scholarly journals Solid State Reaction Synthesis and Characterization of Aluminum Doped Titanium Dioxide Nanomaterials

2020 ◽  
Vol 55 (2) ◽  
Author(s):  
Muna Muzahim Abbas ◽  
Mohammed Rasheed
Keyword(s):  
Titanium Dioxide ◽  
Solid State ◽  
Titanium Dioxide Nanoparticles ◽  
Weight Fraction ◽  
Optical Microscope ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray ◽  
Doped Titanium Dioxide ◽  
Diffraction Patterns

In this paper, aluminum doped titanium dioxide nanopowder with doping concentration of different weights were successfully prepared with a simple technique: the classic ceramic technique (or solid-state method). This technique permits the acquiring of powders as pellets with a small amount of the material. The best conditions for the prepared pellets are obtained. Titanium dioxide nanoparticles are mixed with different amounts of aluminum concentrations (0%, 3%, 5%, and 7%). The powders were then mixed and consolidated into pellets and sintered using a conventional furnace at 1100oC. The mechanical, thermal, structural, morphological (including roughness of the samples’ surfaces), and optical properties for those as-prepared samples are demonstrated by: Shore D hardness instrument, roughness test Instrument, Lee's Disc, X-ray diffraction, optical microscope, scanning electronic microscope, energy-dispersive X-ray spectroscopy and Fourier-transform infrared spectroscopy, respectively. The effect of aluminum doped concentrations on the characteristics of titanium dioxide nanoparticles depending on the above instruments are studied. The X-ray diffraction patterns appear to the crystallinity of these materials with a grain size between 20 nm and 30 nm. A roughness measurement indicates that the value of titanium dioxide nanoparticles decreases with the addition of aluminum weights according to the results of the hardness of the samples. Moreover, the results showed that the thermal conductivity increased with the increasing weight fraction of aluminum material. The main goal of the present paper is to investigate the annealing temperature-dependent behavior of the broadening parameter and the characteristics of aluminum doped titanium dioxide nanoparticles.

scholarly journals Investigation of Structural, Mechanical, Thermal and Optical Properties of Cu Doped TiO2

2021 ◽  
Vol 19 (48) ◽  
pp. 1-9
Author(s):  
Muna M. Abbas ◽  
Mohammed RASHEED
Keyword(s):  
Titanium Dioxide ◽  
Dopant Concentration ◽  
Weight Fraction ◽  
Optical Microscope ◽  
Solid State Method ◽  
X Ray ◽  
Nano Powder ◽  
Morphological Studies ◽  
Test Instrument ◽  
Electronic Microscope

In this work, Pure and Cu: doped titanium dioxide nano-powder was prepared through a solid-state method. the dopant concentration [Cu/TiO2 in atomic percentage (wt%)] is derived from 0 to 7 wt.%. structural properties of the samples performed with XRD revealed all nanopowders are of titanium dioxide having polycrystalline nature. Physical and Morphological studies were conducted using a scanning electronic microscope SEM test instrument to confirm the grain size and texture. The other properties of samples were examined using an optical microscope, Lee's Disc, Shore D hardness instrument, Fourier-transform infrared spectroscopy (FTIR), and Energy-dispersive X-ray spectroscopy (EDX). Results showed that the thermal conductivity increased with the weight fraction of the Cu element increasing.

Fabrication of Ytterbium-Doped Titanium Dioxide Nanoparticles Using Collagen as Template

2013 ◽  
Vol 873 ◽  
pp. 183-187
Author(s):  
Yi Wu Liu ◽  
Bi Wang ◽  
Bing Wei Luo ◽  
Qian He
Keyword(s):  
Titanium Dioxide ◽  
Titanium Dioxide Nanoparticles ◽  
Metal Oxide Nanoparticles ◽  
X Ray Diffraction ◽  
X Ray ◽  
High Crystallinity ◽  
Transmission Electron ◽  
Ft Ir ◽  
Doped Titanium Dioxide ◽  
Ytterbium Doping

Yb-doped titanium dioxide nanoparticles were synthesized using collagen as the template, and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-Vis spectrophotometry, and Fourier transform infrared (FT-IR) spectra. The effect of doping concentration and calcination temperature on structure of TiO2was discussed. The results showed the Yb-TiO2nanoparticles have high crystallinity with the size of 18-28 nm. Ytterbium doping could inhibit the phase transformation from anatase to rutile of TiO2, reduce the crystallite size, improve thermal stability, and improve the light absorption. This study indicates that collagen could be used as an ideal biological template to prepare metal oxide nanoparticles with high crystallinity.

