scholarly journals Lithium-Based Upconversion Nanoparticles for High Performance Perovskite Solar Cells

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2909
Author(s):  
Masfer Alkahtani ◽  
Anas Ali Almuqhim ◽  
Hussam Qasem ◽  
Najla Alsofyani ◽  
Anfal Alfahd ◽  
...  

In this work, we report an easy, efficient method to synthesize high quality lithium-based upconversion nanoparticles (UCNPs) which combine two promising materials (UCNPs and lithium ions) known to enhance the photovoltaic performance of perovskite solar cells (PSCs). Incorporating the synthesized YLiF4:Yb,Er nanoparticles into the mesoporous layer of the PSCs cells, at a certain doping level, demonstrated a higher power conversion efficiency (PCE) of 19%, additional photocurrent, and a better fill factor (FF) of 82% in comparison to undoped PSCs (PCE = ~16.5%; FF = 71%). The reported results open a new avenue toward efficient PSCs for renewable energy applications.

2021 ◽  
Vol 42 (11) ◽  
pp. 112202
Author(s):  
Zhen Li ◽  
Guanjun Yang

Abstract Repressing the thermal decomposition during the process of heat treatment plays an indispensable part in the preparation of perovskite films. Here, a methylammonium iodide healing method was applied to prevent the volatilization of the organic component inside the perovskite structure during the heat treatment. High-quality CH3NH3PbI3 film with a much larger grain size over 800 nm was successfully fabricated via this healing method. Besides, the absorption and photoluminescence intensity were also both improved. Finally, the best power conversion efficiency of 18.89% with a fill factor over 80% was realized in an n–i–p configuration while possessing outstanding stability. This work suggests that methylammonium iodide healing method is a reliable way to promote crystal growth and improve the photovoltaic performance and humidity stability of the CH3NH3PbI3 solar cells.


Nanoscale ◽  
2018 ◽  
Vol 10 (44) ◽  
pp. 20587-20598 ◽  
Author(s):  
Jae-Ho Kim ◽  
Hae-Jun Seok ◽  
Hyeong-Jin Seo ◽  
Tae-Yeon Seong ◽  
Jin Hyuck Heo ◽  
...  

Flexible perovskite solar cells with an ion plated ITO electrode showed a higher power conversion efficiency and better flexibility than sputtered ITO-based perovskite solar cells.


2016 ◽  
Vol 4 (29) ◽  
pp. 11307-11316 ◽  
Author(s):  
Minwoo Park ◽  
Joon-Suh Park ◽  
Il Ki Han ◽  
Jin Young Oh

By incorporating long P3HT nanofibrils as a hole transporting layer, high-performance, air-stable and flexible perovskite solar cells with a large active area (1 cm2) have been realized with an excellent power conversion efficiency of 13.12%.


RSC Advances ◽  
2020 ◽  
Vol 10 (33) ◽  
pp. 19513-19520 ◽  
Author(s):  
Miao Yu ◽  
Lijia Chen ◽  
Guannan Li ◽  
Cunyun Xu ◽  
Chuanyao Luo ◽  
...  

The charge transfer hindrance of adsorbed oxygen species on SnO2 is successfully reduced by modifying it with guanidinium chloride, improving the power conversion efficiency from 15.33% to 18.46% (after modification) with maximum fill factor of 80%.


2017 ◽  
Vol 4 (12) ◽  
pp. 170980 ◽  
Author(s):  
Ya-Qiong Wang ◽  
Shou-Bin Xu ◽  
Jian-Guo Deng ◽  
Li-Zhen Gao

The interfacial compatibility between compact TiO 2 and perovskite layers is critical for the performance of planar heterojunction perovskite solar cells (PSCs). A compact TiO 2 film employed as an electron-transport layer (ETL) was modified using 3-aminopropyl trimethoxy silane (APMS) hydrolysate. The power conversion efficiency (PCE) of PSCs composed of an APMS-hydrolysate-modified TiO 2 layer increased from 13.45 to 15.79%, which was associated with a significant enhancement in the fill factor (FF) from 62.23 to 68.04%. The results indicate that APMS hydrolysate can enhance the wettability of γ-butyrolactone (GBL) on the TiO 2 surface, form a perfect CH 3 NH 3 PbI 3 film, and increase the recombination resistance at the interface. This work demonstrates a simple but efficient method to improve the TiO 2 /perovskite interface that can be greatly beneficial for developing high-performance PSCs.


2017 ◽  
Vol 5 (39) ◽  
pp. 10280-10287 ◽  
Author(s):  
Cong Chen ◽  
Guang Yang ◽  
Junjie Ma ◽  
Xiaolu Zheng ◽  
Zhiliang Chen ◽  
...  

We showed that perovskite solar cells employing Li-treated NiOxas a hole transport layer demonstrated excellent photovoltaic performance, and obtained a power conversion efficiency of up to 18.03%. In addition, the device possessed good long-term stability.


2020 ◽  
Vol 8 (33) ◽  
pp. 11638-11646 ◽  
Author(s):  
Wenxiao Gong ◽  
Heng Guo ◽  
Haiyan Zhang ◽  
Jian Yang ◽  
Haiyuan Chen ◽  
...  

Both wetting and non-wetting tin oxide SnO2 were spin-coated and the non-wetting electron transport layer demonstrated a larger perovskite and higher power conversion efficiency.


Sign in / Sign up

Export Citation Format

Share Document