scholarly journals Impact of Particle Size on the Rheological Properties and Amylolysis Kinetics of Ungelatinized Cassava Flour Suspensions

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 989
Author(s):  
Tien Cuong Nguyen ◽  
Luc Fillaudeau ◽  
Dominique Anne-Archard ◽  
Son Chu-Ky ◽  
Hong Nga Luong ◽  
...  

The effect of particle size on enzymatic hydrolysis of cassava flour at subgelatinization temperature was investigated. A multiscale physical metrology was developed to study the evolution of different physical-biochemical parameters: rheology, granulometry, and biochemistry. In this study, four fractions of cassava flour based on the particle sizes under 75 µm (CR075), 75–125 µm (CR125), 125–250 µm (CR250), and 250–500 µm (CR500) were screened for enzymatic hydrolysis effect. The results showed that all cassava flour suspensions exhibited a shear-thinning behavior, and the viscosity increased drastically with the increase of particle size. During hydrolysis, the viscosity reduced slightly and the non-Newtonian behavior became negligible beyond 4h of the process. The particles size for CR075 and CR125 increased steadily in diameter mean. The samples of CR250 and CR500 showed more fluctuation by first decreasing, followed by increasing in particle sizes during the process. The highest hydrolysis yield was found for samples with particle size under 125 µm (89.5–90.7%), suggesting that mechanical treatment of cassava can enhance the bioconversion rate.

2012 ◽  
Vol 48 (3) ◽  
pp. 312-317 ◽  
Author(s):  
V. V. Shutova ◽  
A. I. Yusipovich ◽  
E. Yu. Parshina ◽  
D. O. Zakharkin ◽  
V. V. Revin

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Zaki S. Seddigi ◽  
Saleh A. Ahmed ◽  
Shahid P. Ansari ◽  
Ekram Danish ◽  
Abdullah Abu Alkibash ◽  
...  

Zinc oxide of different average particle sizes 25 nm, 59 nm, and 421 nm as applied in the photodegradation of MTBE. This study was carried out in a batch photoreactor having a high pressure mercury lamp. Zinc oxide of particle size of 421 nm was found to be the most effective in degrading MTBE in an aqueous solution. On using this type of ZnO in a solution of 100 ppm MTBE, the concentration of MTBE has decreased to 5.1 ppm after a period of five hours. The kinetics of the photocatalytic degradation of MTBE was found to be a first order reaction.


2013 ◽  
Vol 44 ◽  
pp. 11-17 ◽  
Author(s):  
Esha Khullar ◽  
Bruce S. Dien ◽  
Kent D. Rausch ◽  
M.E. Tumbleson ◽  
Vijay Singh

2013 ◽  
Vol 60 (1) ◽  
Author(s):  
Mohd Azizi Che Yunus ◽  
Manzurudin Hasan ◽  
Norasikin Othman ◽  
Siti Hamidah Mohd-Setapar ◽  
Liza Md.-Salleh ◽  
...  

