scholarly journals Confinement Effect of Plasmon for the Fabrication of Interconnected AuNPs through the Reduction of Diazonium Salts

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1957
Author(s):  
Luong-Lam Nguyen ◽  
Quang-Hai Le ◽  
Van-Nhat Pham ◽  
Mathieu Bastide ◽  
Sarra Gam-Derouich ◽  
...  

This paper describes a rapid bottom-up approach to selectively functionalize gold nanoparticles (AuNPs) on an indium tin oxide (ITO) substrate using the plasmon confinement effect. The plasmonic substrates based on a AuNP-free surfactant were fabricated by electrochemical deposition. Using this bottom-up technique, many sub-30 nm spatial gaps between the deposited AuNPs were randomly generated on the ITO substrate, which is difficult to obtain with a top-down approach (i.e., E-beam lithography) due to its fabrication limits. The 4-Aminodiphenyl (ADP) molecules were grafted directly onto the AuNPs through a plasmon-induced reduction of the 4-Aminodiphenyl diazonium salts (ADPD). The ADP organic layer preferentially grew in the narrow gaps between the many adjacent AuNPs to create interconnected AuNPs. This novel strategy opens up an efficient technique for the localized surface modification at the nanoscale over a macroscopic area, which is anticipated to be an advanced nanofabrication technique.

2009 ◽  
Vol 4 (4) ◽  
pp. 239-244 ◽  
Author(s):  
C. O'Dwyer ◽  
M. Szachowicz ◽  
G. Visimberga ◽  
V. Lavayen ◽  
S. B. Newcomb ◽  
...  

2014 ◽  
Vol 490-491 ◽  
pp. 271-273
Author(s):  
So Hyun Jeong ◽  
Ju Youn Kim ◽  
Eui Jung Yun ◽  
Byung Seong Bae

Transparent electrodes are used widely for the many kinds of devices. The most widely used material is ITO (indium tin oxide). The attempts to improve the resistance and flexibility have been tried. The low resistance can be achieved by increasing the thickness of the ITO; however, the increase of the thickness results in the decrease of the transmittance of the incident light. Therefore,decrease of the resistance is required without increase of the thickness. We investigated the effect of the metal material on the resistance of the transparent electrode. After deposition of the metal on the ITO, we investigated the resistance of the electrode after annealing. The lowest sheet resistance was obtained for the metal Mo after 500 °C annealing. The sheet resistance 25.6 Ω/ of the ITO was decreased to 9.6 Ω/ without any significant decrease of the transmittance.


Author(s):  
Renyun Zhang ◽  
Magnus Engholm

Transparent electrodes (TEs) made of metallic nanowires, such as Ag, Au, Cu, and Ni, have attracted rising attention for several reasons: 1) they can act as a substitute for tin oxide-based TEs such as indium-tin oxide (ITO) and fluorine-doped tin oxide (FTO); 2) various methods exist for fabricating such TEs such as filtration, spraying and meyer bar coating; 3) greater compatibility with different substrates can be achieved due to the variety of fabrication methods; and 4) extra functions in addition to serving as electrodes, such as catalytic abilities, can be obtained due to the metals that compose the TEs. There are a large number of applications for TEs, ranging from electronics and sensors to biomedical devices. This short review is a summary of recent progress, mainly during the past five years, on silver nanowire-based TEs. The focus of the review will be on theory development, mechanical, chemical and thermal stability and optical properties. The many applications of TEs are outside the scope of this review.


Nanomaterials ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 628 ◽  
Author(s):  
Renyun Zhang ◽  
Magnus Engholm

Transparent electrodes (TEs) made of metallic nanowires, such as Ag, Au, Cu, and Ni, are attracting increasing attention for several reasons: (1) they can act as a substitute for tin oxide-based TEs such as indium-tin oxide (ITO) and fluorine-doped tin oxide (FTO); (2) various methods exist for fabricating such TEs such as filtration, spraying, and Meyer bar coating; (3) greater compatibility with different substrates can be achieved due to the variety of fabrication methods; and (4) extra functions in addition to serving as electrodes, such as catalytic abilities, can be obtained due to the metals of which the TEs are composed. There are a large number of applications for TEs, ranging from electronics and sensors to biomedical devices. This short review is a summary of recent progress, mainly over the past five years, on silver nanowire-based TEs. The focus of the review is on theory development, mechanical, chemical, and thermal stability as well as optical properties. The many applications of TEs are outside the scope of this review.


2012 ◽  
Vol 1402 ◽  
Author(s):  
Battulga Munkhbat ◽  
Bolormaa Gendensuren ◽  
Ganbaatar Tumenulzii ◽  
Rentsenmyadag Dashzeveg ◽  
Sarangerel Davaasambuu ◽  
...  

ABSTRACTThe work function of the indium tin oxide electrode (ITO) modified by a self-assembled monolayer (SAM), which is used as an electrode in organic electroluminescent (EL) devices, was investigated in this study. It is revealed that chemical modification of ITO with p-substituted with different terminal groups (NH2−, Cl−, and CF3−) benzoic acids as a SAMs material with carboxyl binding group is caused to increase the work function of the ITO electrode. Through a self-assembly process, the transmittance of the ITO with a SAM was not changed. The work function change of ITO with various SAM was measured by using cyclic voltammetry. Characteristics of EL devices were increased because the energy barrier was decreased in an interface between the ITO and an organic layer in the EL devices. The correlation of the work function change and the performance of the chemically modified EL devices was estimated.


2017 ◽  
Vol 268 ◽  
pp. 269-273
Author(s):  
Siti Zulaikha Ngah Demon ◽  
Nursaadah Ahmad Poad ◽  
Noor Fadhilah Rahmat ◽  
Noriah Bidin

Organic devices are advantageous in term of high carrier mobility, lightweight and flexibility. The solution processed method offers economic and efficient device fabrication in small laboratory scale. The α-quaterthiophene (α-4T) is an oligomer and a p-type organic semiconductor. In this study, pure α-4T and polylactide acid (PLA)/α-4T films were spin-coated on glass and indium tin oxide (ITO) substrates at low spin frequency. The hydrated films were left to dry at room temperature and later in vacuum oven. The α-4T microstructures changed when blended with the polymer. The roughness of the 180 nm ITO film was found to be 1 - 30 nm and the organic layer formed uneven thickness (max ~ 300 nm) thicker toward the edge. The preparation of spin coated organic thin film is the first step towards realizing solution processed organic device in electronic packaging.


2020 ◽  
Vol 13 (4) ◽  
pp. 722-727
Author(s):  
ZHU Ye-xin ◽  
◽  
◽  
LI Ya-nan ◽  
SHI Wei-jie ◽  
...  

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