scholarly journals Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.

2003 ◽  
Vol 67 (5) ◽  
pp. 831-853 ◽  
Author(s):  
R. Halama ◽  
T. Wenzel ◽  
B. G. J. Upton ◽  
W. Siebel ◽  
G. Markl

AbstractBasalts from the volcano-sedimentary Eriksfjord Formation (Gardar Province, South Greenland) were erupted at around 1.2 Ga into rift-related graben structures. The basalts have compositions transitional between tholeiite and alkaline basalt with MgO contents <7 wt.% and they display LREE-enrichment relative to a chondritic source. Most of the trace element and REE characteristics are similar to those of basalts derived from OIB-like mantle sources. Initial 87Sr/86Sr ratios of clinopyroxene separates range from 0.70278 to 0.70383 and initial ϵNd values vary from –3.2 to +2.1. The most unradiogenic samples overlap with the field defined by carbonatites of similar age and can be explained by mixing of isotopically depleted and enriched mantle components. Using AFC modelling equations, the Sr-Nd isotope data of the more radiogenic basalts can successfully be modelled by addition of <5% lower crustal granulite-facies gneisses as contaminants. δ18Ov-smow values of separated clinopyroxene range from +5.2 to +6.0% and fall within the range of typical mantle-derived rocks. However, up to 10% mixing with an average lower crustal component are permitted by the data.


2001 ◽  
Vol 138 (4) ◽  
pp. 371-386 ◽  
Author(s):  
ANDERS LINDH ◽  
ULF BERTIL ANDERSSON ◽  
THOMAS LUNDQVIST ◽  
STEFAN CLAESSON

Gabbro and leucogabbro are volumetrically important rocks in the Nordingrå rapakivi complex, East Central Sweden. Plagioclase, ortho- and clinopyroxenes, and olivine dominate the gabbro. Perthitic orthoclase and quartz are interstitial in relation to the major minerals. The present work is based on 232 major-element and a large number of trace element analyses together with 15 whole rock Sm–Nd isotope analyses of the Nordingrå gabbroic rocks. εNd(T) values are negative, −1.1 to −3.2; the most negative values come from the gabbro. Most rocks are enriched in iron, some extremely enriched; none represent primitive mantle melts. The range of Mg-numbers is the same in the gabbro and the leucogabbro. Plots of the Ni-content vs. the Mg-number are scattered, but there is a positive correlation between these two parameters. The primary mantle-normalized ratios between similar trace elements are normally strongly different from one. Values larger as well as smaller than one are found for the same ratio in different rocks. The rare earth elements are only weakly fractionated with small Eu anomalies, negative for the gabbros and positive for the leucogabbros. The primary magma of the Nordingrå gabbro-anorthosite is thought to have been derived from a mildly depleted mantle source. Variations in the degree of partial melting of a reasonably homogeneous enriched mantle do not explain the observed chemical evolution. Crystal differentiation can account for some geochemical features, especially the Fe-enrichment. Crustal contamination is required by other characteristics as, for example, the negative εNd(T) values and the irregular and sometimes high primary-mantle normalized incompatible trace-element ratios. Al-rich relic material from the formation of the rapakivi granite melt is another source of assimilation. Most probably contaminants are heterogeneous, including undepleted crust (represented, for example, by early Svecofennian and Archaean granitoids), depleted crust (restitic after rapakivi magma extraction), and to some degree the associated rapakivi magma itself. Significant parts of this crust should be Archaean in age.


1995 ◽  
Vol 7 (1) ◽  
pp. 73-85 ◽  
Author(s):  
A.D. Morrison ◽  
A. Reay

At Terra Cotta Mountain, in the Taylor Glacier region of south Victoria Land, a 237 m thick Ferrar Dolerite sill is intruded along the unconformity between basement granitoids and overlying Beacon Supergroup sedimentary rocks. Numerous Ferrar Dolerite dykes intrude the Beacon Supergroup and represent later phases of intrusion. Major and trace element data indicate variation both within and between the separate intrusions. Crystal fractionation accounts for much of the geochemical variation between the intrusive events. However, poor correlations between many trace elements require the additional involvement of open system processes. Chromium is decoupled from highly incompatible elements consistent with behaviour predicted for a periodically replenished, tapped and fractionating magma chamber. Large ion lithophile element-enrichment and depletion in Nb, Sr, P and Ti suggests the addition of a crustal component or an enriched mantle source. The trace element characteristics of the Dolerites from Terra Cotta Mountain are similar to those of other Ferrar Group rocks from the central Transantarctic Mountains and north Victoria Land, as well as with the Tasmanian Dolerites. This supports current ideas that the trace element signature of the Ferrar Group is inherited from a uniformly enriched mantle source region.


