scholarly journals Dielectric, Thermal and Water Absorption Properties of Some EPDM/Flax Fiber Composites

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2555
Author(s):  
Anton Airinei ◽  
Mihai Asandulesa ◽  
Maria Daniela Stelescu ◽  
Niţǎ Tudorachi ◽  
Nicusor Fifere ◽  
...  

This paper deals with the dielectric and sorption properties of some flax fiber-reinforced ethylene-propylene-diene monomer (EPDM) composites containing different fiber loadings as well as their behavior after exposure to different doses of electron beam irradiation. Three relaxation processes were evinced, a weak relaxation β at sub-Tg temperatures and two α-type relaxations above the Tg. The EPDM/flax composites exhibited higher values of dielectric constant, dielectric loss and conductivity as compared to a pristine EPDM sample. Using thermogravimetric analysis (TG) coupled with Fourier transform infrared spectroscopy (FTIR) and mass spectrometry (MS) (TG/FTIR/MS system), the degradation products can be identified. The water uptake increased as the flax fiber level increased in composites. The water uptake tests of irradiated composites showed that the highest water content was obtained for a flax fiber level of 20 phr.

2017 ◽  
Vol 40 (1) ◽  
pp. 315-327 ◽  
Author(s):  
Maria Daniela Stelescu ◽  
Anton Airinei ◽  
Elena Manaila ◽  
Nicusor Fifere ◽  
Gabriela Craciun ◽  
...  

2004 ◽  
Vol 50 (5) ◽  
pp. 227-234 ◽  
Author(s):  
M. Petrovic ◽  
P. Gehringer ◽  
H. Eschweiler ◽  
D. Barceló

A commercial blend of nonylphenol ethoxylates (NPEOs) was chosen as representative for non-ionic polyethoxylated surfactants to study the oxidative degradation of this class of surfactants in water using ozonation as well as electron beam irradiation with and without the addition of ozone as treatment processes. The electron beam irradiation processes applied represent so-called Advanced Oxidation Processes (AOPs); the combined ozone/electron beam irradiation is, moreover, the most powerful AOP which can be applied in aqueous systems. It was found that both ozonation and the two AOPs applied were able to decompose not only the NPEOs but also the polyethyleneglycoles (PEGs) formed as by-products from NPEO degradation to residual concentrations below the limit of detection. Moreover, the treatment processes were also used to study the oxidative degradation of nonylphenoxy acetic acid (NPEC) and of nonylphenol (NP) which are formed as by-products from biodegradation of NPEOs.


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2431
Author(s):  
Elena Manaila ◽  
Anton Airinei ◽  
Maria Daniela Stelescu ◽  
Maria Sonmez ◽  
Laurentia Alexandrescu ◽  
...  

Composites based on ethylene–propylene–diene terpolymer (EPDM), butyl/halobutyl rubber and nanosilica were prepared by melt mixing and subjected to different doses of electron beam irradiation. The effect of irradiation dose on the mechanical properties, morphology, glass transition temperature, thermal stability and water uptake was investigated. The efficiency of the crosslinking by electron beam irradiation was analyzed by Charlesby–Pinner parameter evaluation and crosslink density measurements. The scanning electron microscopy data showed a good dispersion of nanosilica in the rubber matrix. An improvement in hardness and 100% modulus was revealed by increasing irradiation dose up to 150 kGy. The interaction between polymer matrix and nanosilica was analyzed using the Kraus equation. Additionally, these results indicated that the mechanical properties, surface characteristics, and water uptake were dependent on crosslink characteristics.


2020 ◽  
pp. 1-10
Author(s):  
X. Mohammadi ◽  
G. Matinfar ◽  
A. Mousavi Khaneghah ◽  
A. Singh ◽  
A. Pratap-Singh

Today, mycotoxins are considered a serious risk for human health and the economy around the world. Hence, dealing with them in such a way as to minimise damage to food and plant materials has become an important issue. Cold atmospheric plasma and electron beam irradiation are updated and non-thermal technologies, which are recently used in detoxification of mycotoxins. Both of these technologies have several unique features that turn them into efficient methods for degrading mycotoxins. Therefore, the main purpose of the present study is exhibiting the detoxification power of these methods and parameters affecting their activity. Besides, their advantages, generating systems, activity mechanism, and the toxicity of degradation products are also reviewed.


2010 ◽  
Vol 15 (2) ◽  
pp. 380-385 ◽  
Author(s):  
Patrícia Y. Inamura ◽  
Kleber Shimazaki ◽  
Maria Aparecida Colombo ◽  
Ricardo de Rosa ◽  
Esperidiana Augusta Barretos de Moura ◽  
...  

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