Kajian ini bertujuan untuk mengkaji kesan saiz zarah ke atas pengekstrakan sebatian catechin daripada biji Areca catechu L. dengan menggunakan Pengekstrakan Pelarut Terpecut (PPT). Saiz zarah biji Areca catechu dipelbagaikan dari 75 μm sehingga 500 μm. Pengekstrakan telah dijalankan padaparameter tetap iaitu suhu (140oC), tekanan (1500 psi), masa (10 minit), isipadu semburan (60%) dan satu kitaran pengekstrakan, masing-masing. Hasil minyak peratusan yang lebih tinggi adalah 300 mg minyak / gram sampel (30.00% pati minyak) ditemui pada 125 μm. Walaubagaimanapun, kandungan catechin dalam pati minyak hanya 0.0375 mg catechin / gram sampel. Saiz zarah yang terbaik dalam julat uji kaji ini telah dikenal pasti pada 500 μm yang memberikan kandungan catechin yang tinggi iaitu 0.0515 mg catechin / gram sampel dari 247.5 mg minyak / gram sampel (24.75% pati minyak). Kata kunci: Saiz zarah; catechin; LC-MS-TOF; pengekstrakan pelarut terpecut The purpose of this work is to investigate the effects of particle size on the extraction of catechincompound from Areca catechu L. seeds by using Accelerated Solvent Extraction (ASE). The particle sizes of Areca catechu L. seeds are varied from 75 µm until 500 µm. The extraction is conducted at fixed parameters which are temperature (140oC), pressure (1500 psi), extraction time (10 minutes), flush volume (60%) and the static cycle is done for 1 extraction cycle respectively. Higher percentage oil yield of 300mg oil/gram of sample (30.00% oil yield) is found at 125 µm. However, the amount of catechin in oil yields is only 0.0375 mg of catechin/gram of sample. The best of particle size within the experimental range has been identified at 500 µm which gives a high content of catechin with 0.0515 mg Catechin/gram of sample from 247.5 mg oil/gram of sample (24.75% oil yield). Keywords: Particle size; catechin; LC-MS-TOF; accelerated solvent extraction


TAPPI Journal ◽  
2020 ◽  
Vol 19 (11) ◽  
pp. 585-593
Author(s):  
ETHAN GLOR ◽  
BRIAN EINSLA ◽  
JOHN ROPER ◽  
JIAN YANG ◽  
VALERIY GINZBURG

Hollow sphere pigments (HSPs) are widely used at low levels in coated paper to increase coating bulk and to provide gloss to the final sheet. However, HSPs also provide an ideal system through which one can examine the effect of pigment size and particle packing within a coating due to their unimodal and tunable particle sizes. The work presented in Part 1 and Part 2 of this study will discuss the use of blends of traditional inorganic pigments and HSPs in coating formulations across a variety of applications for improved coating strength. Part 1 of this study focuses on the theory of bimodal spherical packing and demonstrates the predictive nature of packing models on the properties of coating systems containing HSPs of two different sizes. This study also examines conditions where the model fails by examining the effect of particle size on coating strength in sytems like thermal paper basecoats where the non-HSP component has a broad particle size distribution, and how these surprising trends can be used to generate better-than-expected thermal printing performance in systems with low HSP/clay ratios. Part 2 of this study focuses on the incorporation of HSPs of different particle sizes into paperboard formulations to affect coating strength and opacity.


2020 ◽  
pp. 53-61
Author(s):  
Ansharullah Ansharullah ◽  
Muhammad Natsir

The aims of this study were to characterize the kinetics of enzymatic hydrolysis of sago starch, obtained from Southeast Sulawesi Indonesia. The enzyme used for hydrolysis was bacterial ∝-amylase (Termamyl 120L from Bacillus licheniformis, E. C. 3.2.1.1).  The method to determine the initial velocity (Vo) of the hydrolysis was developed by differentiation a nonlinear equation (NLE).  The Vo of the hydrolysis was measured at various pH (6.0, 6.5,and 7.0), temperatures (40, 60, 75 and 95oC), enzyme concentrations (0.5, 1.0, 1.5 and 2.0 µg per mL) and in the presence of 70 ppm Ca++. The optimum conditions of this experiment were found to be at pH 6.5 – 7.0 and 75oC, and the Vo increased with increasing enzyme concentration. The Vo values at various substrate concentrations were also determined, which were then used to calculate the enzymes kinetics constant of the hydrolysis, including Michaelis-Menten constant (Km) and maximum velocity (Vmax) using a Hanes plot.  Km and Vmax values were found to be higher in the measurement at pH 7.0 and 75oC. The Km values  at four  different combinations of pH and temperatures (pH 6.5, 40oC; pH 6.5, 75oC; pH 7.0, 40oC; pH 7.0, 75oC) were found to be 0.86, 3.23, 0.77 and 3.83 mg/mL, respectively; and Vmax values were 17.5, 54.3, 20.3 and 57.1 µg/mL/min, respectively. The results obtained showed that hydrolysis rate of this starch was somewhat low.


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