Iron Isotope Composition of Adakitic Rocks: The Shangcheng Pluton, Western Dabie Orogen, Central China

There has been little research on the metal isotopic composition of adakitic rock. The main objective of our investigation was to obtain more knowledge on the iron isotopic composition of adakitic rocks and provide new evidence for the genesis of Shangcheng pluton from an iron isotope perspective. The Dabie orogen is divided into eastern and western areas by the Shangcheng-Macheng fault, and the Shangcheng pluton is located in the western Dabie orogen area. The iron isotopic composition of these rocks ranges from 0.08‰ to 0.20‰ (2SD, n = 3). The δ56Fe values of two rocks from the SGD (Sigudun) unit are relatively low (0.11 ± 0.03‰ and 0.08 ± 0.04‰), while the δ56Fe values of the other samples are basically consistent (0.18–0.2‰). Evidence from elemental geochemical characteristics and petrogenesis defines the Shangcheng pluton as adakitic rocks. Our investigation on the elemental and isotopic compositions hints that the enrichment of heavy iron isotopes cannot be explained by weathering/alteration and fluid exsolution. Fractional crystallization of magnetite may account for the enrichment of light iron isotopes in two rocks from the SGD unit, while the fractional iron isotope trend in the other five samples can be explained by Δ56Fecrystal-melt = ~0.035‰. Two investigated rocks from SGD units may have been derived from the partial melting of amphibolite, while the other five samples may have been derived from the partial melting of eclogite containing 10–15% garnet.

Magmatism and related metamorphism as a response to mountain-root collapse of the Dabie orogen: Constraints from geochronology and petrogeochemistry of metadiorites

Post-collisional mountain-root collapse and subsequent massive partial melting occurred in the high-temperature (HT) ultrahigh-pressure (UHP) metamorphic terrane of the North Dabie complex zone (NDZ), central China. The NDZ was deeply subducted in the Triassic, producing widespread migmatites and various magmatic intrusions in the Cretaceous. Post-collisional metadiorites with distinctive large K-feldspar augen porphyroblasts, locally reported but rarely exposed in the NDZ, underwent a complex evolutional history. In this contribution, integrated studies including field investigation, petrographic observation and mineral analysis, zircon U-Pb geochronological and Hf isotopic analyses, and whole-rock elemental and Sr-Nd-Pb isotopic analyses of the metadiorites were carried out. Our results provide new constraints on the mountain-root collapse in the Dabie orogen. The metadiorites are enriched in large ion lithophile elements and light rare earth elements, whereas they are depleted in high field strength elements and heavy rare earth elements with significant Ba positive anomalies, a composition consistent with the lower continental crust. All the studied samples have moderately enriched initial 87Sr/86Sr ratios (0.707582−0.708099), low εNd(t) values (−15.3 to −20.4), and low initial Pb isotopic ratios (16.0978−16.8452, 15.3167−15.4544, and 37.1778−37.8397 for 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb, respectively). However, they have highly negative εHf(t) values and Paleoproterozoic two-stage Hf model ages, which are only partially consistent with data from the associated UHP metamorphic rocks. Such features suggest the metadiorites resulted from a magma produced by mixing of Triassic UHP mafic lithologies and minor amounts of mantle-derived materials. Zircon morphological analysis and U-Pb sensitive high-resolution ion microprobe dating combined with conventional thermobarometry indicate that these upwelling melts crystallized at pressure-temperature (P-T) conditions of 5.4−5.7 kbar and 750−768 °C at ca. 130 Ma and subsequently suffered HT metamorphism at ca. 125 Ma. We conclude that the metadiorites’ precursors were derived from partial melting of the Triassic subducted Neoproterozoic mafic lower-crustal rocks, with addition of minor amounts of mantle-derived materials in the Early Cretaceous, in response to mountain-root collapse of the orogen. Based on petrographic textures and mineral compositions, it is moreover inferred that formation of the distinctive K-feldspar porphyroblasts is likely related to a two-stage process, i.e., crystallization derived from biotite breakdown after the formation of the metadiorite at T = 640−703 °C and P < 4.5 kbar and coarsening related to shear deformation.

New Detrital Apatite Fission Track Thermochronological Constraints on the Meso-Cenozoic Tectono-Thermal Evolution of the Micangshan-Dabashan Tectonic Belt, Central China

The Micangshan-Dabashan tectonic belt, located in the southern Qinling-Dabie Orogen near the northeastern Tibetan Plateau, is a crucial area for understanding the processes and mechanisms of orogenesis. Previous studies have been focused on the cooling process via thermochronology and the mechanism and process of basement uplift have been investigated. However, the coupling process of basement exhumation and sedimentary cap cooling is unclear. The tectono-thermal history constrained by the detrital apatite fission track (AFT) results could provide valuable information for understanding crustal evolution and the coupling process. In this study, we provided new detrital AFT thermochronology results from the Micangshan-Dabashan tectonic belt and obtained nine high-quality tectono-thermal models revealing the Meso-Cenozoic cooling histories. The AFT ages and lengths suggest that the cooling events in the Micangshan area were gradual from north (N) to south (S) and different uplift occurred on both sides of Micangshan massif. The cooling in Dabashan tectonic zone was gradual from northeast (NS) to southwest (SW). The thermal histories show that a relatively rapid cooling since ca. 160 Ma occurred in the Micangshan-Dabashan tectonic belt, which was a response to the event of Qinling orogenic belt entered the intracontinental orogenic deformation. This cooling event may relate to the northeastward dextral compression of the Yangtze Block. The sedimentary cap of Cambriano-Ordovician strata responded positively to this rapid cooling event and entered the PAZ since ca. 63 Ma. The deep buried samples may be limited affected by climate and water erosion and the accelerated cooling was not obvious in the Late Cenozoic. Collectively, the cooling processes of basement and sedimentary cap in Micangshan-Dabashan tectonic belt were inconsistent. The uplift of the sedimentary area is not completely consistent with that of the basement under thrust and nappe action. The rigid basement was not always continuous and rapidly uplifted or mainly showed as lateral migration in a certain stage because of the different intensities and modes of thrust and nappe action, and the plastic sedimentary strata rapidly uplifted due to intense folding deformation.

