scholarly journals The Galvanic Corrosion Behavior of Phosphated Carbon Steel Used at Carabiners Manufacturing

2019 ◽  
Vol 70 (1) ◽  
pp. 215-219 ◽  
Author(s):  
Diana Petronela Burduhos Nergis ◽  
Carmen Nejneru ◽  
Dumitru Doru Burduhos Nergis ◽  
Cristian Savin ◽  
Andrei Victor Sandu ◽  
...  

The carabiners are metallic links used to quickly connect the components of personal fall arrest equipment. Because these systems are used in corrosive environments, the carabiners must possess good corrosion resistance properties. In order to improve these properties, a phosphate layer was chemically deposited by converting on the carabiner material surface. This paper presents the microscopic analysis of the phosphated layer and the galvanic corrosion behavior of phosphated carbon steel, coupled to duralumin and initial carbon steel. Corrosion resistance has been studied for Black Sea water and fire extinguishing solution.

2020 ◽  
Vol 10 (8) ◽  
pp. 2753 ◽  
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Petrica Vizureanu ◽  
Andrei Victor Sandu ◽  
Costica Bejinariu

This study aims to evaluate the corrosion resistance of carbon steel, used for carabiners manufacturing, coated with three different types of phosphate layer. The phosphate layers have been obtained by phosphate conversion coating with three different types of phosphate solutions: zinc-based solution, zinc-iron-based phosphate solution, and manganese-based phosphate solution. Additionally, the test was performed on zinc phosphate samples impregnated with molybdenum bisulfate-based oil and zinc phosphate samples further coated with a layer of elastomer-based paint. Considering the areas where the carabiners are used (civil engineering, navigation, oil industry, rescue operations, etc.), the corrosive environments studied are rainwater, Black Sea water, and fire extinguishing solution. The structure of the deposited layers was studied by scanning electron microscopy, while the interface structure between the alloy and corrosive environment was analyzed by electrochemical impedance spectroscopy. According to this study, the corrosion resistance of zinc-based phosphate coated samples and zinc/iron-based phosphate coated samples is higher than that of the studied carbon steel samples, despite the corrosion environment. Also, the most aggressive corrosion environment was the fire extinguishing solution.


Coatings ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1542
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Dumitru-Doru Burduhos-Nergis ◽  
Costica Bejinariu

Worker safety is one of the main aspects to be taken into account in any activity carried out at work. When we talk about the safety of the worker at activities carried out at height, the condition and characteristics of the personal protective equipment against falling from a height are one of the main causes of work accidents resulting in serious injuries or death. Carabiners are the main components of the safety system; their role is to connect the other components of the system or to make the connection between the system and the anchor point. Therefore, to be used safely, the carabiners’ material must have high corrosion resistance in different environments. This paper is part of a complex study that aims to improve the corrosion properties of carbon steel used in the manufacture of carabiners. Previous studies have shown that the corrosion resistance of carbon steel in various corrosive environments has been improved by the deposition of different types of phosphate layers, as well as other subsequently deposited layers. The aim of this paper is to study the galvanic corrosion evaluation between different galvanic couples (duralumin-coated samples, aluminium bronze-coated samples, and carbon steel-coated samples) tested in three different corrosive media. Moreover, the study approaches for the first time the galvanic corrosion of systems that can be formed between the materials used in the manufacture of carabiners. Accordingly, it was observed that, overall, the samples coated with a Zn phosphate layer exhibited the best performance in all the corrosive environments (saltwater and fire extinguishing solution).


2018 ◽  
Vol 7 (3.20) ◽  
pp. 412
Author(s):  
Azhar Wahab Abdalrhem ◽  
Ali Jaber Naeemah ◽  
Makki Noori jawad

This work was to investigating the corrosion behavior of low carbon steel in a salt solution of 3.5wt% NaCl after undergoing two different types of heat treatment at 960 ºC in a furnace. The material of low carbon steel was cut into nine small pieces under three groups A, B and C, without heated annealing and hardening heat treatment respectively. The heat treatment was at temperature 960ºC. The hardness of the sample as received will be 203 kg/mm2 while after hardening the hardness was increased. The sample was mounted using hot and cold mounting. The microstructure and surface morphology was observed by using Scanning Electron Microscope (SEM) and Optical Microscope (OM) after grinding, polishing and etching on the sample. In group A cementite can be observed clearly on pearlite on the surface before corrosion test. After four days soaking in 3.5 wt% NaCl solution was observed all cementite and pearlite will be transformed to austenite with the remnants of cementite make the surface unstable hence increases the initial corrosion. After four days soaking when the cementite is oxidized and a thick film of corrosion product covers the material surface. The formation of Martensite due to quenching and rapid cooling in group C sample increases the corrosion rate from 0.072 mpy to 0.302 due to decreased of corrosion potential from -572 mV to -639 mV after four days soaking. The corrosion rate of each sample was measured by using electrochemical polarization measurement and Tafel extrapolation technique. From previous result, it was observed that samples which had undergone annealing mode of heat treatment turned out to be the ones with the best corrosion resistance.  


