scholarly journals Evidence of crustal contamination of mafic rocks associated with rapakivi rocks: an example from the Nordingrå complex, Central Sweden

2001 ◽  
Vol 138 (4) ◽  
pp. 371-386 ◽  
Author(s):  
ANDERS LINDH ◽  
ULF BERTIL ANDERSSON ◽  
THOMAS LUNDQVIST ◽  
STEFAN CLAESSON
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Incompatible Trace Element ◽  
Primitive Mantle ◽  
Nd Isotope ◽  
East Central ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Two Parameters ◽  
Isotope Analyses

Gabbro and leucogabbro are volumetrically important rocks in the Nordingrå rapakivi complex, East Central Sweden. Plagioclase, ortho- and clinopyroxenes, and olivine dominate the gabbro. Perthitic orthoclase and quartz are interstitial in relation to the major minerals. The present work is based on 232 major-element and a large number of trace element analyses together with 15 whole rock Sm–Nd isotope analyses of the Nordingrå gabbroic rocks. εNd(T) values are negative, −1.1 to −3.2; the most negative values come from the gabbro. Most rocks are enriched in iron, some extremely enriched; none represent primitive mantle melts. The range of Mg-numbers is the same in the gabbro and the leucogabbro. Plots of the Ni-content vs. the Mg-number are scattered, but there is a positive correlation between these two parameters. The primary mantle-normalized ratios between similar trace elements are normally strongly different from one. Values larger as well as smaller than one are found for the same ratio in different rocks. The rare earth elements are only weakly fractionated with small Eu anomalies, negative for the gabbros and positive for the leucogabbros. The primary magma of the Nordingrå gabbro-anorthosite is thought to have been derived from a mildly depleted mantle source. Variations in the degree of partial melting of a reasonably homogeneous enriched mantle do not explain the observed chemical evolution. Crystal differentiation can account for some geochemical features, especially the Fe-enrichment. Crustal contamination is required by other characteristics as, for example, the negative εNd(T) values and the irregular and sometimes high primary-mantle normalized incompatible trace-element ratios. Al-rich relic material from the formation of the rapakivi granite melt is another source of assimilation. Most probably contaminants are heterogeneous, including undepleted crust (represented, for example, by early Svecofennian and Archaean granitoids), depleted crust (restitic after rapakivi magma extraction), and to some degree the associated rapakivi magma itself. Significant parts of this crust should be Archaean in age.

scholarly journals Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Crustal Evolution ◽  
Trace Element Data ◽  
The Urals ◽  
Nd Isotope ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
Geochemical Specialization

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.

scholarly journals Nd-Hf isotope geochemistry and lithogeochemistry of the Rambler Rhyolite, Ming VMS deposit, Baie Verte Peninsula, Newfoundland: evidence for slab melting and implications for VMS localization

2021 ◽  
Author(s):  
S J Piercey ◽  
J -L Pilote
Keyword(s):  
Rare Earth ◽  
Trace Element ◽  
Isotope Geochemistry ◽  
Primitive Mantle ◽  
Isotopic Data ◽  
Depleted Mantle ◽  
Element Enrichment ◽  
Felsic Volcanic ◽  
Magmatic History ◽  
Felsic Rocks

