scholarly journals Improvement of Separation Efficiency of Automobile Shredder Residue by Pre-treatment and Electrostatic Separation

2017 ◽  
Vol 10 (3) ◽  
pp. 361-365
Author(s):  
Si-On Lim ◽  
Ohhyung Han ◽  
Chulhyun Park ◽  
kimmingyu
Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 879
Author(s):  
Beom-Uk Kim ◽  
Chul-Hyun Park

There is increasing demand for an efficient technique for separating automobile shredder residue (ASR) obtained from end-of-life vehicles (ELVs). A particular challenge is the physical separation of conductive materials from glass. In this study, the performance of pretreatment and induction electrostatic separation process was evaluated. The results show that a sieving/washing (combination of sieving and washing) pretreatment was the most effective for removing conductive material compared to electrostatic separation alone. The optimum separation efficiency of copper products was achieved with an applied voltage of 20 kV, a relative humidity of less than 35%, and a splitter position of 8 cm. Although the separation efficiency was slightly reduced when some small glass particles remained attached to the conductive materials, the separation efficiency of copper from the pretreated ASR dramatically increased to 83.1% grade and 90.4% recovery, compared to that of raw ASR (34.3% grade and 58.6% recovery). Based on these results, it was demonstrated that the proposed sieving/washing pretreatment was proficient at removing conductive materials from glass; thus, it has the potential to significantly improve the efficiency of electrostatic separation for ASR.


2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Mirela Dulama ◽  
Nicoleta Deneanu ◽  
Cristian Dulama ◽  
Margarit Pavelescu

The paper presents the experimental tests concerning the treatment by membrane techniques of radioactive aqueous waste. Solutions, which have been treated by using the bench-scale installation, were radioactive simulated secondary wastes from the decontamination process with modified POD. Generally, an increasing of the retention is observed for most of the contaminants in the reverse osmosis experiments with pre-treatment steps. The main reason for taking a chemical treatment approach was to selectively remove soluble contaminants from the waste. In the optimization part of the precipitation step, several precipitation processes were compared. Based on this comparison, mixed [Fe(CN)6]4-/Al3+/Fe2+ was selected as a precipitation process applicable for precipitation of radionuclides and flocculation of suspended solid. Increased efficiencies for cesium radionuclides removal were obtained in natural zeolite adsorption pre-treatment stages and this was due to the fact that volcanic tuff used has a special affinity for this element. Usually, the addition of powdered active charcoal serves as an advanced purifying method used to remove organic compounds and residual radionuclides; thus by analyzing the experimental data (for POD wastes) one can observe a decreasing of about 50% for cobalt isotopes subsequently to the active charcoal adsorption.. The semipermeable membranes were used, which were prepared by the researchers from the Research Center for Macromolecular Materials and Membranes, Bucharest. The process efficiency was monitored by gamma spectrometry.


2001 ◽  
Vol 42 (5) ◽  
pp. 573-586 ◽  
Author(s):  
S Galvagno ◽  
F Fortuna ◽  
G Cornacchia ◽  
S Casu ◽  
T Coppola ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2734
Author(s):  
Bin Yang ◽  
Ming Chen

Automobile shredder residue (ASR) pyrolysis produces solid, liquid, and gaseous products, particularly pyrolysis oil and gas, which could be used as renewable alternative energy resources. Due to the primary pyrolysis reaction not being complete, the yield of gaseous product is low. The pyrolysis tar comprises chemically unstable volatiles before condensing into liquid. Understanding the characteristics of volatile products will aid the design and improvement of subsequent processes. In order to accurately analyze the chemical characteristics and yields of volatile products of ASR primary pyrolysis, TG–FTIR–GC/MS analysis technology was used. According to the analysis results of the Gram–Schmidt profiles, the 3D stack plots, and GC/MS chromatograms of MixASR, ASR, and its main components, the major pyrolytic products of ASR included alkanes, olefins, and alcohols, and both had dense and indistinguishable weak peaks in the wavenumber range of 1900–1400 cm−1. Many of these products have unstable or weaker chemical bonds, such as =CH–, =CH2, –C=C–, and –C=CH2. Hence, more syngas with higher heating values can be obtained with further catalytic pyrolysis gasification, steam gasification, or higher temperature pyrolysis.


Minerals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 568 ◽  
Author(s):  
Jincheng Ran ◽  
Xianyang Qiu ◽  
Zhen Hu ◽  
Quanjun Liu ◽  
Baoxu Song

In this study, the surface modification of arsenopyrite and pyrite with low temperature oxygen plasma was developed as an effective approach to improve the flotation separation efficiency of minerals. The micro-flotation experiments results indicated that plasma pre-treatment can achieve selective flotation of arsenopyrite from pyrite. The XPS analysis results indicated that the oxidation degree of plasma-modification arsenopyrite surface is much higher than that of pyrite. A large number of sulfide components on the surface of the mineral were oxidized to highly-valence hydrophilic oxides by plasma pre-treatment. ICP-MS analysis results revealed that the dissolution rate was determined by the oxidation degree of minerals and plasma modified accelerated the dissolution of arsenopyrite and pyrite. Zeta potential determination results confirmed that plasma can keep a relatively higher adsorption of SBX on the pyrite surface but inhibit the adsorption of collector onto the arsenopyrite surface.


Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1682 ◽  
Author(s):  
Bin Yang ◽  
Ming Chen

Pyrolysis and gasification have gradually become the main means to dispose of automobile shredder residue (ASR), since these methods can reduce the volume and quality of landfill with lower cost and energy recovery can be conducted simultaneously. As the ASR pyrolysis process is integrated, the results of pyrolysis reactions of organic components and the interaction among polymeric components can be clarified by co-pyrolysis thermogravimetric experiments. The results show that the decomposition mechanisms of textiles and foam are markedly changed by plastic in the co-pyrolysis process, but the effect is not large for rubber and leather. This effect is mainly reflected in the pyrolysis temperature and pyrolysis rate. The pyrolytic trend and conversion curve shape of the studied ASR can be predicted by the main polymeric components with a parallel superposition model. The pyrolytic product yields and characterizations of gaseous products were analyzed in laboratory-scale non-isothermal pyrolysis experiments at finished temperatures of 500 °C, 600 °C, and 700 °C. The results prove that the yields of pyrolytic gas products are determined by the thermal decomposition of organic substances in the ASR and final temperature.


2020 ◽  
Vol 64 (3) ◽  
pp. 357-363 ◽  
Author(s):  
Mihály Zakar ◽  
Dániel Imre Farkas ◽  
Erika Hanczné Lakatos ◽  
Gábor Keszthelyi-Szabó ◽  
Zsuzsanna László

This study aimed to investigate the effect of ozone and Fenton-reaction as a pre-treatment before ultrafiltration of model dairy waste waters containing sodium caseinate. Filtration resistances and pollutant retentions were determined and compared. It was found, that both pre-treatment increased the retention, achieving almost 100 % pollutant elimination efficiency after short term pre-oxidation. The effect of Fe-ion concentration on Fenton pretreatment efficiency also was examined, and it was found that higher concentration resulted in decreased filtration resistances, revealing that coagulation-flocculation effect of reactants has dominant role in the protein separation efficiency. The presence of lactose also affects the pollutant removal efficiency, it promotes fouling in presence of Fenton reagents.


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