Author(s):  
Leonardo Augusto Luiz ◽  
Juliano de Andrade ◽  
Camila Melo Pesqueira ◽  
Irene Bida de Araújo Fernandes Siqueira ◽  
Gustavo Bavaresco Sucharski ◽  
...  

2020 ◽  
Vol 1012 ◽  
pp. 401-406
Author(s):  
Carlos Trivellato de Carvalho Filho ◽  
Pedro Paiva Brito

In the present work, the friction surfacing process was applied to manufacture aluminum alloy (AA6351) coatings on low carbon steel (AISI 1020) substrates. After friction surfacing the AA6351 deposited coatings were submitted to two finishing process in order to adjust surface roughness: milling and milling followed by sanding. The corrosion behavior of the two finishing process was compared with the as-deposited condition in order to determine the influence of surface roughness on the corrosion resistance of friction surfacing coatings. The corrosion behavior was examined by electrochemical impedance spectroscopy and potentiodynamic polarization in a 3.5wt.%NaCl solution containing naturally dissolved O2. The results obtained indicated that the elevated surface roughness observed in the as-deposited condition led to relatively lower corrosion resistance in comparison, with lower values for polarization resistance and more anodic corrosion potential.


CORROSION ◽  
10.5006/3672 ◽  
2020 ◽  
Author(s):  
Dinh Pham ◽  
Sachiko Hiromoto ◽  
Equo Kobayashi

The influences of Zn content and heat treatment on microstructure and corrosion behavior of Mg-xZn (x=1, 3, 5 and 7 wt.%) alloys were studied. (α-Mg + MgZn) eutectic cells and Zn-segregated regions were formed in the as-cast alloys. The Zn-rich phases acted as micro-cathodes in galvanic corrosion. Volume fraction of the Zn-rich phases increased with Zn content of the as-cast alloys, leading to a decrease in corrosion resistance. The corrosion rate of the as-cast alloys increased by 4 times with an increase of the volume fraction of eutectic cell from 0.07 vol.% of Mg-1Zn alloy to 2.18 vol.% of Mg-5Zn alloy. The corrosion rate of Mg-7Zn alloy with 2.87 vol% eutectic cells was 2 times higher than that of Mg-5Zn alloy. The Zn-rich phases dissolved by the T4 treatment and only the T4-treated Mg-7Zn alloy obviously showed eutectic cells of 1.73 vol.%. The polarization resistance (Rp) of the T4-treated Mg-1, 3 and 5Zn alloys was 2-10 times higher than that of the as-cast alloys. The T4-treated Mg-7Zn showed similar Rp to the as-cast Mg-5Zn alloy. Consequently, the volume fraction of Zn-rich phases dominated the corrosion resistance of Mg-xZn alloys.


2020 ◽  
Vol 1 (2) ◽  
pp. 12-17
Author(s):  
Chao Zhang ◽  
Xiang Yin ◽  
Chun Qing

The objective of the study was to conduct the comparative analysis of steel types corrosion resistance. Three selected steel types were used in the study. The selected types were structural steel, stainless steel, and MMFX steel. The methodology we adopted is that we evaluated the steel parts resistance towards corrosion by doing in-salt spray experiment and the immersion of aqueous solution of sodium chloride. For salt spray test, we used guidelines by ASTM B117. This practice provides a controlled corrosion environment which is used for exposing specimen to salt spray chamber. For immersion test, test specimens are analyzed at regular time interval as the first rust is appeared. For carbon steel, we used three specimen and mostly initial rust appeared in initial 13 to 15 hours. For stainless steel, inter granular corrosion were analyzed. The results show that the first cycle started after about 46 hours; the second cycle started about 1% and the third cycle started with the rage of about 2 to 30%. For MMFX 2 steel, the results show that for MMFX carbon steel, the chloride threshold ratio is about 6 times higher than black bars and more than double of other types. The conclusion of the study is that in big structures like bridges, the MMFX steel should be used.


2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
V. Johnsirani ◽  
J. Sathiyabama ◽  
Susai Rajendran ◽  
A. Suriya Prabha

The inhibition efficiency (IE) of an aqueous extract of henna leaves in controlling corrosion of carbon steel in seawater has been evaluated by weight-loss method. The weight loss study reveals that the formulation consisting of 8 mL of henna extract (HE) and 25 ppm of Zn2+ has 94% inhibition efficiency in controlling corrosion of carbon steel in sea water. Polarization study reveals that HE and Zn2+ system functions as mixed type inhibitor. AC impedance spectra reveal that protective film is formed on the metal surface. The nature of the metal surface has been analysed by FTIR spectra, SEM, and AFM analysis.


2018 ◽  
Vol 53 (8) ◽  
pp. 625-632 ◽  
Author(s):  
Wangping Wu ◽  
Jianwen Liu ◽  
Xiaoyan Li ◽  
Tongshu Hua ◽  
Xiao Cong ◽  
...  

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