scholarly journals Nano-MnO2 Decoration of TiO2 Microparticles to Promote Gaseous Ethanol Visible Photoremoval

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 686 ◽  
Author(s):  
Marta Stucchi ◽  
Daria Boffito ◽  
Eleonora Pargoletti ◽  
Giuseppina Cerrato ◽  
Claudia Bianchi ◽  
...  
Keyword(s):  
Visible Light ◽  
High Performance ◽  
Noble Metals ◽  
Large Scale ◽  
Light Emitting Diode ◽  
Low Cost ◽  
Light Emitting ◽  
Physico Chemical ◽  
Visible Light Active ◽  
Activity Screening

TiO2-based photocatalysis under visible light is an attractive way to abate air pollutants. Moreover, developing photocatalytic materials on a large-scale requires safe and low-cost precursors. Both high-performance TiO2 nanopowders and visible-light active noble metals do not match these requirements. Here, we report the design of novel Mn-decorated micrometric TiO2 particles. Pigmentary TiO2 replaced unsafe nano-TiO2 and firmly supported MnOx particles. Mn replaced noble metals such as Au or Ag, opening the way for the development of lower cost catalysts. Varying Mn loading or pH during the impregnation affected the final activity, thus giving important information to optimize the synthesis. Photocatalytic activity screening occurred on the gas-phase degradation of ethanol as a reference molecule, both under ultraviolet (UV) (6 h) and Light Emitting Diode (LED) (24 h) irradiation. Mn-doped TiO2 reached a maximum ethanol degradation of 35% under visible light after 24 h for the sample containing 20% of Mn. Also, we found that an acidic pH increased both ethanol degradation and mineralization to CO2, while an alkaline pH drastically slowed down the reaction. A strict correlation between photocatalytic results and physico-chemical characterizations of the synthesized powders were drawn.

A flexible, lightweight and stretchable all-solid-state supercapacitor based on warp-knitted stainless-steel mesh for wearable electronics

2022 ◽  
pp. 004051752110698
Author(s):  
Chuanli Su ◽  
Guangwei Shao ◽  
Qinghua Yu ◽  
Yaoli Huang ◽  
Jinhua Jiang ◽  
...  
Keyword(s):  
Stainless Steel ◽  
High Performance ◽  
Light Emitting Diode ◽  
Low Cost ◽  
Three Dimensional ◽  
Rate Capability ◽  
Cycling Stability ◽  
Wearable Electronics ◽  
Light Emitting ◽  
Dimensional Network

Highly conductive, flexible, stretchable and lightweight electrode substrates are essential to meet the future demand on supercapacitors for wearable electronics. However, it is difficult to achieve the above characteristics simultaneously. In this study, ultrafine stainless-steel fibers (with a diameter of ≈30 μm) are knitted into stainless-steel meshes (SSMs) with a diamond structure for the fabrication of textile stretchable electrodes and current collectors. The electrodes are fabricated by utilizing an electrodeposited three-dimensional network graphene framework and poly(3,4-ethylenedioxythiophene) (PEDOT) coating on the SSM substrates via a two-step electrodeposition process, which show a specific capacitance of 77.09 F g−1 (0.14 A g−1) and superb cycling stability (91% capacitance retention after 5000 cycles). Furthermore, the assembled flexible stretchable supercapacitor based on the PEDOT/reduced graphene oxide (RGO)@SSM electrodes exhibits an areal capacitance (53 mF cm−2 at 0.1 mA cm−2), a good cycling stability (≈73% capacitance retention after 5000 cycles), rate capability (36 mF cm−2 at 5 mA cm−2), stretchable stability (≈78% capacitance retention at 10% strain for 500 stretching cycles) and outstanding flexibility and stability under various bending deformations. The assembled supercapacitors can illuminate a thermometer and a light-emitting diode, demonstrating their potential application as stretchable supercapacitors. This simple and low-cost method developed for fabricating lightweight, stretchable and stable high-performance supercapacitors offers new opportunities for future stretchable electronic devices.

scholarly journals Solid-State Synthesis of Direct Z-Scheme Cu2O/WO3 Nanocomposites with Enhanced Visible-Light Photocatalytic Performance

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 293
Author(s):  
Hassan Ali ◽  
Ali Guler ◽  
Milan Masar ◽  
Pavel Urbanek ◽  
Michal Urbanek ◽  
...  
Keyword(s):  
Solid State ◽  
Visible Light ◽  
Photocatalytic Performance ◽  
Light Emitting Diode ◽  
Scanning Calorimetry ◽  
Light Emitting ◽  
Low Concentrations ◽  
Vis Spectroscopy ◽  
Visible Light Active ◽  
Cu2o Nanoparticles

