rare Metal Pegmatite

Abstract This research reviews the geology, petrogenesis, compositional trends and geochronology of the rare-metal pegmatite of southwestern Nigeria. The source of these pegmatites is still presently debated which have been explained as either product of highly fractionated molten material or anatexis of the local crust. However, published works of past authors have been compiled to give a detailed understanding of the formation of the mineral deposits. The basement complex of southwestern Nigeria comprises of Precambrian rocks of amphibolite, the hornblende gneiss and the granite gneisses which were formed as a result of the opening and closing of the ensialic basin with significant, extensive subduction during the Pan-African orogeny. The pegmatites in this region have shown internal zoning and a high degree of evolution from the border zone to the core zone during the crystallization and solidification of the felsic granite to pegmatite melt. The rare-metal pegmatites have distinct chemical compositions and mineralogy, containing quartz, biotite, muscovite, microcline, garnet with localized tourmaline, tantalite and columbite. These pegmatites vary significantly by their bulk-rock and mineral chemistry which indicates a more peraluminous attribute and enrichments of lithophile elements of Rb, Cs, Ta and Ba. Previous K/Ar isotopic ages (502.8±13.0 Ma and 514.5±13.2 Ma) suggest that the pegmatites are related to the post-collisional phase of intensive metasomatism. Adopted from previous studies, a five-stage conceptual model of evolution which is widely accepted have been proposed for the origin of the pegmatites.

scholarly journals The Nordre Strømfjord shear zone and the Arfersiorfik quartz diorite in Arfersiorfik, the Nagssugtoqidian orogen, West Greenland

2006 ◽  
Vol 11 ◽  
pp. 145-162 ◽  
Author(s):  
Kai Sørensen ◽  
John A. Korstgård ◽  
William E. Glassley ◽  
Bo Møller Stensgaard
Keyword(s):  
Shear Zone ◽  
Volcanic Rocks ◽  
Quartz Diorite ◽  
Ductile Deformation ◽  
Chemical Compositions ◽  
West Greenland ◽  
South West ◽  
Wide Range ◽  
Inland Ice ◽  
Zone Deformation

The Nordre Strømfjord shear zone in the fjord Arfersiorfik, central West Greenland, consists of alternating panels of supracrustal rocks and orthogneisses which together form a vertical zone up to 7 km wide with sinistral transcurrent, ductile deformation, which occurred under middle amphibolite facies conditions. The pelitic and metavolcanic schists and paragneisses are all highly deformed, while the orthogneisses appear more variably deformed, with increasing deformation evident towards the supracrustal units. The c. 1.92 Ga Arfersiorfik quartz diorite is traceable for a distance of at least 35 km from the Inland Ice towards the west-south-west. Towards its northern contact with an intensely deformed schist unit it shows a similar pattern of increasing strain, which is accompanied by chemical and mineralogical changes. The metasomatic changes associated with the shear zone deformation are superimposed on a wide range of original chemical compositions, which reflect magmatic olivine and/ or pyroxene as well as hornblende fractionation trends. The chemistry of the Arfersiorfik quartz diorite suite as a whole is comparable to that of Phanerozoic plutonic and volcanic rocks of calc-alkaline affinity.

scholarly journals Petrology, mineral chemistry, and geochemistry of Late Triassic Ni–Cu ore-bearing mafic–ultramafic intrusions, Hongqiling, northeastern China: petrogenesis and tectonic implications

2019 ◽  
Vol 56 (2) ◽  
pp. 111-128
Author(s):  
Ai Li ◽  
Jian Wang ◽  
Yue Song
Keyword(s):  
Crustal Contamination ◽  
Parental Magma ◽  
Mineral Chemistry ◽  
Late Triassic ◽  
Sulfide Deposit ◽  
Chemical Compositions ◽  
Tholeiitic Magma ◽  
Average Value ◽  
Central Asian ◽  
History Of

The Hongqiling magmatic Ni–Cu sulfide deposit, situated on the southern margin of the eastern Central Asian Orogenic Belt (CAOB), is composed of over 30 mafic–ultramafic intrusions. These ore-bearing intrusions are composed mainly of harzburgite, lherzolite, websterite, orthopyroxenite, and norite (gabbro). The constituent minerals are olivine, diopside, bronzite, calcic-hornblende, plagioclase, and spinel with orthopyroxene as a dominant mineral in these intrusions. These ore-bearing intrusions are not Alaskan-type complexes. Spinel and clinopyroxene both exhibit different chemical compositions from those in the Alaskan-type complexes. The rocks that make up the intrusions have high contents of MgO (average value = 25.20 wt.%) and low TiO2 (average value = 0.58 wt.%). The high MgO contents of the minerals and the high Mg# (71) of the calculated melt in equilibrium with olivine demonstrate that the parental magma of the Hongqiling mafic–ultramafic intrusions was a high-Mg tholeiitic magma. The Hongqiling ore-bearing mafic–ultramafic intrusions and the calculated “trapped liquids” for the olivine-orthopyroxene cumulate rocks are all enriched in large-ion lithophile elements and depleted in high field strength elements. The Ce/Pb, Ta/La, Th/Yb, and (La/Sm)PM values and the depletion of Nb and Ta suggest that the magma experienced crustal contamination. The Hongqiling ore-bearing intrusions display many similarities with mafic–ultramafic intrusions that formed in a post-collisional extensional environment in the western CAOB (e.g., Huangshanxi). Common features include their whole-rock compositions and mineral chemistry. Combined with the evolutionary history of the eastern segment of the CAOB, we believe that the Late Triassic Hongqiling mafic–ultramafic intrusions formed in a post-collisional extensional environment.

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