New high precision lithogeochemistry and Nd and Hf isotopic data were collected on felsic rocks of the Rambler Rhyolite formation from the Ming volcanogenic massive sulphide (VMS) deposit, Baie Verte Peninsula, Newfoundland. The Rambler Rhyolite formation consists of intermediate to felsic volcanic and volcaniclastic rocks with U-shaped primitive mantle normalized trace element patterns with negative Nb anomalies, light rare earth element-enrichment (high La/Sm), and distinctively positive Zr and Hf anomalies relative to surrounding middle rare earth elements (high Zr-Hf/Sm). The Rambler Rhyolite samples have epsilon-Ndt = -2.5 to -1.1 and epsilon-Hft = +3.6 to +6.6; depleted mantle model ages are TDM(Nd) = 1.3-1.5 Ga and TDM(Hf) = 0.9-1.1Ga. The decoupling of the Nd and Hf isotopic data is reflected in epsilon-Hft isotopic data that lies above the mantle array in epsilon-Ndt -epsilon-Hft space with positive ?epsilon-Hft values (+2.3 to +6.2). These Hf-Nd isotopic attributes, and high Zr-Hf/Sm and U-shaped trace element patterns, are consistent with these rocks having formed as slab melts, consistent with previous studies. The association of these slab melt rocks with Au-bearing VMS mineralization, and their FI-FII trace element signatures that are similar to rhyolites in Au-rich VMS deposits in other belts (e.g., Abitibi), suggests that assuming that FI-FII felsic rocks are less prospective is invalid and highlights the importance of having an integrated, full understanding of the tectono-magmatic history of a given belt before assigning whether or not it is prospective for VMS mineralization.

Origin of Late Triassic mafic–ultramafic intrusions in the Hongqiling Ni–Cu sulfide deposit, Northeast China: evidence from trace element and Sr–Nd isotope geochemistry

2018 ◽  
Vol 55 (12) ◽  
pp. 1312-1323 ◽  
Author(s):  
Xinyun Zhao ◽  
Libo Hao ◽  
Qiaoqiao Wei ◽  
Qingqing Liu ◽  
Jian Zhou ◽  
...  
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Northeast China ◽  
Eastern China ◽  
Crustal Contamination ◽  
Late Triassic ◽  
Substantial Contribution ◽  
Sulfide Deposit ◽  
Magma Evolution ◽  
Depleted Mantle

There are many Late Triassic mafic–ultramafic intrusions in the Hongqiling magmatic Ni–Cu sulfide deposit, Northeast China. Research on magma evolution leading to formation of these mafic–ultramafic intrusions is of great significance for understanding the mantle beneath Northeast China and associated Ni–Cu mineralization. A trace element study of the No. 1, 3, and 7 intrusions in the Hongqiling deposit reveals that these mafic–ultramafic intrusions are characterized by enrichment of incompatible elements, which however cannot be interpreted by subduction modification. Furthermore, model of batch partial melting of depleted mantle accompanied by upper crustal contamination can simulate the trace element patterns of these mafic–ultramafic intrusions, but partial melting of depleted mantle accompanied by lower crustal contamination model cannot work. In addition, Sr–Nd isotopic compositions of the Hongqiling No. 1, 3, and 7 intrusions also indicate that crustal contamination could have occurred mainly during the magma ascent. Consequently, a possible scenario for the magma evolution is that the primary mafic–ultramafic magma was derived from batch partial melting of a depleted mantle, and then contaminated by Cambrian–Ordovician metamorphic rocks of the Hulan Group during ascent. We conclude that the mantle source contained no significant crustal component in the Late Triassic and was also independent of substantial contribution from subducted material, and therefore the Mesozoic large-scale lithospheric delamination beneath eastern China may happen after a period of time of the Late Triassic.

Oxygen-Hafnium-Neodymium Isotope Constraints on the Origin of the Talnakh Ultramafic-Mafic Intrusion (Norilsk Province, Russia)

2020 ◽  
Vol 115 (6) ◽  
pp. 1195-1212 ◽  
Author(s):  
Kreshimir N. Malitch ◽  
Elena A. Belousova ◽  
William L. Griffin ◽  
Laure Martin ◽  
Inna Yu. Badanina ◽  
...  
Keyword(s):  
Crustal Contamination ◽  
Ultramafic Rocks ◽  
Magma Chambers ◽  
Nd Isotope ◽  
Crustal Component ◽  
Depleted Mantle ◽  
Magma Sources ◽  
A Minor ◽  
T Values