In this paper, we report the preparation of visible-light active direct Z-scheme Cu2O/WO3 nanocomposite photocatalyst by a solid-state reaction avoiding the otherwise inevitable formation of CuWO4 phase in wet syntheses. Structure, morphology, and thermal and optical properties of prepared WO3 nanoplatelets decorated by Cu2O were investigated by XRD, Raman spectroscopy, SEM/TEM, combined thermogravimetric (TG)/differential scanning calorimetry (DSC) analysis, and UV–VIS spectroscopy. The photocatalytic performance of the prepared samples under UV and visible light was studied through monitoring discoloration of methylene blue under illumination by selected wavelengths, allowing for the distinguishing between the contributions of the two semiconductive components. Experimental results showed that the decoration of WO3 nanoplates by Cu2O nanoparticles led to an improvement in photocatalytic performance, regardless of used LED (Light-Emitting Diode) wavelength, even at low concentrations. By using scavengers selectively blocking reactive species involved in the discoloration reaction, we determined that the Cu2O/WO3 nanocomposite exhibited the characteristics of direct Z-scheme-type photocatalyst.

Enabling High-Throughput, Low-Cost Manufacturing of OLED Display and Lighting Panels

2009 ◽  
Vol 1212 ◽  
Author(s):  
Michael Long ◽  
Bruce E Koppe ◽  
Neil P Redden ◽  
Michael L Boroson ◽  
Tukaram K Hatwar ◽  
...  
Keyword(s):  
Large Scale ◽  
Light Emitting Diode ◽  
Low Cost ◽  
Utilization Efficiency ◽  
Color Filter ◽  
Vacuum Deposition ◽  
Deposition Rates ◽  
Light Emitting ◽  
Low Cost Manufacturing ◽  
Deposition Technology

AbstractLarge-scale manufacturing of organic light-emitting diode (OLED) panels for lighting and display has been slowed by several manufacturing factors, prominent among which are low throughput due in part to the fine metal mask technology for patterning the red-, green-, and blue-light-emitting pixels and low materials utilization efficiency of the available vacuum deposition technology. To overcome these impediments to low-cost OLED manufacturing, Kodak developed a blanket white-emitting OLED architecture in combination with a pixilated color filter array to eliminate the need for fine metal masks and developed a vacuum deposition technology capable of high deposition rates and high materials utilization efficiency. These developments, taken together, allow much higher throughput and yield on fifth-generation and larger substrates that promise to enable low-cost manufacturing of OLED displays and lighting panels. This paper focuses on the deposition technology Kodak developed, a flash vaporization process that can deliver very high materials utilization efficiency at high deposition rates for small-molecule OLED materials without increasing material decomposition.

scholarly journals Enhanced Visible Light Photocatalytic Activity ofV2O5Cluster Modified N-DopedTiO2for Degradation of Toluene in Air

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Fan Dong ◽  
Yanjuan Sun ◽  
Min Fu
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Noble Metals ◽  
Large Scale ◽  
Low Cost ◽  
Photogenerated Electron ◽  
Visible Light Photocatalytic Activity ◽  
Highly Active ◽  
Photogenerated Electrons ◽  
Visible Light Photocatalytic

V2O5cluster-modified N-doped TiO2(N-TiO2/V2O5) nanocomposites photocatalyst was prepared by a facile impregnation-calcination method. The effects of V2O5cluster loading content on visible light photocatalytic activity of the as-prepared samples were investigated for degradation of toluene in air. The results showed that the visible light activity of N-doped TiO2was significantly enhanced by loading V2O5clusters. The optimal V2O5loading content was found to be 0.5 wt.%, reaching a removal ratio of 52.4% and a rate constant of 0.027 min−1, far exceeding that of unmodified N-doped TiO2. The enhanced activity is due to the deposition of V2O5clusters on the surface of N-doped TiO2. The conduction band (CB) potential of V2O5(0.48 eV) is lower than the CB level of N-doped TiO2(−0.19 V), which favors the photogenerated electron transfer from CB of N-doped TiO2to V2O5clusters. This function of V2O5clusters helps promote the transfer and separation of photogenerated electrons and holes. The present work not only displays a feasible route for the utilization of low cost V2O5clusters as a substitute for noble metals in enhancing the photocatalysis but also demonstrates a facile method for preparation of highly active composite photocatalyst for large-scale applications.

