scholarly journals Probing the Electron Transfer between iLOV Protein and Ag Nanoparticles

Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2544
Author(s):  
Xia Ran ◽  
Qianqian Zhang ◽  
Yu Zhang ◽  
Jin Chen ◽  
Zhongran Wei ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Fluorescence Intensity ◽  
Ag Nanoparticles ◽  
Interaction Mechanism ◽  
Tryptophan Residue ◽  
Biomedical Sciences ◽  
Time Resolved ◽  
Mechanism Of Interaction ◽  
Controlled Experimentation ◽  
First Time

Nanomaterials have been widely used in biomedical sciences; however, the mechanism of interaction between nanoparticles and biomolecules is still not fully understood. In the present study, we report the interaction mechanism between differently sized Ag nanoparticles and the improved light-oxygen-voltage (iLOV) protein. The steady-state and time-resolved fluorescence results demonstrated that the fluorescence intensity and lifetime of the iLOV protein decreased upon its adsorption onto Ag nanoparticles, and this decrease was dependent upon nanoparticle size. Further, we showed that the decrease of fluorescence intensity and lifetime arose from electron transfer between iLOV and Ag nanoparticles. Moreover, through point mutation and controlled experimentation, we demonstrated for the first time that electron transfer between iLOV and Ag nanoparticles is mediated by the tryptophan residue in the iLOV protein. These results are of great importance in revealing the function of iLOV protein as it applies to biomolecular sensors, the field of nano-photonics, and the interaction mechanism between the protein and nanoparticles.

scholarly journals Interaction mechanism of aloe-emodin with trypsin: molecular structure–affinity relationship and effect on biological activities

RSC Advances ◽  
2020 ◽  
Vol 10 (35) ◽  
pp. 20862-20871
Author(s):  
Guoyan Ren ◽  
He Sun ◽  
Gen Li ◽  
Jinling Fan ◽  
Lin Du ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Biological Activity ◽  
Biological Activities ◽  
Interaction Mechanism ◽  
Mechanism Of Interaction ◽  
Development And Utilization ◽  
Aloe Emodin

The mechanism of interaction between AE and trypsin was studied firstly. The biological activity of both decreased after the interaction. These results provide a basis for the development and utilization of AE.

scholarly journals Additive Manufacturing for Effective Smart Structures: The Idea of 6D Printing

2021 ◽  
Vol 5 (5) ◽  
pp. 119
Author(s):  
Stelios K. Georgantzinos ◽  
Georgios I. Giannopoulos ◽  
Panteleimon A. Bakalis
Keyword(s):  
Additive Manufacturing ◽  
Degrees Of Freedom ◽  
Smart Structures ◽  
Interaction Mechanism ◽  
Modeling And Simulations ◽  
Environmental Stimulus ◽  
Material Component ◽  
Design And Manufacturing ◽  
First Time ◽  
Printing Techniques

This paper aims to establish six-dimensional (6D) printing as a new branch of additive manufacturing investigating its benefits, advantages as well as possible limitations concerning the design and manufacturing of effective smart structures. The concept of 6D printing, to the authors’ best knowledge, is introduced for the first time. The new method combines the four-dimensional (4D) and five-dimensional (5D) printing techniques. This means that the printing process is going to use five degrees of freedom for creating the final object while the final produced material component will be a smart/intelligent one (i.e., will be capable of changing its shape or properties due to its interaction with an environmental stimulus). A 6D printed structure can be stronger and more effective than a corresponding 4D printed structure, can be manufactured using less material, can perform movements by being exposed to an external stimulus through an interaction mechanism, and it may learn how to reconfigure itself suitably, based on predictions via mathematical modeling and simulations.

scholarly journals Photoinduced electron transfer processes of single-wall carbon nanotube (SWCNT)–based hybrids

Nanophotonics ◽  
2020 ◽  
Vol 9 (16) ◽  
pp. 4689-4701
Author(s):  
Lili Du ◽  
Wenjuan Xiong ◽  
Wai Kin Chan ◽  
David Lee Phillips
Keyword(s):  
Electron Transfer ◽  
Transient Absorption ◽  
Electronic Materials ◽  
Photophysical Properties ◽  
Functional Materials ◽  
Single Wall Carbon Nanotubes ◽  
Spectroscopic Techniques ◽  
Time Resolved ◽  
Single Wall Carbon ◽  
Electron Transfer Processes

AbstractIn this review, noncovalent functionalization of single-wall carbon nanotubes (SWCNTs) is briefly reviewed. The functional materials summarized here include metalloporphyrin derivatives, biomolecules and conjugated polymers. Notably, time-resolved spectroscopic techniques such as time-resolved fluorescence and transient absorption were employed to directly investigate the electron transfer and recombination processes between the functionalities and the SWCNTs. In addition, Raman spectroscopy is also useful to identify the interaction and the electron transfer direction between both the functionalities and the SWCNTs. An improved understanding of the mechanisms of these SWCNT-based nanohybrids in terms of their structural and photophysical properties can provide more insights into the design of new electronic materials.

scholarly journals Electron self-exchange activation parameters of diethyl sulfide and tetrahydrothiophene

2013 ◽  
Vol 9 ◽  
pp. 1448-1454
Author(s):  
Martin Goez ◽  
Martin Vogtherr
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Nuclear Polarization ◽  
Activation Barrier ◽  
Activation Parameters ◽  
Radical Cations ◽  
Free Energies ◽  
Time Resolved ◽  
Diethyl Sulfide ◽  
Chemically Induced

Electron transfer between the title compounds and their radical cations, which were generated by photoinduced electron transfer from the sulfides to excited 2,4,6-triphenylpyrylium cations, was investigated by time-resolved measurements of chemically induced dynamic nuclear polarization (CIDNP) in acetonitrile. The strongly negative activation entropies provide evidence for an associative–dissociative electron exchange involving dimeric radical cations. Despite this mechanistic complication, the free energies of activation were found to be well reproduced by the Marcus theory of electron transfer, with the activation barrier still dominated by solvent reorganization.

scholarly journals Time-resolved and temperature tuneable measurements of fluorescent intensity using a smartphone fluorimeter

The Analyst ◽  
2017 ◽  
Vol 142 (11) ◽  
pp. 1953-1961 ◽  
Author(s):  
Md Arafat Hossain ◽  
John Canning ◽  
Zhikang Yu ◽  
Sandra Ast ◽  
Peter J. Rutledge ◽  
...  
Keyword(s):  
Steady State ◽  
Fluorescence Intensity ◽  
Time Resolved Fluorescence ◽  
Time Resolved ◽  
Fluorescent Intensity ◽  
Intensity Measurements

A smartphone fluorimeter is demonstrated for steady-state and time-resolved fluorescence intensity measurements at tunable temperatures.

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