Facile Solid State Method Route Synthesis and Enhance Visible Light Activities of BiVO4 by Doping Co

2016 ◽  
Vol 703 ◽  
pp. 316-320
Author(s):  
Hai Feng Chen ◽  
Jing Ling Hu ◽  
Bing Xu
Keyword(s):  
Solid State ◽  
Visible Light ◽  
Catalytic Effect ◽  
Catalytic Properties ◽  
Raw Materials ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
Illumination Time ◽  
X Ray ◽  
State Method

Using NH4VO3, Bi (NO3)3•5H2O and Co (NO3)2•6H2O as raw materials, Co doped BiVO4 (Co/BiVO4) photocatalysts were successfully prepared by solid state method. And the photo catalytic properties were test in this work. Crystal structures of these samples were characterized by X-ray diffraction (XRD). The Methyl Orange (MO) was simulated as the sewage under the visible light to explorer the influence of the illumination time and the mass of photocatalyst. The visible-light absorption spectrum of BiVO4 was broadening with doping Co. It was found that the Co/BiVO4 had higher photocatalytic activity than pure BiVO4 .The reason of enhanced catalytic effect also had been analyzed and discussed in the article.

scholarly journals Making and Characterization of Limnpo4 Using Solid State Reaction Method for Lithium Ion Battery Cathodes

2019 ◽  
pp. 583-588
Author(s):  
Adelyna Oktavia ◽  
Kurnia Sembiring ◽  
Slamet Priyono
Keyword(s):  
Solid State ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Solid State Reaction Method ◽  
Raw Material ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray ◽  
General Investigation

Hospho-material of olivine, LiMnPO4 identified as promising for cathode material generation next Lithium-ion battery and has been successfully synthesized by solid-state method with Li2Co3, 2MnO2, 2NH4H2PO4 as raw material. The influence of initial concentration of precursors at kalsinasi temperatures (400-800 ° C) flows with nitrogen. The purity and composition phase verified by x-ray diffraction analysis (XRD), scanning electron microscopy (SEM), spectroscopy, energy Dispersive x-ray Analysis (EDS), Raman spectra. General investigation shows that there is a correlation between the concentration of precursors, the temperature and the temperature of sintering kalsinasi that can be exploited to design lithium-ion next generation.

Doping Titanium Dioxide by Fluoride Ion

2019 ◽  
Vol 946 ◽  
pp. 181-185 ◽  
Author(s):  
Sergei N. Fedorov ◽  
Vladimir Yuryevich Bazhin ◽  
Vladimir G. Povarov
Keyword(s):  
Titanium Dioxide ◽  
Hydrofluoric Acid ◽  
Thermodynamic Data ◽  
Temperature Increase ◽  
Sol Gel ◽  
Chemical Properties ◽  
Fluoride Ion ◽  
X Ray Diffraction ◽  
X Ray ◽  
Doped Titanium Dioxide

Titanium dioxide has a special feature: anatase, to rutile transformation which was considered in our investigations. It is especially important to keep anatase form of titanium dioxide for photocatalytic materials, different ceramics with tribo-chemical properties, self-cleaning coatings and self-sterilizing coatings. For that only one of the titanium dioxide forms is more suitable – anatase, which is more active but not stable, because it transforms to rutile during the time or with the temperature increase loses its activity. Different methods of stabilising anatase have been considered in the paper. Several doping agents have been determined and it was chosen fluorine ion to modify titanium dioxide. Stabilization of anatase is achieved by preparing the reaction mixture by a sol-gel method with hydrofluoric acid. It has shown thermodynamic data, results of experiment, temperatures of anatase to rutile transformation of non-doped and doped titanium dioxide, its X-Ray diffraction and TGA. It is proved that titanium dioxide doped by fluorine ion keeps anatase form till the temperature is more than 1000 °C.

Synthesis and Characterization of 3Y-TZP by Gel Solid-State Method

2011 ◽  
Vol 412 ◽  
pp. 61-64
Author(s):  
Xiao Bo Wu ◽  
Da Zhi Sun ◽  
Dan Yu Jiang ◽  
Hai Fang Xu ◽  
De Xin Huang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Sintering Behavior ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray ◽  
Powder Particles ◽  
State Method ◽  
Average Size

3Y-TZP powder has been successfully synthesized by gel solid-state method. The structural phases of powder particles were analyzed by X-ray diffraction and the morphology was analyzed by scanning electron microscopy. The average size of grains was 230 nm. The sintering behavior, mechanical properties and microstructure of 3Y-TZP ceramics sintered by this powder were investigated. The experiment results showed that the mechanical properties of ceramics were excellent.