Abstract The ultramafic-mafic Talnakh intrusion in the Norilsk province (Russia) hosts one of the world’s major platinum group element (PGE)-Cu-Ni sulfide deposits. This study employed a multitechnique approach, including in situ Hf-O isotope analyses of zircon combined with whole-rock Nd isotope data, in order to gain new insights into genesis of the Talnakh economic intrusion. Zircons from gabbrodiorite, gabbroic rocks of the layered series, and ultramafic rocks have similar mantle-like mean δ18O values (5.39 ± 0.49‰, n = 27; 5.64 ± 0.48‰, n = 34; and 5.28 ± 0.34‰, n = 7, respectively), consistent with a mantle-derived origin for the primary magma(s) parental to the Talnakh intrusion. In contrast, a sulfide-bearing taxitic-textured troctolite from the basal part of intrusion has high δ18O (mean of 6.50‰, n = 3), indicating the possible involvement of a crustal component during the formation of sulfide-bearing taxitic-textured rocks. The Hf isotope compositions of zircon from different rocks of the Talnakh intrusion show significant variations, with ɛHf(t) values ranging from –3.2 to 9.8 for gabbrodiorite, from –4.3 to 11.6 for unmineralized layered-sequence gabbroic rocks, from 2.3 to 12 for mineralized ultramafic rocks, and from –3.5 to 8.8 for mineralized taxitic-textured rocks at the base of the intrusion. The significant range in the initial 176Hf/177Hf values is ascribed to interaction of distinct magma sources during formation of the Talnakh intrusion. These include (1) a juvenile source equivalent to the depleted mantle, (2) a subcontinental lithospheric source, and (3) a minor crustal component. Initial whole-rock Nd isotope compositions of the mineralized taxitic-textured rocks from the base of the intrusion (mean ɛNd(t) = –1.5 ± 1.8) differ from the other rocks, which have relatively restricted ranges in initial ɛNd (mean ɛNd = 0.9 ± 0.2). The major set of ɛNd values around 1.0 at Talnakh is attributed to limited crustal contamination, presumably in deep magma chambers, whereas the smaller set of negative ɛNd values in taxitic-textured rocks is consistent with greater involvement of a crustal component and reflects an interaction with the wall rocks during emplacement.

A comparison of Eastern North America and Coastal New England magma suites: implications for subcontinental mantle evolution and the broad-terrane hypothesis

2005 ◽  
Vol 42 (9) ◽  
pp. 1571-1587 ◽  
Author(s):  
Michael J Dorais ◽  
Matthew Harper ◽  
Susan Larson ◽  
Hendro Nugroho ◽  
Paul Richardson ◽  
...  
Keyword(s):  
North America ◽  
New England ◽  
Trace Element ◽  
Crustal Contamination ◽  
Flood Basalt ◽  
Incompatible Trace Element ◽  
Eastern North America ◽  
Mantle Evolution ◽  
Isotopic Compositions ◽  
Maritime Canada

New England and Maritime Canada host two major suites of Mesozoic diabase dykes. The oldest is the Coastal New England dykes that were emplaced between 225 and 230 Ma. These rocks are dominantly alkaline with trace element and isotopic compositions indicative of a high-238U/204Pb mantle (HIMU) source. The oldest of the ~200 Ma Mesozoic rift magmas is represented by the Talcott basalt of the Hartford basin and its feeder dykes. External to the basin is the compositionally equivalent Higganum dyke. The extension of the Higganum, the Onway dyke in New Hampshire, is identical in major and trace element and isotopic compositions indicating that the dyke system represented a feeder to flows of flood basalt proportions. The Talcott system rocks have some trace element similarities with arc basalts and have been interpreted as representing melts of a subduction zone modified mantle beneath the Laurentian- Gondwanan suture. Incompatible trace element ratios and Ba, Th, and U values are, however, unlike arc basalts and are more indicative of crustal contamination of the primary magma. The coastal New England magmas have oceanic island basalt signatures that are generally thought to represent plume-tail magmatism, which is antithetic to a plume-head origin for the younger eastern North America magmas. However, coastal New England rocks have the same trace element signatures as the alkaline rocks of the Loihi seamount, which represent the pre-shield stage to the voluminous tholeiitic magmatism in Hawaii.

