scholarly journals Classification of Australian Waterbodies across a Wide Range of Optical Water Types

2020 ◽  
Vol 12 (18) ◽  
pp. 3018
Author(s):  
Elizabeth J. Botha ◽  
Janet M. Anstee ◽  
Stephen Sagar ◽  
Eric Lehmann ◽  
Thais A. G. Medeiros
Keyword(s):  
Spectral Response ◽  
Optical Observations ◽  
Optical Data ◽  
Water Types ◽  
Continental Scale ◽  
Inherent Optical Properties ◽  
Eastern Australia ◽  
Wide Range ◽  
Development Goals

Baseline determination and operational continental scale monitoring of water quality are required for reporting on marine and inland water progress to Sustainable Development Goals (SDG). This study aims to improve our knowledge of the optical complexity of Australian waters. A workflow was developed to cluster the modelled spectral response of a range of in situ bio-optical observations collected in Australian coastal and continental waters into distinct optical water types (OWTs). Following clustering and merging, most of the modelled spectra and modelled specific inherent optical properties (SIOP) sets were clustered in 11 OWTs, ranging from clear blue coastal waters to very turbid inland lakes. The resulting OWTs were used to classify Sentinel-2 MSI surface reflectance observations extracted over relatively permanent water bodies in three drainage regions in Eastern Australia. The satellite data classification demonstrated clear limnological and seasonal differences in water types within and between the drainage divisions congruent with general limnological, topographical, and climatological factors. Locations of unclassified observations can be used to inform where in situ bio-optical data acquisition may be targeted to capture a more comprehensive characterization of all Australian waters. This can contribute to global initiatives like the SDGs and increases the diversity of natural water in global databases.

scholarly journals Single-nanowire spectrometers

Science ◽  
2019 ◽  
Vol 365 (6457) ◽  
pp. 1017-1020 ◽  
Author(s):  
Zongyin Yang ◽  
Tom Albrow-Owen ◽  
Hanxiao Cui ◽  
Jack Alexander-Webber ◽  
Fuxing Gu ◽  
...  
Keyword(s):  
Single Cell ◽  
Spectral Response ◽  
Spectral Imaging ◽  
Visible Range ◽  
Response Functions ◽  
In Situ Characterization ◽  
Optical Components ◽  
Wide Range ◽  
Current Systems

Spectrometers with ever-smaller footprints are sought after for a wide range of applications in which minimized size and weight are paramount, including emerging in situ characterization techniques. We report on an ultracompact microspectrometer design based on a single compositionally engineered nanowire. This platform is independent of the complex optical components or cavities that tend to constrain further miniaturization of current systems. We show that incident spectra can be computationally reconstructed from the different spectral response functions and measured photocurrents along the length of the nanowire. Our devices are capable of accurate, visible-range monochromatic and broadband light reconstruction, as well as spectral imaging from centimeter-scale focal planes down to lensless, single-cell–scale in situ mapping.

Optical properties, of waters in the Murray-Darling Basin, South-eastern Australia

1990 ◽  
Vol 41 (5) ◽  
pp. 581 ◽  
Author(s):  
RL Oliver
Keyword(s):  
Optical Properties ◽  
Relative Role ◽  
Yellow Colour ◽  
Scattering Coefficients ◽  
Inherent Optical Properties ◽  
Murray Darling Basin ◽  
Eastern Australia ◽  
The Relationship

Apparent and inherent optical properties were determined for a range of water types in the Murray- Darling basin by using a combination of field and laboratory techniques. The absorption coefficient was calculated directly from in situ irradiance measurements of photosynthetically active radiation, whereas the scattering coefficient was determined from the irradiance measurements in conjunction with published nomograms relating the apparent and inherent optical properties. The validity of the nomograms for use in these waters was confirmed by comparing values of the average cosine calculated directly from in situ measurements with those estimated from the nomograms. These were closely correlated except for sites with chlorophyll concentrations greater than 200 mg m-3. The scattering coefficients estimated from the nomograms were approximately numerically equal to the turbidity in nephelometric turbidity units, but the variability of the relationship made it unsuitable for checking the validity of the nomograms. The relative role of dissolved and particulate components in the absorption and scattering of irradiance was examined by using spectrophotometry and linear regression of inherent optical properties on concentrations of the components. Estimates of specific absorption and scattering coefficients for algae, non-chlorophyllous suspended particles, and dissolved yellow colour were comparable to similar coefficients reported in the literature. The relative importance of these components to absorption and scattering varied considerably between sites and demonstrated the need for information on inherent optical properties in understanding the factors causing changes in optical water quality.

scholarly journals A semi-analytical model for diffuse reflectance in marine and inland waters

2015 ◽  
Vol 12 (4) ◽  
pp. 1893-1912 ◽  
Author(s):  
J. D. Pravin ◽  
P. Shanmugam ◽  
Y.-H. Ahn
Keyword(s):  
Optical Properties ◽  
Water Column ◽  
Analytical Model ◽  
Diffuse Reflectance ◽  
Present Model ◽  
Open Ocean ◽  
Inherent Optical Properties ◽  
Wide Range ◽  
Good Agreement