Ullmann coupling for low-cost synthesis of anthracene-based polyfluorenes: A photophysical approach

2020 ◽  
pp. 095400832094538
Author(s):  
Deepika C Hasija ◽  
Vaijayanti D Ghase ◽  
Meenakshi M Rananaware ◽  
Vishwanath R Patil
Keyword(s):  
Molecular Weight ◽  
Glass Transition ◽  
Transition Temperature ◽  
Large Scale ◽  
Light Emitting Diode ◽  
Low Cost ◽  
Cost Effective ◽  
Decomposition Temperature ◽  
Light Emitting ◽  
Highest Occupied Molecular Orbital

A set of anthracene containing polyfluorenes (PFs) having 9,10-diphenylanthracene with alkyl substituents and aniline containing fluorenes were prepared. Commonly, light-emitting polymers were synthesized using expensive palladium-like catalysts. In the present work, palladium was replaced by copper as a cost-effective PF synthesis catalyst, which is also suitable for large-scale polymer synthesis. Synthesized PFs emit light in the blue region with a bandgap of 2.87–2.90 eV. Thermally stable PFs had a decomposition temperature of more than 305°C and a glass transition temperature of 125–138°C. PFs were soluble in organic solvents and had a molecular weight of around 21,700–25,500. The electrochemical study of these PFs showed low level of highest occupied molecular orbital (HOMO) energy of −5.16 to −5.26 eV, which was significantly higher than that of PF (5.7 eV). These findings suggested that the resulting PFs could be used as a component of the light-emitting diode.

scholarly journals In vitro rapid inactivation of SARS-CoV-2 by visible light photocatalysis using boron-doped bismuth oxybromide

2021 ◽  
Author(s):  
Li Ling ◽  
Tea Carletti ◽  
Zihang Cheng ◽  
Ruixuan Wang ◽  
Yanxiao Ren ◽  
...  
Keyword(s):  
Visible Light ◽  
Culture Media ◽  
Light Emitting Diode ◽  
Emerging Pathogens ◽  
Light Emitting ◽  
Healthy Environment ◽  
Boron Doped ◽  
Visible Light Active ◽  
Led Irradiation

AbstractInactivation of SARS-CoV-2 in wastewater and on surfaces is critical to prevent the fecal-oral and fomite transmission, respectively. We hypothesized that visible light active photocatalysts could dramatically enhance the rate or extent of virus inactivation and enable the use of visible light rather than shorter wavelength ultraviolet light. A novel visible light active photocatalyst, boron-doped bismuth oxybromide (B-BiOBr), was synthesized and tested for its SARS-CoV-2 inactivation towards Vero E6 cell lines in dark and under irradiation at 426 nm by a light emitting diode (LED) in water. SARS-CoV-2 inactivation in the presence of B-BiOBr (0.8 g/L) under LED irradiation reached 5.32-log in 5 min, which was 400 to 10,000 times higher than those achieved with conventional photocatalysts of tungsten or titanium oxide nanomaterials, respectively. Even without LED irradiation, B-BiOBr inactivated 3.32-log of SARS-CoV-2 in the dark due to the ability of bismuth ions interfering with the SARS-CoV-2 helicase function. LED irradiation at 426 nm alone, without the photocatalyst, contributed to 10% of the observed inactivation and was attributed to production of reactive oxygen species due to blue-light photoexcitation of molecules in the culture media, which opens further modes of action to engineer disinfection strategies. The visible light active B-BiOBr photocatalyst, with its rapid SARS-CoV-2 inactivation in the presence and absence of light, holds tremendous opportunities to build a healthy environment by preventing the fecal-oral and fomite transmission of emerging pathogens.

Electrically driven single microribbon based near-infrared exciton-polariton light-emitting diode

CrystEngComm ◽  
2021 ◽  
Author(s):  
Mingming Jiang ◽  
Fupeng Zhang ◽  
Kai Tang ◽  
Peng Wan ◽  
Caixia Kan
Keyword(s):  
High Performance ◽  
Near Infrared ◽  
Light Emitting Diodes ◽  
Light Emitting Diode ◽  
Light Sources ◽  
Coherent Light ◽  
Light Emitting ◽  
Exciton Polaritons ◽  
Laser Devices

Achieving electrically-driven exciton-polaritons has drawn substantial attention toward developing ultralow-threshold coherent light sources, containing polariton laser devices and high-performance light-emitting diodes (LEDs). In this work, we demonstrate an electrically driven...

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