Differentiation and source of the Nipissing Diabase intrusions, Ontario, Canada

1993 ◽  
Vol 30 (6) ◽  
pp. 1123-1140 ◽  
Author(s):  
P. C. Lightfoot ◽  
H. de Souza ◽  
W. Doherty
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Primitive Mantle ◽  
Magma Source ◽  
Magma Type ◽  
Ni Content ◽  
Chemical Signatures ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Major and trace element data are presented for 2.2 Ga Proterozoic diabase sills from across the Nipissing magmatic province of Ontario. In situ differentiation of the magma coupled with assimilation of Huronian Supergroup roof sediments is responsible for the variation in composition between quartz diabase and granophyric diabase seen within many of the differentiated intrusions. Uniform trace element and isotope ratio signatures, such as La/Sm (2.8 – 3.7) and εNdCHUR (−2.7 to −5.9) characterize chilled margins and undifferentiated quartz diabases. These chemical signatures suggest the existence of a single magma source that was parental to intrusions throughout the magmatic province; this magma has higher La/Sm and lower Ti/Y than primitive mantle and is displaced towards the composition of shales. Most chilled diabases and quartz diabases have a similar Mg# (0.64 and 0.60) and Ni content (98 and 127 ppm), and it is argued that the magma differentiated at depth and was emplaced as a uniform low-Mg magma. The Wanapitei intrusion and Kukagami Lake sill are an exception in that although the quartz diabase has La/Sm similar to the Nipissing magma type, which suggests that they came from the same source, the Mg# (0.68–0.71) and Ni content (130–141 ppm) are higher, which may suggest that they are either slightly more primitive examples of the normal Nipissing magma or that cumulus hypersthene has been resorbed. The light rare earth element enriched signature of the Nipissing magmas was perhaps introduced from the continental crust as the magma migrated from the mantle to the surface, but a remarkably constant and large amount (>20%) of crustal contamination would be required. An addition of 1 –3% shale to the source of a transitional mid-ocean ridge basalt type magma can broadly reproduce the compositional features of the Nipissing magma type. The source characteristics were perhaps imparted during subduction accompanying the terminal Kenoran orogeny.

An application of Nd isotope mapping in structural geology: delineating an allochthonous Grenvillian terrane at North Bay, Ontario

2003 ◽  
Vol 140 (5) ◽  
pp. 539-548 ◽  
Author(s):  
A. P. DICKIN ◽  
R. H. MCNUTT
Keyword(s):  
Structural Geology ◽  
Amphibolite Facies ◽  
High Grade ◽  
Grenville Province ◽  
Nd Isotope ◽  
Bay Area ◽  
The North ◽  
Depleted Mantle ◽  
Different Types ◽  
Isotope Analyses

Fifty new Nd isotope analyses are presented from the North Bay area of the Grenville Province in Ontario. These data are used to map the extent of an allochthonous Grenvillian terrane which is an outlier of the Allochthonous Polycyclic Belt of the Grenville Province. Amphibolite facies orthogneisses from the allochthonous terrane have depleted mantle Nd model ages (TDM) below 1.8 Ga, whereas the gneisses of the structurally underlying parautochthon almost invariably have model ages above 1.8 Ga. The distribution of model ages is consistent with the distribution of distinct types of metabasic rock, used by other researchers as the criterion for recognizing rocks of the allochthonous and parautochthonous belts of the Grenville Province. The agreement between these different types of evidence demonstrates that Nd isotope mapping is a reliable and powerful tool for mapping terrane boundaries in high-grade metamorphic belts.

