K X-ray spectra have been obtained from Platinum-Group Element (PGE) minerals using 40 MeV Proton-Induced X-ray Emission. It is possible to resolve all four component X-ray lines for the PGEs. In cases where there is more than one PGE present, some K X-ray lines may overlap, but in all cases, there were single lines available for quantitative analysis. The spectrum obtained from the sperrylite during exposure to the proton beam beam contained Au X-rays. The presence of the Au can be attributed to (p,xn) reactions with Pt, induced by proton bombardment of the sample. The intensity of Au X-ray lines in the spectrum is proportional to the amount of Pt in the sample and the cross-section for (p,xn) reactions between Pt and Au at 40 MeV.