Supplemental Material: Magmatism and related metamorphism as a response to mountain-root collapse of the Dabie orogen: Constraints from geochronology and petrogeochemistry of metadiorites

Table S1: Electron microprobe analyses (wt%) of representative minerals in the NDZ metadiorites; Table S2: Major and trace elements concentrations of the NDZ metadiorites; Table S3: Zircon SHRIMP U-Pb isotopic compositions of the NDZ metadiorites; Table S4: Zircon REE concentrations of sample 1310YZH5 from the NDZ; Table S5: Zircon Lu-Hf isotopic compositions of the NDZ metadiorites; Table S6: Whole-rock Rb-Sr, Sm-Nd, and Pb isotopic data of the NDZ metadiorites; Table S7: P-T estimates of the NDZ metadiorites.

Theoretical inversion of the fossil hydrothermal systems with oxygen isotopes of constituent minerals partially re-equilibrated with externally infiltrated fluids

ABSTRACT While the external infiltration of water has been identified from modern geothermal and/or fossil hydrothermal systems through stable isotopes, the physicochemical boundary conditions like the initial oxygen isotopes of water $( {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } ) $ and rock as well as alteration temperature were implicitly presumed or empirically estimated by the conventional forward modelling. In terms of a novel procedure proposed to deal with partial re-equilibration of oxygen isotopes between constituent minerals and water, the externally infiltrated meteoric and magmatic water are theoretically inverted from the early Cretaceous post-collisional granitoid and intruded Triassic gneissic country rock across the Dabie orogen in central-eastern China. The meteoric water with a $ {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } $ value of −11.01 ‰ was externally infiltrated with a granitoid and thermodynamically re-equilibrated with rock-forming minerals at 140°C with a minimum water/rock (W/R)o ratio around 1.10 for an open system. The lifetime of this meteoric hydrothermal system is kinetically constrained less than 0.7 million years (Myr) via modelling of surface reaction oxygen exchange. A gneissic country rock, however, was externally infiltrated by a magmatic water with $ {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } $ value of 4.21 ‰ at 340°C with a (W/R)o ratio of 1.23, and this magmatic hydrothermal system could last no more than 12 thousand years (Kyr) to rapidly re-equilibrate with rock-forming minerals. Nevertheless, the external infiltration of water can be theoretically inverted with oxygen isotopes of re-equilibrated rock-forming minerals, and the ancient hydrothermal systems driven by magmatism or metamorphism within continental orogens worldwide can be reliably quantified.

Petrogenesis and tectonic significance of the middle Neoproterozoic highly fractionated A-type granite in the South Qinling block

The South Qinling block, a segment of the Yangtze craton involved in the Qinling–Dabie orogen, is critical for understanding the tectonic evolution of eastern China. However, the tectonic setting of the South Qinling block and the northern margin of the Yangtze block during middle Neoproterozoic time has long been the subject of debate, with two distinctly different models (continental rift or volcanic arc) proposed. Here, a comprehensive study of zircon U–Pb geochronology and geochemistry has been carried out on the Chengwan granitic pluton from the Suizao terrane in the South Qinling block. The granites are monzogranite and syenogranite in lithology, and are mainly composed of potash feldspar, quartz, plagioclase and biotite. This suite has long been regarded as a Palaeozoic magmatic pluton, but zircon U–Pb ages of 809 ± 9 Ma and 816 ± 4 Ma are obtained in this study. The granites are metaluminous to strongly peraluminous with high alkali contents, and exhibit highly fractionated features, including high SiO2, low Zr/Hf ratios, rare earth element tetrad effects and enrichment of K and Rb. They show Hf–Nd isotopic decoupling, which may be genetically related to their petrogenetic process. Based on the geochemical features and the positive εHf(t) values of the zircons, it is indicated that the granites may have been derived from partial melting of juvenile tonalitic rocks by biotite breakdown under fluid-absent conditions. The Chengwan granite geochemically belongs to the A2-subtype granites, suggesting that it might have formed in a post-orogenic tectonic setting. The highly fractionated A-type granite in this study may represent extensional collapse shortly after the collisional events in the South Qinling block, and thus indicate a tectonic regime switch, from compression to extension, as early as middle Neoproterozoic time. Integrating our new data with documented magmatic, metamorphic and sedimentary events during middle Neoproterozoic time in the region may support a continental rift model, and argues against arc models.