Construction and Operating Parameters of Adsorptive Chillers

The chapter is devoted to the design and performance of adsorptive chillers. Basic types of design and operating principle of adsorptive chillers were analyzed. Advantages and disadvantages performance of one-, two-, three-, and four-bed solar power adsorptive chillers are compared. Performance of adsorptive refrigerators based on composite adsorbents was studied. The correlation between the adsorbent composition and the coefficient of energy performance of the adsorptive chiler was revealed. An optimal composition of adsorbent 'silica gel – sodium sulphate' is stated to be of 20% silica gel and 80% sodium sulphate. The maximal values of the coefficient of performance of cycle of studied solar adsorptive chiller about of 1.14 are stated for composites containing about 20 wt. % silica gel and 80 wt% sodium sulphate. As a consequence of decreasing of adsorbent mass, the coefficient of performance is shown to increase when sodium sulphate content in the composite increased. Regeneration process parameters of the composite were shown to strongly affect on the coefficient of performance of the adsorptive chiller. The growth of the coefficient of performance is stated to result from decreasing the difference between adsorbent temperature and regeneration temperature from 85 to 55°C. The basic factors affecting the net coefficient of energy performance of the adsorptive solar refrigerator were stated daily solar radiant flux alongside with composition of the adsorbent and difference between adsorbent temperature and temperature regeneration. Net coefficients of performance of solar adsorptive refrigerator based on composite ‘silica gel – sodium sulphate' were stated to change from 0.25 to 0.34 during operating period. Utilization of the adsorption heat is suggested to warm the heat carrier which applied to heat adsorbent during regeneration. The ways to improve the design and performance of adsorptive solar chillers are suggested. The first one involves the introduction of solar collectors made of cellular polycarbonate plastics in the design of adsorptive solar chiller. Instantaneous efficiency coefficient were calculated as special thermal performance-solar radiant flux surface density ratio, optical efficiency factor is determined as special thermal performance-solar radiant flux surface density ratio at the equal temperatures of heat transfer medium and environment, reduced heat loss factor being calculated as the product of solar collector efficiency factor and net heat loss coefficient. The environmental test of developed collectors PSK-AV2-3, PSK-AV1-2, PSK-AV2-1, PSK-VS1-2, PSK-VS2-2, PSK-VS2-3, PSK-ST10-PW were conducted. The correlation of their results with laboratory tests when the thermohydraulic stand applied is shown. Relative accuracy of laboratory and environment tests was shown to be not exceeding 5 – 7%. The optical efficiency factor and the coefficient of thermal losses of polymeric solar collectors were determined. On the basis of the dependencies of the efficiency of the solar collectors vs. the reduced temperature, optimal designs of the polymeric solar collectors for the adsorption chilling solar systems are determined to be depended on the temperature of the regeneration temperature of the sorbents. As the temperatures of the regeneration of composite adsorbent ranged from 50ºС to 60ºС, appliance of the collectors PSK-AV2-1, PSK-CT10-PW occur to be expedient, and PSK-AB2-3, PSK-VS2-3, PSK-AB1-2, PSK-VS2-2, and PSK-VS1-2 are revealed to be more efficient when regeneration temperatures increased over 80 ºС. Thermotechnical characteristics of designed polymeric solar collectors are shown to surpass conventional metal and vacuum collectors. The perspectives of polymeric solar collectors in the design of adsorptive chilling solar plants were shown. Another way to improve the performance of adsorptive solar chillers concerns with equipping it with a photosensitive element and an electric drive, which will allow changing the angle of slope of the adsorber to the horizon depending on the intensity of the solar radiation. The chapter can be useful for design the efficient adsorptive chilling plants.

The chapter is devoted to design and performance of adsorptive heat pumps. In the first sub-division, state-of-the-art of the adsorptive heat pumping is analyzed. It involves analysing operating principle of adsorptive heat pumps, comparing of the properties of adsorbents used, bed specifications, and operating conditions. Original construction of the adsorptive heat pump is designed by authors for independent heat supply systems or hot water supply of buildings and other structures for various purposes. The composites ‘silica gel – sodium sulphate' or ‘silica gel – sodium acetate' were used as adsorbents. Discharging was performed in a daytime, when heat pump supplied heating system with water warmed to 45 – 35°C. The regeneration mode proceeded at night from 0.00 to 8.00 a.m. Efficiency of suggested adsorptive heat pump is estimated by two methods: as ratio of adsorption heat to sum of desorption heat and external heat supplied to sorbent during its heating up to regeneration temperature (coefficient of performance of cycle) and as ratio of heat of adsorption to heat supplied by solar collector (net coefficient of performance). Suggested heat pump coefficients of energy performance of cycle are stated to be 2.084 when composite ‘silica gel – sodium sulphate' used and 2.021 when ‘silica gel – sodium acetate' used. Seasonal dependence of net coefficient energy performance for suggested adsorptive heat pump based on composites ‘silica gel – sodium sulphate' and ‘silica gel – sodium acetate' is revealed. Correlation of coefficients of energy performance of adsorptive heat pump and composite sorbents properties (sorption capacity and regeneration temperature) is stated. Insignificant decreasing of coefficients of energy performance when ‘silica gel – sodium acetate' used is explained by lower sorptive capacity as compared to ‘silica gel – sodium sulphate'. Suggested heat pump application perspectives are shown for heat supply systems to result from traditional energy sources independence and environmental advantages. Adsorptive heat pumps development challenges, major limitations for commercialization of adsorptive heat pumping, and requirements to ongoing innovations are analysed. The present chapter can be useful for energy efficient decentralized heat supply systems based on adsorptive heat pump unit.


