scholarly journals Multifunctional Hybrid Composites with Enhanced Mechanical and Thermal Properties Based on Polybenzoxazine and Chopped Kevlar/Carbon Hybrid Fibers

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1308 ◽  
Author(s):  
Hamid Ghouti ◽  
Abdeldjalil Zegaoui ◽  
Mehdi Derradji ◽  
Wan-an Cai ◽  
Jun Wang ◽  
...  

This work studied the structural, morphological, mechanical, and thermal properties of newly designed polymeric materials using high-performance hybrid fibers to reinforce the polybenzoxazine resins. To achieve this goal, hybrid fibers consisting of chopped Kevlar and carbon fibers were subjected to a silane surface treatment, incorporated into the resin matrix in various combinations, and then isothermally cured using the compression molding technique. The mechanical performances of the prepared composites were scrutinized in terms of bending and tensile tests. By way of illustration, the composites holding 20 wt % Kevlar fibers and 20 wt % carbon fibers accomplished a bending strength and modulus of 237.35 MPa and 7.80 GPa, respectively. Additionally, the same composites recorded a tensile stress and toughness of 77 MPa and 0.27 MPa, respectively, indicating an increase of about 234% and 32.8% when compared to the pristine resin’s properties. The thermogravimetric analysis denoted an excellent thermal resistance of the reinforced hybrid composites. Fourier transform infrared spectroscopy proved that the functional groups of the as-used coupling agent were effectively grafted on the external surfaces of the reinforcing systems, and further confirmed that the chemical reaction took place between the treated fibers and the polybenzoxazine matrix, although the scanning electron microscope showed a uniform dispersion and interfacial adhesion of the fibers within the resin matrix. In fact, the incorporation of treated fibers along with their good dispersion/adhesion could explain the progressive enhancement in terms of thermal and mechanical properties that were observed in the hybrid composites.

2018 ◽  
Vol 31 (6) ◽  
pp. 719-732 ◽  
Author(s):  
Abdeldjalil Zegaoui ◽  
Mehdi Derradji ◽  
Abdul Qadeer Dayo ◽  
Aboubakr Medjahed ◽  
Hui-yan Zhang ◽  
...  

The investigation and design of new polymeric materials with an astonishing combination of properties are nowadays of great importance to facilitate the manufacturing process of high-quality products intended to be utilized in different applications and technical fields. For this intent, novel high-performance blend composites composed of the cyanate ester/benzoxazine resin blend reinforced by different proportions of silane-surface modified Kevlar and glass fibers were successfully fabricated by a compression molding technique and characterized by different experimental tests. The mechanical test results revealed that the bending and impact strength properties were considerably improved when increasing the amount of the hybrid fibers. The studied materials also presented excellent thermal stabilities as compared to the unfilled blend’s properties. With respect to the properties of the reinforcing systems, these improvements seen in either the mechanical or thermal properties could be due to the good dispersion as well as excellent adhesion of the reinforcing fibers inside the resin matrix, which were further evidenced by the Fourier transform infrared spectroscopy and scanning electron microscopy results. Consequently, the improved mechanical and thermal properties promote the use of the fabricated hybrid composites in domestic and industrial applications requiring functional materials with advanced properties for aerospace and military applications.


2018 ◽  
Vol 242 ◽  
pp. 01004 ◽  
Author(s):  
Dilyus Chukov ◽  
Sarvarkhodzha Nematulloev ◽  
Andrey Stepashkin ◽  
Aleksey Maksimkin ◽  
Dmitriy Zherebtsov ◽  
...  

The aim of this study is to create composites based on the high-temperature polymer reinforced with the carbon fibers and to study interfacial interaction between carbon fibers and polymer matrix. We propose a new method to obtain polysulfone based composite materials reinforced with high-modulus carbon fibers. The influences of thermal oxidation of carbon fibers on mechanical and thermal properties of the composites were studied. It was found that the obtained composite materials have sufficiently high mechanical properties, tensile strength up to 1047 MPa and Young’s modulus up to 70.9 GPa were found. Considerable interest to the polymer composites is associated with their high performance and good mechanical and thermal properties, which enable a broad range of aerospace, automotive and medical applications. Additionally, the manufacturing process of such composites can easily be optimized and automatized, furthermore, it is not time-consuming process in relation with thermosetting polymer based composites.


Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 754
Author(s):  
Jantrawan Pumchusak ◽  
Nonthawat Thajina ◽  
Watcharakorn Keawsujai ◽  
Pattarakamon Chaiwan

This work aims to explore the effect of organo-modified montmorillonite nanoclay (O-MMT) on the mechanical, thermo-mechanical, and thermal properties of carbon fiber-reinforced phenolic composites (CFRP). CFRP at variable O-MMT contents (from 0 to 2.5 wt%) were prepared. The addition of 1.5 wt% O-MMT was found to give the heat resistant polymer composite optimum properties. Compared to the CFRP, the CFRP with 1.5 wt% O-MMT provided a higher tensile strength of 64 MPa (+20%), higher impact strength of 49 kJ/m2 (+51%), but a little lower bending strength of 162 MPa (−1%). The composite showed a 64% higher storage modulus at 30 °C of 6.4 GPa. It also could reserve its high modulus up to 145 °C. Moreover, it had a higher heat deflection temperature of 152 °C (+1%) and a higher thermal degradation temperature of 630 °C. This composite could maintain its mechanical properties at high temperature and was a good candidate for heat resistant material.


2021 ◽  
pp. 1-11
Author(s):  
Vinayagam Mohanavel ◽  
Thandavamoorthy Raja ◽  
Anshul Yadav ◽  
Manickam Ravichandran ◽  
Jerzy Winczek

2020 ◽  
pp. 152808372093662
Author(s):  
K C Nagaraja ◽  
S Rajanna ◽  
G S Prakash ◽  
G Rajeshkumar

In this work the effect of stacking sequence of Carbon (C)/Glass (G) fibers and halloysites addition (1, 3 and 5 wt.%) on the mechanical and thermal properties of the hybrid composites were explored. The composite laminates were prepared by using Vacuum Assisted Resin Infusion Technique (VARIT). The outcomes disclosed that the hybrid composites having sequence of C2G3C2 (2-Carbon/3-Glass/2-Carbon layers) showed better overall properties. Moreover, the addition of halloysites enhanced the mechanical and thermal properties of the C2G3C2 hybrid composites. In particular, the hybrid composites added with 3 wt.% of halloysites showed higher overall properties among the other hybrid composites investigated. Finally, the morphological analysis was performed on the fractured surface of mechanical tested composites to study the failure mechanisms occurred. Based on the obtained results it can be concluded that the C2G3C2 hybrid composites added with 3 wt.% of halloysite could be a suitable alternative light weight material for automobile, aerospace and building structures.


2018 ◽  
Vol 935 ◽  
pp. 5-10 ◽  
Author(s):  
Azamat L. Slonov ◽  
Azamat A. Zhansitov ◽  
Elena V. Rzhevskaya ◽  
Diana M. Khakulova ◽  
Elina V. Khakyasheva ◽  
...  

The effect of the length and concentration of carbon fibers on the rheological, mechanical and thermal properties of high-temperature thermoplastics – polyphenylene sulfone was investigated. As fillers fibers with a length of 0.2 and 3 mm are used.


Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 866 ◽  
Author(s):  
Alexandre L. Pereira ◽  
Mariana D. Banea ◽  
Jorge S.S. Neto ◽  
Daniel K.K. Cavalcanti

The main objective of this work was to investigate the effect of hybridization on the mechanical and thermal properties of intralaminar natural fiber-reinforced hybrid composites based on sisal. Ramie, sisal and curauá fibers were selected as natural fiber reinforcements for the epoxy matrix based composites, which were produced by the hand lay-up technique. Tensile, flexural and impact tests were carried out according to American society for testing and materials (ASTM) standards to characterize the hybrid composites, while differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to evaluate the thermal properties. It was found that the mechanical properties are improved by hybridization of sisal based composites. The thermal analysis showed that the hybridization did not significantly affect the thermal stability of the composites. A scanning electron microscopy (SEM) was used to examine the fracture surface of the tested specimens. The SEM images showed a brittle fracture of the matrix and fiber breakage near the matrix.


2013 ◽  
Vol 401-403 ◽  
pp. 713-716
Author(s):  
Cheng Fang ◽  
Dong Bo Guan ◽  
Wei Guo Yao ◽  
Shou Jun Wang ◽  
Hui An

The epoxy resin was modified with the mixture of α,ω-dihydroxy poly-(3,3,3-trifluoropropyl) siloxane (PTFPMS), KH560 and stannous octoate. KH560 can react with PTFPMS and also epoxy resin curing agent. The two reactions were characterized by FI-IR. The modified epoxy resin was characterized by FI-IR. The result showed that fluorine-containing silicone had been successfully introduced into the epoxy system. The mechanical and thermal properties of the modified epoxy resin were analyzed. The results showed that with the increase of PTFPMS the impact strength of epoxy resin increased, hardness and bending strength correspondingly reduced, slight decrease in the glass transition temperature.


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