Abstract. A semi-analytical model for predicting diffuse reflectance of coastal and oceanic waters is developed based on the water-column optical properties and illumination conditions. Diffuse reflectance (R) is an apparent optical property that is related to the Gordon's parameter (bb/(a+bb)) through a proportionality factor "f". The conventional assumption of "f" as a constant (0.33) yields large errors in case of turbid and productive coastal waters and a predictive model based on this assumption is generally restricted to open-ocean waters (low chlorophyll case). In this paper, we have sorted the dependent factors that influence "f" values in the water column. Here, the parameter "f" is modeled as a function of wavelength, depth, inherent optical properties (IOPs) and illumination conditions. This work eliminates the spectral constants (KChl and KSS) associated with our previous model and constrains the present model to be solely dependent on the IOPs and illumination conditions. Data used for parameterization and validation are obtained from in situ measurements in different waters within coastal environments. Validation shows good agreement between the model R and in situ R values with the overall mean relative error of less than a few percent. The model is valid for a wide range waters within coastal and open-ocean environments.

scholarly journals Four-dimensional distribution of the 2010 Eyjafjallajökull volcanic cloud over Europe observed by EARLINET

2012 ◽  
Vol 12 (11) ◽  
pp. 30203-30257 ◽  
Author(s):  
G. Pappalardo ◽  
L. Mona ◽  
G. D'Amico ◽  
U. Wandinger ◽  
M. Adam ◽  
...  
Keyword(s):  
Optical Properties ◽  
Central Europe ◽  
Optical Data ◽  
Volcanic Event ◽  
The Balkans ◽  
Continental Scale ◽  
Wide Range ◽  
Volcanic Cloud ◽  
The Impact ◽  
First Time

Abstract. The eruption of the Icelandic volcano Eyjafjallajökull in April/May 2010 represents a "natural experiment" to study the impact of volcanic emissions on a continental scale. For the first time, quantitative data about the presence, altitude, and layering of the volcanic cloud, in conjunction with optical information, are available for most parts of Europe derived from the observations by the European Aerosol Research Lidar NETwork (EARLINET). Based on multi-wavelength Raman lidar systems EARLINET is the only instrument worldwide that is able to provide dense time series of high-quality optical data to be used for aerosol typing and for the retrieval of particle microphysical properties as a function of altitude. In this work we show the four-dimensional (4-D) distribution of the Eyjafjallajökull volcanic cloud over Europe as observed by EARLINET during the entire volcanic event (15 April–26 May 2010). All optical properties directly measured (backscatter, extinction, and particle linear depolarization ratio) are stored in the EARLINET database available at http://www.earlinet.org. A specific relational database providing the volcanic mask over Europe, realized ad hoc for this specific event, has been developed and is available on request at http://www.earlinet.org. During the first days after the eruption, volcanic particles were detected over Central Europe within a wide range of altitudes, from the lower stratosphere down to the local Planetary Boundary Layer (PBL). After 19 April 2010, volcanic particles were detected over South and South Eastern Europe. During the first half of May (5–15 May), material emitted by the Eyjafjallajökull volcano was detected over Spain and Portugal and then over the Mediterranean and the Balkans. Last observations of the event were recorded until 25 May in Central Europe and in the Eastern Mediterranean area. For the first time, volcanic aerosol layering and optical properties are presented and discussed for the entire volcanic event on a continental scale providing an unprecedented data set for evaluating satellite data and aerosol dispersion models for these kind of volcanic events.

scholarly journals Four-dimensional distribution of the 2010 Eyjafjallajökull volcanic cloud over Europe observed by EARLINET

2013 ◽  
Vol 13 (8) ◽  
pp. 4429-4450 ◽  
Author(s):  
G. Pappalardo ◽  
L. Mona ◽  
G. D'Amico ◽  
U. Wandinger ◽  
M. Adam ◽  
...  
Keyword(s):  
Optical Properties ◽  
Central Europe ◽  
Optical Data ◽  
Data Set ◽  
Volcanic Event ◽  
The Balkans ◽  
Continental Scale ◽  
Wide Range ◽  
Volcanic Cloud ◽  
The Impact