scholarly journals The alkaline intraplate volcanism of the Antalya nappes (Turkey): a Late Triassic remnant of the Neotethys

2008 ◽  
Vol 179 (4) ◽  
pp. 397-410 ◽  
Author(s):  
René C. Maury ◽  
Henriette Lapierre ◽  
Delphine Bosch ◽  
Jean Marcoux ◽  
Leopold Krystyn ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Late Triassic ◽  
Primitive Mantle ◽  
Heavy Rare Earth Element ◽  
Alkali Basalts ◽  
Crustal Component ◽  
Ocean Island ◽  
Ocean Island Basalts ◽  
Enriched Mantle

AbstractLate Triassic submarine alkali basalts and hawaiites were collected from two superimposed tectonic slices belonging to the Kara Dere – Sayrun unit of the Middle Antalya nappes, southwestern Turkey. New determinations on conodont faunas allow to date this sequence to the Lower Carnian (Julian). The volcanic rocks show rather homogeneous compositions, with high TiO2 and relatively low MgO and Ni contents which suggest olivine fractionation. Their primitive mantle-normalised multi-elements plots show Nb and Ta enrichments relative to La, Pb negative anomalies and heavy rare earth element and Y depletions typical of intraplate ocean island basalts. These characteristics are consistent with the major and trace element compositions of their primary clinopyroxene phenocrysts, which do not show any feature ascribable to crustal contamination. The studied lavas display a restricted range of εNd (+4.6 to +5.2) which falls within the range of ocean island basalts. Their initial (143Nd/144Nd)i ratios are too low to be explained by a simple mixing line between depleted MORB mantle (DMM) and HIMU components. Their Pb and Nd isotopic compositions plot along a mixing line between HIMU component and an enriched mantle, the composition of which could be the result of the addition of about 5 to 8% of an EM2 component (recycled marine sediments) to DMM. The lack of evidence for any continental crustal component in their genesis could be consistent with their emplacement in an intra-oceanic setting.

A geochemical and Sr-Nd-O isotopic study of the Proterozoic Eriksfjord Basalts, Gardar Province, South Greenland: Reconstruction of an OIB signature in crustally contaminated rift-related basalts

2003 ◽  
Vol 67 (5) ◽  
pp. 831-853 ◽  
Author(s):  
R. Halama ◽  
T. Wenzel ◽  
B. G. J. Upton ◽  
W. Siebel ◽  
G. Markl
Keyword(s):  
Trace Element ◽  
Granulite Facies ◽  
Alkaline Basalt ◽  
Isotopic Study ◽  
Nd Isotope ◽  
Crustal Component ◽  
Isotope Data ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Lower Crustal

AbstractBasalts from the volcano-sedimentary Eriksfjord Formation (Gardar Province, South Greenland) were erupted at around 1.2 Ga into rift-related graben structures. The basalts have compositions transitional between tholeiite and alkaline basalt with MgO contents <7 wt.% and they display LREE-enrichment relative to a chondritic source. Most of the trace element and REE characteristics are similar to those of basalts derived from OIB-like mantle sources. Initial 87Sr/86Sr ratios of clinopyroxene separates range from 0.70278 to 0.70383 and initial ϵNd values vary from –3.2 to +2.1. The most unradiogenic samples overlap with the field defined by carbonatites of similar age and can be explained by mixing of isotopically depleted and enriched mantle components. Using AFC modelling equations, the Sr-Nd isotope data of the more radiogenic basalts can successfully be modelled by addition of <5% lower crustal granulite-facies gneisses as contaminants. δ18Ov-smow values of separated clinopyroxene range from +5.2 to +6.0% and fall within the range of typical mantle-derived rocks. However, up to 10% mixing with an average lower crustal component are permitted by the data.

scholarly journals Unravelling the relationship between mafic magmatism and Sb mineralization through dolerite geochemistry (Central Iberian Zone, Spain)