2010 ◽  
Vol 58 ◽  
pp. 35-65
Author(s):  
Paul Martin Holm ◽  
L.E. Pedersen, ◽  
B Højsteen

More than 250 dykes cut the mid Proterozoic basement gneisses and granites of Bornholm. Most trend between NNW and NNE, whereas a few trend NE and NW. Field, geochemical and petrological evidence suggest that the dyke intrusions occurred as four distinct events at around 1326 Ma (Kelseaa dyke), 1220 Ma (narrow dykes), 950 Ma (Kaas and Listed dykes), and 300 Ma (NW-trending dykes), respectively. The largest dyke at Kelseaa (60 m wide) and some related dykes are primitive olivine tholeiites, one of which has N-type MORB geochemical features; all are crustally contaminated. The Kelseaa type magmas were derived at shallow depth from a fluid-enriched, relatively depleted, mantle source,but some have a component derived from mantle with residual garnet. They are suggested to have formed in a back-arc environment. The more than 200 narrow dykes are olivine tholeiites (some picritic), alkali basalts, trachybasalts, basanites and a few phonotephrites. The magmas evolved by olivine and olivine + clinopyroxene fractionation. They have trace element characteristics which can be described mainly by mixing of two components: one is a typical OIB-magma (La/Nb < 1, Zr/Nb = 4, Sr/Nd = 16) and rather shallowly derived from spinel peridotite; the other is enriched in Sr and has La/Nb = 1.0 - 1.5, Zr/Nb = 9, Sr/Nd = 30 and was derived at greater depth, probably from a pyroxenitic source. Both sources were probably recycled material in a mantle plume. A few of these dykes are much more enriched in incompatible elements and were derived from garnet peridotite by a small degree of partial melting. The Kaas and Listed dykes (20-40 m) and related dykes are evolved trachybasalts to basaltic trachyandesites. They are most likely related to the Blekinge Dalarne Dolerite Group. The few NW-trending dykes are quartz tholeiites, which were generated by large degrees of rather shallow melting of an enriched mantle source more enriched than the source of the older Bornholm dykes. The source of the NW-trending dykes was probably a very hot mantle plume.


2010 ◽  
Vol 51 (10) ◽  
pp. 2089-2120 ◽  
Author(s):  
A. le Roex ◽  
C. Class ◽  
J. O'Connor ◽  
W. Jokat

Author(s):  
R. J. Pankhurst ◽  
M. J. Hole ◽  
M. Brook

ABSTRACTThe genesis of subduction-related magmas in the Andean region of South America and the Antarctic Peninsula is considered in relation to the Palaeozoic to Cenozoic granitoids belts which are thought to parallel palaeo-coastlines. Their Sr-Nd isotope systematics show a wide range of initial compositions (87Sr/86Sr0 0·7038 to >0·710; εNd, +4 to –10) requiring material input from both depleted mantle and continental crust. In local transects there are consistent trends with time of emplacement, from enriched (crustal) to depleted (mantle) sources, regardless of the sense of migration of magmatism (towards or away from the continent). These trends represent mixing between mantle-derived material and anatectic melts of the lower crust: in each case the crustal end-member reflects the age and isotopic composition of the local deep crustal basement (Precambrian in the easternmost Andes, Palaeozoic in the W and in the Antarctic Peninsula). The depleted end-member could be derived by melting within the subducted oceanic crust, the overlying mantle or previously crystallised mafic underplating. One of the most important factors controlling the mixing process is the angle of subduction, resulting in magma generation under variable tectonic conditions.


1991 ◽  
Vol 18 (7) ◽  
pp. 1301-1304 ◽  
Author(s):  
P. K. Kepezhinskas ◽  
K. B. Kepezhinskas ◽  
I. S. Pukhtel

2021 ◽  
Vol 177 (1) ◽  
Author(s):  
M. Kirchenbaur ◽  
S. Schuth ◽  
A. R. Barth ◽  
A. Luguet ◽  
S. König ◽  
...  

AbstractMany terrestrial silicate reservoirs display a characteristic depletion in Nb, which has been explained in some studies by the presence of reservoirs on Earth with superchondritic Nb/Ta. As one classical example, K-rich lavas from the Sunda rear-arc, Indonesia, have been invoked to tap such a high-Nb/Ta reservoir. To elucidate the petrogenetic processes active beneath the Java rear-arc and the causes for the superchondritic Nb/Ta in some of these lavas, we studied samples from the somewhat enigmatic Javanese rear-arc volcano Muria, which allow conclusions regarding the across-arc variations in volcanic output, source mineralogy and subduction components. We additionally report some data for an along-arc sequence of lavas from the Indonesian part of the Sunda arc, extending from Krakatoa in the west to the islands of Bali and Lombok in the east. We present major and trace element concentrations, Sr–Nd–Hf–Pb isotope compositions, and high-field-strength element (HFSE: Nb, Ta, Zr, Hf, W) concentrations obtained via isotope dilution and MC-ICP-MS analyses. The geochemical data are complemented by melting models covering different source compositions with slab melts formed at variable P–T conditions. The radiogenic isotope compositions of the frontal arc lavas in combination with their trace element systematics confirm previously established regional variations of subduction components along the arc. Melting models show a clear contribution of a sediment-derived component to the HFSE budget of the frontal arc lavas, particularly affecting Zr–Hf and W. In contrast, the K-rich rear-arc lavas tap more hybrid and enriched mantle sources. The HFSE budget of the rear-arc lavas is in particular characterized by superchondritic Nb/Ta (up to 25) that are attributed to deep melting involving overprint by slab melts formed from an enriched garnet–rutile-bearing eclogitic residue. Sub-arc slab melting was potentially triggered along a slab tear beneath the Sunda arc, which is the result of the forced subduction of an oceanic basement relief ~ 8 Myr ago as confirmed by geophysical studies. The purported age of the slab tear coincides with a paucity in arc volcanism, widespread thrusting of the Javanese basement crust as well as the short-lived nature of the K-rich rear-arc volcanism at that time.


2006 ◽  
Vol 44 (7) ◽  
pp. 729-735 ◽  
Author(s):  
K. N. Egorov ◽  
L. V. Solov’eva ◽  
V. P. Kovach ◽  
Yu. V. Men’shagin ◽  
M. N. Maslovskaya ◽  
...  

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