scholarly journals The Effect of Manganese Ion Impurity on the Kinetics and Overvoltage of Zinc Electrodeposition from a Sulfate Solution.

1974 ◽  
Vol 28a ◽  
pp. 93-98 ◽  
Author(s):  
Miguel Saloma ◽  
Hans Holtan Jr. ◽  
E. N. Svendsen ◽  
Terje Østvold ◽  
Alf Bjørseth ◽  
...  
2007 ◽  
Vol 561-565 ◽  
pp. 1669-1672 ◽  
Author(s):  
Qing Hua Tian ◽  
Xue Yi Guo ◽  
Ping Xue ◽  
Yu Song ◽  
Lian Duan

It is very possible for the foam zinc materials to take the place of zinc powder and become a new ideal material of electrode for zinc-air battery, because of its excellent three dimensional reticulated structure, high porosity, high specific surface area and uniform quality, and was widely used in many other fields. A novel method for preparing very porous zinc foam was proposed, in which the polyurethane foam as substrate was processed by degreasing process, roughening process, activation, electroless plating and zinc electrodeposition. Then, experiments were carried out to explore the effects of the solution composition(concentration of ZnSO4)and the operation conditions (such as the interelectrode distance; current density, temperature, pH value of electroplating solution and so on) on the morphology of the foam zinc and the current efficiency. The optimum experimental conditions were determined by optimizing the factors. On these conditions the foam zinc presents a three-dimensional reticular structure with high porosity, and uniformity, and the outward appearance of the coating is bright.


1983 ◽  
Vol 48 (2) ◽  
pp. 421-438 ◽  
Author(s):  
Milan Pospíšil ◽  
Jiří Spěváček ◽  
Jindřich Kryška

Hydrated iron(III) oxides were obtained by discontinuous precipitation of an iron(II) sulfate solution with aqueous ammonium - saturated with carbon dioxide to different CO2/NH3 ratios. An additional thermal treatment of these oxides, under different conditions, provided genetic sequences of intermediates and their final products - catalysts on a Fe2O3/K2O basis, with different promoters. The catalysts were studied by means of the microstructural; analysis, thermogravimetry, DTA, IR spectroscopy and further tested by the dehydrogenation of ethylbenzene to styrene. It was observed that by changing the CO2/NH3 ratio in the precipitation of the initial solutions one can influence some of the properties, as well as, the morphology and thermal stability of the initial intermediates of the preparation of the catalysts. The above mentioned properties become practically unified with the increasing number of the heat treatment operations, with all the investigated catalysts - with the exception of the catalysts' behaviour during their reduction with hydrogen. The presence of iron oxides in various valency states and the different phase composition of the catalysts during their reduction affect the final activity and selectivity of the catalyst in the reaction under the study.


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