scholarly journals Novel Polyester Amide Membranes Containing Biquinoline Units and Complex with Cu(I): Synthesis, Characterization, and Approbation for n-Heptane Isolation from Organic Mixtures

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 645
Author(s):  
Alexandra Pulyalina ◽  
Ilya Faykov ◽  
Vera Nesterova ◽  
Mikhail Goikhman ◽  
Irina Podeshvo ◽  
...  
Keyword(s):  
Comparative Study ◽  
Physical Properties ◽  
Chemical Structure ◽  
Contact Angles ◽  
Polymer Complex ◽  
Organic Mixtures ◽  
Thermomechanical Characteristics ◽  
Flat Membranes ◽  
Pervaporation Separation ◽  
Metal Polymer

The wide possibilities of designing a chemical structure and creating complexes with transition metals make polymers of heteroaromatic structure interesting objects, from both scientific and practical aspects. In this work, modern biquinoline-containing polymers, namely polyester amide (PEA) and its metal–polymer complex (PEA–Cu(I)), were synthesized and used to form dense flat membranes. A comparative study of their morphology, same physical properties (density, free volume, and contact angles), and thermomechanical characteristics was carried out. The transport properties of the modern membranes were studied during pervaporation, to solve a problem of n-heptane isolation from its binary mixtures with thiophene and methanol. It was shown that only the PEA membrane is selective for the separation of thiophene impurities from the mixture with n-heptane. In pervaporation of methanol/n-heptane mixture, the РЕА–Cu(I) membrane exhibits significantly higher pervaporation separation index, as compared with that of the РЕА membrane.

scholarly journals A comparative study of the physical properties of Pr0.63La0.37−xSrxMnO3 (xSr = 0.00–0.30) characterized by “λ” shape dc magnetizations

AIP Advances ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 045214
Author(s):  
Riheb Hamdi ◽  
Yousef Haik ◽  
Saleh S. Hayek ◽  
Ayman Samara ◽  
Said A. Mansour
Keyword(s):  
Comparative Study ◽  
Physical Properties

Physical Properties and Chemical Structure of High-Amylose Corn Starch Fractions

1964 ◽  
Vol 16 (11) ◽  
pp. 345-351 ◽  
Author(s):  
Edna M. Montgomery ◽  
K. R. Sexson ◽  
R. J. Dimler ◽  
F. R. Senti
Keyword(s):  
Physical Properties ◽  
Chemical Structure ◽  
Corn Starch ◽  
High Amylose

Numerical Simulation of Bubble Growth During Nanofluid Flow Boiling in a Microchannel

2014 ◽  
Author(s):  
Arman Khalighi ◽  
Matthew Blomquist ◽  
Abhijit Mukherjee
Keyword(s):  
Heat Transfer ◽  
Physical Properties ◽  
Heat Dissipation ◽  
Flow Boiling ◽  
Contact Angles ◽  
Electronic Systems ◽  
Simulation Based ◽  
Fluid Media ◽  
Thermo Physical Properties ◽  
Current Heat

In recent years, heat dissipation in micro-electronic systems has become a significant design limitation for many component manufactures. As electronic devices become smaller, the amount of heat generation per unit area increases significantly. Current heat dissipation systems have implemented forced convection with both air and fluid media. However, nanofluids may present an advantageous and ideal cooling solution. In the present study, a model has been developed to estimate the enhancement of the heat transfer when nanoparticles are added to a base fluid, in a single microchannel. The model assumes a homogeneous nanofluid mixture, with thermo-physical properties based on previous experimental and simulation based data. The effect of nanofluid concentration on the dynamics of the bubble has been simulated. The results show the change in bubble contact angles due to deposition of the nanoparticles has more effect on the wall heat transfer compared to the effect of thermo-physical properties change by using nanofluid.

scholarly journals A comparative study of the physical properties of conventional and Grander-modified adhesive systems

2011 ◽  
Vol 26 (4) ◽  
pp. 315-320
Author(s):  
Sérgio Eduardo de Paiva Gonçalves ◽  
Rafael Augusto Burim ◽  
Patrícia Rondon Pleffken ◽  
Daphne Câmara Barcellos ◽  
Ana Paula Martins Gomes ◽  
...  
Keyword(s):  
Comparative Study ◽  
Physical Properties ◽  
Adhesive Systems

scholarly journals Brazilian gutta-percha points. Part II: thermal properties

2007 ◽  
Vol 21 (1) ◽  
pp. 29-34 ◽  
Author(s):  
Cláudio Maniglia-Ferreira ◽  
Eduardo Diogo Gurgel-Filho ◽  
João Batista Araújo Silva Jr ◽  
Regina Célia Monteiro de Paula ◽  
Judith Pessoa Andrade Feitosa ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Properties ◽  
Physical Properties ◽  
Ambient Temperature ◽  
Amorphous Phase ◽  
Thermal Behaviour ◽  
Chemical Structure ◽  
Scanning Calorimetry ◽  
Gutta Percha ◽  
Thermal Manipulation

This study was undertaken to explore the effect of heating on gutta-percha, analyzing the occurrence of endothermic peaks corresponding to the transformation that occurs in the crystalline structure of the polymer during thermal manipulation. This study also seeked to determine the temperature at which these peaks occur, causing a transformation from the beta- to the alpha-form, and from the alpha- to the amorphous phase. Eight nonstandardized gutta-percha points commercially available in Brazil (Konne, Tanari, Endopoint, Odous, Dentsply 0.04, Dentsply 0.06, Dentsply TP, Dentsply FM) and pure gutta-percha (control) were analysed using differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). The transition temperatures were determined and analysed. With the exception of Dentsply 0.04 and Dentsply 0.06, the majority of the products showed thermal behaviour typical of beta-gutta-percha, with two endothermic peaks, exhibiting two crystalline transformations upon heating from ambient temperature to 130°. Upon cooling and reheating, few samples presented two endothermic peaks. It was concluded that heating dental gutta-percha to 130°C causes changes to its chemical structure which permanently alter its physical properties.

Sign in / Sign up

Export Citation Format

Share Document