scholarly journals Electrochemical Enantiomer Recognition Based on sp3-to-sp2 Converted Regenerative Graphene/Diamond Electrode

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1050 ◽  
Author(s):  
Jingyao Gao ◽  
Haoyang Zhang ◽  
Chen Ye ◽  
Qilong Yuan ◽  
Kuan Chee ◽  
...  

It is of great significance to distinguish enantiomers due to their different, even completely opposite biological, physiological and pharmacological activities compared to those with different stereochemistry. A sp3-to-sp2 converted highly stable and regenerative graphene/diamond electrode (G/D) was proposed as an enantiomer recognition platform after a simple β-cyclodextrin (β-CD) drop casting process. The proposed enantiomer recognition sensor has been successfully used for d and l-phenylalanine recognition. In addition, the G/D electrode can be simply regenerated by half-minute sonication due to the strong interfacial bonding between graphene and diamond. Therefore, the proposed G/D electrode showed significant potential as a reusable sensing platform for enantiomer recognition.

2017 ◽  
Vol 5 (26) ◽  
pp. 6471-6479 ◽  
Author(s):  
Hye Ji Im ◽  
Gwang Hoon Jun ◽  
Dong Ju Lee ◽  
Ho Jin Ryu ◽  
Soon Hyung Hong

GNP/Ni/Wax nanocomposites fabricated by a molecular-level mixing process show enhanced shielding effectiveness due to homogeneously decorated Ni nanoparticles on GNP with strong interfacial bonding.


2020 ◽  
Vol 105 ◽  
pp. 107785 ◽  
Author(s):  
Branka B. Petković ◽  
Miloš Ognjanović ◽  
Milena Krstić ◽  
Vesna Stanković ◽  
Ljiljana Babincev ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3646 ◽  
Author(s):  
Yefei Li ◽  
Cong Li ◽  
Shuli Tang ◽  
Qiaoling Zheng ◽  
Juan Wang ◽  
...  

Using zirconia toughened alumina (ZTA) particles and Ni–Ti complex powders as raw materials, high-Cr cast iron reinforced by ZTA particles was prepared by an infiltration casting process. A continuous transition layer formed at the interface between ZTA particles and the Cr15 matrix, which proves that there is strong metallurgical interfacial bonding at the interface. The phases in the Ni–Ti layer of the ZTAP/Fe composite were preserved compared with the microstructure of sintered ZTA ceramic preform. The hardness of the Ni3Ti, TiO and AlNi2Ti phases in the interfacial transition layer was measured by the nano-indentation method, which is 12.5 GPa, 16.1 GPa and 9.2 GPa, respectively. The three-body wear resistance of the composite reached 12.6 times that of high-Cr cast iron.


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