scholarly journals Natural Graphite Cuboids

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 110 ◽  
Author(s):  
Andrey Korsakov ◽  
Olga Rezvukhina ◽  
John Jaszczak ◽  
Dmitriy Rezvukhin ◽  
Denis Mikhailenko
Keyword(s):  
Ultrahigh Pressure ◽  
Metamorphic Rocks ◽  
Formation Mechanisms ◽  
Natural Graphite ◽  
Natural Systems ◽  
Magmatic Rocks ◽  
Internal Morphology ◽  
Polycrystalline Aggregates ◽  
Common Center ◽  
Transformation Processes

Graphite cuboids are abundant in ultrahigh-pressure metamorphic rocks and are generally interpreted as products of partial or complete graphitization of pre-existing diamonds. The understanding of the graphite cuboid structure and its formation mechanisms is still very limited compared to nanotubes, cones, and other carbon morphologies. This paper is devoted to the natural occurrences of graphite cuboids in several metamorphic and magmatic rocks, including diamondiferous metamorphic assemblages. The studied cuboids are polycrystalline aggregates composed either of numerous smaller graphite cuboids with smooth surfaces or graphite flakes radiating from a common center. Silicates, oxides, and sulphides are abundant in all the samples studied, testifying that the presence of oxygen, sulfur, or sulphides in natural systems does not prevent the spherulitic growth of graphite. The surface topography and internal morphology of graphite cuboids combined with petrological data suggest that graphite cuboids originated from a magmatic or metamorphic fluid/melt and do not represent products of diamond-graphite transformation processes, even in diamond-bearing rocks.

Two-Stage Exhumation of Ultrahigh-Pressure Metamorphic Rocks from the Western Dabie Orogen, Central China

2011 ◽  
Vol 119 (1) ◽  
pp. 15-31 ◽  
Author(s):  
Yuanbao Wu ◽  
Shan Gao ◽  
Xiaochi Liu ◽  
Jing Wang ◽  
Min Peng ◽  
...  
Keyword(s):  
Central China ◽  
Ultrahigh Pressure ◽  
Metamorphic Rocks ◽  
Two Stage ◽  
Dabie Orogen

Evolution of geodynamics since the Archean: Significant change at the dawn of the Phanerozoic

Geology ◽  
2020 ◽  
Vol 48 (5) ◽  
pp. 488-492 ◽  
Author(s):  
M. Brown ◽  
C.L. Kirkland ◽  
T.E. Johnson
Keyword(s):  
Ultrahigh Pressure ◽  
Secular Change ◽  
Metamorphic Rocks ◽  
Data Sets ◽  
Ultrahigh Pressure Metamorphism ◽  
Slab Breakoff ◽  
Wide Range ◽  
O Isotope ◽  
Global Data Sets ◽  
Global Data

Abstract A time-series analysis of thermobaric ratios (temperature/pressure [T/P]) for Paleoarchean to Cenozoic metamorphic rocks identified significant shifts in mean T/P that may be related to secular change in the geodynamics on Earth. Thermobaric ratios showed significant (>95% confidence) change points at 1910, 902, 540, and 515 Ma, recording drops in mean T/P, and at 1830, 604, and 525 Ma, recording rises in mean T/P. Highest mean T/P occurred during the Mesoproterozoic, and lowest mean T/P occurred from the Cambrian to the Oligocene. Correlated changes were seen between T/P and global data sets of time-constrained hafnium (Hf) and oxygen (O) isotope compositions in zircon. The range of correlated variation in T/P, Hf, and O was larger during the formation of Rodinia than Columbia. Large changes and a wide range for these variables continued through the Phanerozoic, during which a statistically significant 83 m.y. frequency of T/P excursions recorded the high tempo of orogenic activity associated with the separation, migration, and accretion of continental terranes during the formation of Pangea. Since the early Tonian, the decreasing mean T/P of metamorphism, widespread appearance of blueschist and ultrahigh-pressure metamorphism, and wide fluctuations in Hf and O isotope compositions document a change to the modern plate-tectonic regime, characterized by widespread continental subduction and deeper slab breakoff than in the Proterozoic.

scholarly journals Hydrogeochemistry, Geothermometry, and Genesis of the Hot Springs in the Simao Basin in Southwestern China

Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-23 ◽  
Author(s):  
Yuqi Zhang ◽  
Xun Zhou ◽  
Haisheng Liu ◽  
Mingxiao Yu ◽  
Kuo Hai ◽  
...  
Keyword(s):  
Carbonate Rocks ◽  
Hot Springs ◽  
Cold Water ◽  
Metamorphic Rocks ◽  
Formation Mechanisms ◽  
Chemical Compositions ◽  
Red Beds ◽  
Incongruent Dissolution ◽  
Geothermal Waters ◽  
Isotopic Analyses