Photoconversion of CO2 using copper-modified titanium dioxide nanoparticles

2011 ◽  
Vol 76 (11) ◽  
pp. 1335-1346 ◽  
Author(s):  
Jing Wei ◽  
Xin Tan ◽  
Tao Yu ◽  
Lin Zhao
Keyword(s):  
Titanium Dioxide ◽  
Photoelectron Spectroscopy ◽  
Titanium Dioxide Nanoparticles ◽  
Sol Gel ◽  
Chemical Properties ◽  
High Photocatalytic Activity ◽  
X Ray Diffraction ◽  
X Ray ◽  
Uv Illumination ◽  
One Step

A series of copper-modified titanium dioxide (Cu/TiO2) nanoparticles were synthesized via one-step sol-gel method. The crystal structure and chemical properties were characterized using X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The Cu/TiO2nanoparticles were applied to CO2photoconversion and the yield of formaldehyde was used to evaluate the photocatalytic performance. The optimum amount of copper modifying was 0.6 wt.% and the yield of formaldehyde was 946 μmol/gcatunder UV illumination for 6 h. 20 wt.% Cu/TiO2also performed a high photocatalytic activity, which yielded 433 μmol/gcatformaldehyde under UV illumination for 6 h.

Powder X-Ray Data for Synthetic Anhydrous Sodium Zirconium Silicates

1987 ◽  
Vol 2 (3) ◽  
pp. 176-179 ◽  
Author(s):  
G. Wilson ◽  
F. P. Glasser
Keyword(s):  
Solid State ◽  
Diffraction Pattern ◽  
Powder Diffraction ◽  
Solid State Reaction ◽  
The Other ◽  
X Ray Diffraction ◽  
Powder Diffraction File ◽  
X Ray ◽  
Sodium Zirconium ◽  
Diffraction Patterns

AbstractA systematic survey of phase formation in the Na2O-ZrO2-SiO2 system has revealed inconsistencies in the number and identity of ternary phases, and of their X-ray powder data. The phases Na2ZrSiO5, Na4Zr2Si3O12, Na2ZrSi2O7 and Na2ZrSi4O11 were prepared by solid-state reaction and their experimental X-ray diffraction patterns measured. Calculated X-ray diffraction patterns were generated by computer, using published crystallographic data, and critically compared with the experimentally observed values. The unit-cell constants were redefined to a greater accuracy than the presently accepted values published in the Powder Diffraction File. Only Na4Zr2Si3O12 produced an X-ray diffraction pattern which agreed with that previously published; those from the other phases were significantly different in both the intensities and positions of the reflections. Data for synthetic Na2ZrSi4O11 identical to the mineral vlasovite are reported.

scholarly journals Synthesis, Crystal Structure, and Electrical Properties of a New Molybdylarsenate LiNa5K3Mo11As3O45

2014 ◽  
Vol 2014 ◽  
pp. 1-9
Author(s):  
Hamadi Hamza ◽  
Mohamed Faouzi Zid ◽  
Ahmed Driss
Keyword(s):  
Crystal Structure ◽  
Electrical Conductivity ◽  
Solid State ◽  
Inorganic Compound ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
One Dimensional ◽  
X Ray ◽  
Triclinic System ◽  
State Method

LiNa5K3Mo11As3O45 is a new inorganic compound. It was synthesized by a solid state method. The crystal structure has been studied by single crystal X-ray analysis. The R-values reached 2.8%. The title compound crystallizes in the triclinic system, space group P-1, with a = 10.550 (2) Å, b = 11.723 (2) Å, c = 17.469 (3) Å, α = 102.35 (3)°, β = 87.61 (2)°, and γ = 111.03 (3)°. The anionic unit [Mo11As3O45]9− is formed by nine MoO6 octahedra, two MoO5 trigonal bipyramids, and three AsO4 tetrahedra. The association of [Mo11As3O45]9− units, running along [010], leads to a one-dimensional framework. Li, K, and Na are located in the space surrounding the anionic ribbons. This material was characterized by SEM microscopy, IR spectroscopy, and powder X-ray diffraction. The electrical conductivity was investigated from 528 K to 673 K by impedance complex followed by DSC spectroscopy.

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