2021 ◽  
Author(s):  
Héctor Ricardo Campos Rodríguez ◽  
Eric Gloaguen ◽  
Anthony Pochon ◽  
Pablo Higueras ◽  
Saturnino Lorenzo ◽  
...  
Keyword(s):  
Tectonic Setting ◽  
Crustal Contamination ◽  
Primitive Mantle ◽  
Variscan Belt ◽  
Mafic Magmatism ◽  
Mafic Dykes ◽  
Central Iberian Zone ◽  
Mafic Intrusions ◽  
Enriched Mantle ◽  
La Mancha

&lt;p&gt;This work presents the preliminary results of geochemistry of mafic intrusions (diabase dykes) and their relationship with antimony mineralization in the Central-Iberian Zone (Variscan Belt). Two different areas were studied, the Almad&amp;#233;n (Al) and the San Antonio (SA) areas.&lt;/p&gt;&lt;p&gt;Both macroscopic and microscopic observations show that mafic dykes are mainly composed by clinopyroxene, plagioclase, Fe-Ti oxides and to a lesser extent of calcite and sulphides (pyrite, chalcopyrite and pyrrhotite). These samples are altered presenting chlorite and epidote as alteration minerals. Pyroxene is sometimes altered to amphibole.&lt;/p&gt;&lt;p&gt;Whole rock geochemistry analyses from 20 samples show a difference between SA and Al dolerites. The first fall into the classical basalt field whereas the second fall into the alkali basalt field according to the Zr/TiO2 vs Nb/Y diagram. The tectonic setting for the SA samples coincides with the volcanic arc setting whereas the samples from Al fall into the within plate magmatism.&amp;#160;&lt;/p&gt;&lt;p&gt;Primitive mantle normalized diagrams display high negative anomalies in Rb, K, with small negative anomalies in Nb and Ta for both SA and Al. High positive anomalies for both areas in Cs, Pb (especially for SA) and Li accompanied by small positive anomalies in P and Ti can be observed. Dolerites from Al are more enriched in Ba, Th, U, Nb, Ba, La, Ce, Sr, P, Nd, Sn, Zr, Hf than SA. All samples are depleted in HREE and enriched in LREE. Anomalies in Rb, Nb, Ta and Li may be related with crustal contamination. Pb anomalies could be associated with assimilation of country rocks, especially marine sediments, this anomaly is also related to subduction processes. Positive P and Ti anomalies of some samples is due to the apatite and ilmenite enrichment respectively. Negative anomalies in K could be associated with presence of phlogopite in the source. Rare Earth Elements contents are compatible with the presence of garnet in the source and low degree of partial melting, this is consistent with the correlation between La/Sm vs Gd/Yb and La/Sm vs Rb. Trace element ratios such as Th/La (0,10 for SA) and (0,09 for Al) suggest an enriched mantle source.&lt;/p&gt;&lt;p&gt;Some of these mafic intrusions were collected near antimony mineralization whereas the other are located at distance but in the same swarm of mafic dykes. A spatial and genetic link between Sb mineralization and mafic magmatism has been proposed in other parts of the Variscan Belt, especially in the Armorican Massif.&lt;/p&gt;&lt;p&gt;The source of these Sb mineralization could be related to an enriched mantle with crustal contamination. The geochemical link between mafic magmatism and Sb mineralization and their source in the Central Iberian Zone is still a matter of study.&lt;/p&gt;&lt;p&gt;Acknowledgments&lt;/p&gt;&lt;p&gt;This work was funded by the ANR (ANR-19-MIN2-0002-01), the AEI (MICIU/AEI/REF.: PCI2019-103779) and author&amp;#8217;s institutions in the framework of the ERA-MIN2 AUREOLE project, as well as by Project SBPLY/17/180501/000273, Consejer&amp;#237;a de Educaci&amp;#243;n, Regional Government of Castilla-La Mancha, Spain.&lt;/p&gt;

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