In the Simao Basin in southwest China widely occur red beds of poor permeability. Nevertheless, more than 100 springs exist in the basin, some of which are hot springs with varying temperature. Hot springs contain abundant information on hydrogeochemical processes and groundwater circulation. In this study, hydrochemical and isotopic analyses and mixed models are used to examine the sources of recharge, heat, and solutes of the hot springs to better understand the subsurface processes and formation mechanisms of different hot springs in the basin. Three types of springs are found in the Simao Basin: springs of HCO3-Na type occur in the metamorphic rocks, springs of HCO3-Ca(Mg) and Cl-HCO3-Na-Ca types in the carbonate rocks, and springs of Cl(SO4)-SO4(Cl)-HCO3-Na(Ca) type in the red beds. Data of δ2H and δ18O indicate that the hot springs in the Simao Basin are meteoric in origin. Incongruent dissolution is the dominant process affecting the chemical compositions of the spring waters. The hydrochemical constituents of the hot springs in the metamorphic rocks, carbonate rocks, and red beds are influenced by the weathering of albite and the dissolution of carbonate, gypsum, anhydrite, and halite. The geothermal waters are mixed with shallow cold waters in their ascending processes, and the mixing ratios of cold water range from 58% to 94%. Due to the effect of mixing, the reservoir temperatures (51°C-127°C) calculated with the quartz geothermometer are regarded as the minimum reservoir temperatures. More reliable reservoir temperatures (91°C-132°C) are estimated with the fixed-Al method. The following mechanisms contribute to the formation of hot springs in the Simao Basin: the groundwater receives recharge from infiltration of precipitation and undergoes deep circulation, during which groundwater is heated by heat flow and incongruently dissolves the subsurface minerals and emerges in the form of hot springs along the permeable fracture or fault zones.

40Ar-39Ar Thermochronological Constraints on the Exhumation of Ultrahigh-Pressure Metamorphic Rocks in the Sulu Terrane of Eastern China

2005 ◽  
Vol 47 (8) ◽  
pp. 872-886 ◽  
Author(s):  
Li-Hung Lin ◽  
Pei-Ling Wang ◽  
Ching-Hua Lo ◽  
Chin-Ho Tsai ◽  
Bor-Ming Jahn
Keyword(s):  
Eastern China ◽  
Ultrahigh Pressure ◽  
Metamorphic Rocks ◽  
Sulu Terrane

Viscous relaxation of mineral Inclusions and its implications for reaction overstepping calculations in metamorphic rocks

2020 ◽  
Author(s):  
Evangelos Moulas ◽  
Xin Zhong ◽  
Lucie Tajcmanova
Keyword(s):  
Independent Method ◽  
Metamorphic Rocks ◽  
Additional Method ◽  
Natural Systems ◽  
Long Period ◽  
Mineral Inclusions ◽  
Large Peak ◽  
Viscous Relaxation ◽  
T Path ◽  
Temperature Time

<p>Over the recent years, Raman elastic barometry has been developed as an additional method <span>to calculate</span> metamorphic conditions in natural systems. A major advantage of Raman elastic barometry is that it does not depend on thermodynamic databases and classic geobarometry methods <span>but</span> relies on mechanical calculations. As a consequence, Raman elastic barometry offers an independent method for estimating the pressure conditions <span>that prevailed at the</span> <span>time of entrapment</span> of mineral<span>s</span> du<span>ring</span> growth of their host<span>s</span>.</p><p>The di<span>fference between</span> the pressure calculated <span>using</span> elastic geobarometry and <span>that calculated by phase</span> equilibria methods has recently <span>been employed to</span> <span>estimate</span> the extent of metamorphic reaction overstepping in natural systems. <span>Quantification of</span> the <span>latter however implicitly assumes that the rheology</span> of the inclusion-host system <span>is perfectly</span> elastic. This assumption may no<span>t</span> hold at high temperatures, where viscous creep of minerals takes place.</p><p>The amount of viscous relaxation of <span>a host-inclusion</span> system is a path<span>-</span>dependent quantity which mostly depends on the temperature-time (T-t) path <span>followed</span>. <span>Here</span>, we present examples of visco-elastic relaxation of mineral inclusions and calculate the apparent reaction overstepping which results by assuming that the mechanical system is purely elastic. <span>Our modelling shows</span> that host-inclusion systems <span>that</span> experienced large peak temperatures for long period<span>s</span> of time will retain inclusion residual pressures that <span>cann</span>ot be simply related to the growth of the<span>ir hosts</span> and should <span>therefore not</span> be used for reaction overstepping calculations.</p>

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