scholarly journals Gas Sensing with Iridium Oxide Nanoparticle Decorated Carbon Nanotubes

Sensors ◽  
2018 ◽  
Vol 19 (1) ◽  
pp. 113 ◽  
Author(s):  
Juan Casanova-Cháfer ◽  
Eric Navarrete ◽  
Xavier Noirfalise ◽  
Polona Umek ◽  
Carla Bittencourt ◽  
...  

The properties of multi-wall carbon nanotubes decorated with iridium oxide nanoparticles (IrOx-MWCNTs) are studied to detect harmful gases such as nitrogen dioxide and ammonia. IrOx nanoparticles were synthetized using a two-step method, based on a hydrolysis and acid condensation growth mechanism. The metal oxide nanoparticles obtained were employed for decorating the sidewalls of carbon nanotubes. Iridium-oxide nanoparticle decorated carbon nanotube material showed higher and more stable responses towards NH3 and NO2 than bare carbon nanotubes under different experimental conditions, establishing the optimal operating temperatures and estimating the limits of detection and quantification. Furthermore, the nanomaterials employed were studied using different morphological and compositional characterization techniques and a gas sensing mechanism is proposed.

Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 874 ◽  
Author(s):  
Juan Casanova-Cháfer ◽  
Èric Navarrete ◽  
Eduard Llobet

The properties of Iridium oxide (IrO2) decorated Multi-Wall Carbon Nanotubes (IrO2-MWCNTs) are studied for detecting nitrogen dioxide and ammonia vapors. IrO2 nanoparticles were synthetized using a hydrolysis and acid condensation growth mechanism, and subsequently employed for decorating the sidewalls of carbon nanotubes. Decorated MWCNTs films were deposited onto SiO2/Si substrates for achieving chemoresistive gas sensors. NO2 and NH3 gases were detected under different experimental conditions. Higher and more stable responses towards NH3 and NO2 were observed for iridium-oxide nanoparticle decorated MWCNT material, compared to bare MWCNT material. Raman Spectroscopy was employed to study the nanomaterials and the optimal operating temperatures were determined.


2019 ◽  
Vol 23 (1) ◽  
pp. 237-242 ◽  
Author(s):  
Rogerio V. Gelamo ◽  
Ali Abbaspourrad ◽  
C. Verissimoa ◽  
Alfredo R. Vaz ◽  
F. P. Rouxinol ◽  
...  

Author(s):  
Michela Sainato ◽  
Md Tanim Humayun ◽  
Lara Gundel ◽  
Paul Solomon ◽  
Liliana Stan ◽  
...  

ACS Nano ◽  
2014 ◽  
Vol 8 (11) ◽  
pp. 11290-11304 ◽  
Author(s):  
Xiaojie Liu ◽  
Iris Marangon ◽  
Georgian Melinte ◽  
Claire Wilhelm ◽  
Cécilia Ménard-Moyon ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1882
Author(s):  
Jin Ah Lee ◽  
Won Jun Lee ◽  
Joonwon Lim ◽  
Sang Ouk Kim

Metal oxide nanoparticles supported on heteroatom-doped graphitic surfaces have been pursued for several decades for a wide spectrum of applications. Despite extensive research on functional metal oxide nanoparticle/doped carbon nanomaterial hybrids, the role of the heteroatom dopant in the hybridization process of doped carbon nanomaterials has been overlooked. Here, the direct growth of MnOx and RuOx nanoparticles in nitrogen (N)-doped sites of carbon nanotubes (NCNTs) is presented. The quaternary nitrogen (NQ) sites of CNTs actively participate in the nucleation and growth of the metal nanoparticles. The evenly distributed NQ nucleation sites mediate the generation of uniformly dispersed <10 nm diameter MnOx and RuOx nanoparticles, directly decorated on NCNT surfaces. The electrochemical performance of the resultant hybridized materials was evaluated using cyclic voltammetry. This novel hybridization method using the dopant-mediated nucleation and growth of metal oxides suggests ways that heteroatom dopants can be utilized to optimize the structure, interface and corresponding properties of graphitic carbon-based hybrid materials.


2008 ◽  
Vol 92 (2) ◽  
pp. 023110 ◽  
Author(s):  
Jesse Wensel ◽  
Brian Wright ◽  
Dustin Thomas ◽  
Wayne Douglas ◽  
Bert Mannhalter ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (43) ◽  
pp. 24888-24894 ◽  
Author(s):  
Nibedita Behera ◽  
Manoranjan Arakha ◽  
Mamali Priyadarshinee ◽  
Biraja S. Pattanayak ◽  
Siba Soren ◽  
...  

Metal oxide nanoparticles (NPs) have shown enhanced antibacterial effects against many bacteria.


2019 ◽  
Vol 10 ◽  
pp. 105-118 ◽  
Author(s):  
Hussam M Elnabawy ◽  
Juan Casanova-Chafer ◽  
Badawi Anis ◽  
Mostafa Fedawy ◽  
Mattia Scardamaglia ◽  
...  

In this work, we investigated the parameters for decorating multiwalled carbon nanotubes with iron oxide nanoparticles using a new, inexpensive approach based on wet chemistry. The effect of process parameters such as the solvent used, the amount of iron salt or the calcination time on the morphology, decoration density and nanocluster size were studied. With the proposed approach, the decoration density can be adjusted by selecting the appropriate ratio of carbon nanotubes/iron salt, while nanoparticle size can be modulated by controlling the calcination period. Pristine and iron-decorated carbon nanotubes were deposited on silicon substrates to investigate their gas sensing properties. It was found that loading with iron oxide nanoparticles substantially ameliorated the response towards nitrogen dioxide.


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