Abstract. The eruption of the Icelandic volcano Eyjafjallajökull in April–May 2010 represents a "natural experiment" to study the impact of volcanic emissions on a continental scale. For the first time, quantitative data about the presence, altitude, and layering of the volcanic cloud, in conjunction with optical information, are available for most parts of Europe derived from the observations by the European Aerosol Research Lidar NETwork (EARLINET). Based on multi-wavelength Raman lidar systems, EARLINET is the only instrument worldwide that is able to provide dense time series of high-quality optical data to be used for aerosol typing and for the retrieval of particle microphysical properties as a function of altitude. In this work we show the four-dimensional (4-D) distribution of the Eyjafjallajökull volcanic cloud in the troposphere over Europe as observed by EARLINET during the entire volcanic event (15 April–26 May 2010). All optical properties directly measured (backscatter, extinction, and particle linear depolarization ratio) are stored in the EARLINET database available at http://www.earlinet.org. A specific relational database providing the volcanic mask over Europe, realized ad hoc for this specific event, has been developed and is available on request at http://www.earlinet.org. During the first days after the eruption, volcanic particles were detected over Central Europe within a wide range of altitudes, from the upper troposphere down to the local planetary boundary layer (PBL). After 19 April 2010, volcanic particles were detected over southern and south-eastern Europe. During the first half of May (5–15 May), material emitted by the Eyjafjallajökull volcano was detected over Spain and Portugal and then over the Mediterranean and the Balkans. The last observations of the event were recorded until 25 May in Central Europe and in the Eastern Mediterranean area. The 4-D distribution of volcanic aerosol layering and optical properties on European scale reported here provides an unprecedented data set for evaluating satellite data and aerosol dispersion models for this kind of volcanic events.

In-situ electrical-resistivity measurements in the high-voltage electron microscope

1978 ◽  
Vol 36 (1) ◽  
pp. 68-69
Author(s):  
W. E. King
Keyword(s):  
Electrical Resistivity ◽  
Electron Microscope ◽  
High Voltage ◽  
Resistivity Measurements ◽  
Voltage Electron ◽  
High Voltage Electron Microscope ◽  
High Voltage Electron ◽  
Wide Range ◽  
Helium Gas

A side-entry type, helium-temperature specimen stage that has the capability of in-situ electrical-resistivity measurements has been designed and developed for use in the AEI-EM7 1200-kV electron microscope at Argonne National Laboratory. The electrical-resistivity measurements complement the high-voltage electron microscope (HVEM) to yield a unique opportunity to investigate defect production in metals by electron irradiation over a wide range of defect concentrations.A flow cryostat that uses helium gas as a coolant is employed to attain and maintain any specified temperature between 10 and 300 K. The helium gas coolant eliminates the vibrations that arise from boiling liquid helium and the temperature instabilities due to alternating heat-transfer mechanisms in the two-phase temperature regime (4.215 K). Figure 1 shows a schematic view of the liquid/gaseous helium transfer system. A liquid-gas mixture can be used for fast cooldown. The cold tip of the transfer tube is inserted coincident with the tilt axis of the specimen stage, and the end of the coolant flow tube is positioned without contact within the heat exchanger of the copper specimen block (Fig. 2).

Site specific agricultural soil management with the use of new technologies

2013 ◽  
Vol 16 (1) ◽  
pp. 59-67
Keyword(s):  
New Technologies ◽  
Digital Interface ◽  
Appropriate Treatment ◽  
Wide Range ◽  
Soil Variation ◽  
Soil Information ◽  
Remote Sensing Techniques ◽  
Agricultural Areas

<p>The Soil Science Institute of Thessaloniki produces new digitized Soil Maps that provide a useful electronic database for the spatial representation of the soil variation within a region, based on in situ soil sampling, laboratory analyses, GIS techniques and plant nutrition mathematical models, coupled with the local land cadastre. The novelty of these studies is that local agronomists have immediate access to a wide range of soil information by clicking on a field parcel shown in this digital interface and, therefore, can suggest an appropriate treatment (e.g. liming, manure incorporation, desalination, application of proper type and quantity of fertilizer) depending on the field conditions and cultivated crops. A specific case study is presented in the current work with regards to the construction of the digitized Soil Map of the regional unit of Kastoria. The potential of this map can easily be realized by the fact that the mapping of the physicochemical properties of the soils in this region provided delineation zones for differential fertilization management. An experiment was also conducted using remote sensing techniques for the enhancement of the fertilization advisory software database, which is a component of the digitized map, and the optimization of nitrogen management in agricultural areas.</p>

Indium Bromide-catalyzed Unprecedented Hydrogenolysis: A Novel One-Pot Synthesis of Per-O-Acetylated β-carboxymethyl O and S-glycosides

2020 ◽  
Vol 24 (8) ◽  
pp. 900-908
Author(s):  
Ram Naresh Yadav ◽  
Amrendra K Singh ◽  
Bimal Banik
Keyword(s):  
Asymmetric Synthesis ◽  
Chiral Auxiliary ◽  
Bioactive Molecules ◽  
One Pot ◽  
Enantiomerically Pure ◽  
Stereoselective Glycosylation ◽  
One Pot Synthesis ◽  
Wide Range

Numerous O (oxa)- and S (thia)-glycosyl esters and their analogous glycosyl acids have been accomplished through stereoselective glycosylation of various peracetylated bromo sugar with benzyl glycolate using InBr3 as a glycosyl promotor followed by in situ hydrogenolysis of resulting glycosyl ester. A tandem glycosylating and hydrogenolytic activity of InBr3 has been successfully investigated in a one-pot procedure. The resulting synthetically valuable and virtually unexplored class of β-CMGL (glycosyl acids) could serve as an excellent potential chiral auxiliary in the asymmetric synthesis of a wide range of enantiomerically pure medicinally prevalent β-lactams and other bioactive molecules of diverse medicinal interest.

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