2019 ◽  
Vol 29 (3) ◽  
pp. 200-208 ◽  
Author(s):  
Elena A. Belyanovskaya ◽  
Grigoriy N. Pustovoy ◽  
Kostyntyn M. Sukhyy ◽  
Yana O. Sergiyenko ◽  
Oleksandr O. Yeromin ◽  
...  

Abstract The operation processes of adsorptive solar refrigerators based on composite adsorbents ‘silica gel - sodium sulphate’ were studied. The correlation between the adsorbent composition and the coefficient of the energy performance of the device was stated. As a consequence of the decreasing of adsorbent mass, the coefficient of performance is increased when sodium sulphate content in the composite increased. Effect of the regeneration process parameters on the composite on the coefficient of performance of the adsorptive refrigenerator was stated. The growth of the coefficient of performance is shown to result from decreasing the difference between adsorbent temperature and regeneration temperature from 85 to 55°C. The maximum values of the coefficient of performance of studied solar adsorptive refrigenerator about of 1.14 are stated for composites containing about 20 wt. % silica gel and 80 wt. % sodium sulphate.


The chapter is focused on technology of heat and moisture regeneration for ventilation systems. In the first sub-division recent progress in adsorptive technologies for air dehumidification, heating and conditioning is analyzed. In the next sub-divisions results of original researches of authors on adsorptive heat and moisture regeneration are given. The design of adsorptive heat-moisture regenerator for ventilation systems is shown. Its operation and the results of field tests are described. The technology of regeneration of low-potential heat and moisture by composite sorbent ‘silica gel – sodium sulphate' is suggested. Experimental plots of temperature, absolute and relative humidity at the inlet and the outlet of the apparatus and between cassettes with the composite are given. Correlation of flows switch-over time, airflow rate and temperature drop is stated. The relationships temperature efficiency factor vs. dimensionless temperature drop and moisture efficiency factor vs. absolute humidity dimensionless drop are derived with fair accuracy for engineering calculation. Ability of purposeful modification of the above-mentioned characteristics within broad ranges by changing the half-cycle time, the size of the granules of the adsorbent and its amount is revealed. The mathematical model and algorithm for determining the basic parameters of adsorptive regenerator operating processes are developed. The proposed algorithm involves calculating the volume of air passed through the layer of adsorptive heat-storage material, the concentration of water in the airflow at the outlet of the regenerator, the adsorption, the heat of adsorption, the final temperature of the cold air, the air temperature after mixing the cold air from the street and the warm air in the room at the warm end of the regenerator during inflow, calculation of the final concentration of water in the flow at the cold end of the regenerator, the volume of air passing through the layer of heat-accumulating material, adsorption and heat of adsorption, the final temperature of the air at the cold end of the regenerator, the air temperature after mixing of the cold air from the street and the warm air from the room at the cold end of regenerator during outflow, determining the temperature efficiency coefficient, summarized adsorption and maximal adsorption time. The correlation of air temperatures near the warm and cold end of the regenerator, as well as the temperature efficiency factors calculated according to the proposed algorithm and obtained by experimental way is confirmed. The mathematical modeling of the processes of operation of adsorption regenerators based on composites ‘silica gel – sodium sulphate' and ‘sodium acetate' in the conditions of the typical ventilation system of residential premises is carried out. The dependences of the temperature efficiency factor vs. the time of switching air flows and the velocity of air flow, as well as the temperatures of external and internal air under stationary conditions are shown. An optimal composition of composite adsorbents is stated to be 20% of silica gel and 80% of salt, that is, sodium sulphate or sodium acetate. Due to higher value of maximal adsorption composite ‘silica gel – Na2SO4' is shown to be required in half as much as compared with ‘silica gel – CH3COONa'. The results of the research can be used in the development of energy-efficient ventilation systems and devices for residential and warehouse premises.


2020 ◽  
Vol 12 (14) ◽  
pp. 5611
Author(s):  
Elena Belyanovskaya ◽  
Miroslav Rimár ◽  
Roman D. Lytovchenko ◽  
Miroslav Variny ◽  
Kostyantyn M. Sukhyy ◽  
...  

The performance of an adsorptive heat-moisture regenerator based on a silica gel–sodium sulphate composite adsorbent was studied. The correlation between the adsorbent composition and structural characteristics of the laboratory-scale device was investigated. An algorithm for the calculation of the efficiency factors of the adsorptive regenerator was further developed. The suggested algorithm calculates the operational parameters, including the temperatures, humidities and volumetric flows of internal and external air, and estimates the regenerator’s performance via temperature and moisture efficiency factors, total adsorption and time needed to achieve maximum adsorption, air pressure loss and fan power input. The validity of the calculation results obtained using the proposed algorithm was confirmed experimentally. Temperature efficiency factor, air pressure loss and fan power consumption are crucial parameters for the estimation of the optimal operating regime of an adsorptive heat-moisture regenerator. The correlation between meteorological conditions and efficiency factors was assessed and applied in a simulation of residential house-scale air conditioning unit operation. Maximal values of temperature efficiency factor were found at internal and external air temperatures of 15 to 20 °C and −5 to 0 °C, respectively. Moisture efficiency factors were observed to reach their maximum at the absolute humidities of external and internal air of 4.0 to 5.0 g/m3 and 2.75 to 3.0 g/m3, respectively. The fan power consumption of the adsorptive heat-moisture regenerator was found to be comparable to or even lower than that of commercial air conditioning units used in comparably voluminous interiors.


2019 ◽  
Vol 83 (1) ◽  
pp. 4-9 ◽  
Author(s):  
Elena Belyanovskaya ◽  
R. Lytovchenko ◽  
Konstanthyn Sukhyy ◽  
O. Prokopenko ◽  
O. Yeromin ◽  
...  

The criteria of adsorbent selection for adsorption transformers of thermal energy in ventilation systems are considered. The main characteristics of adsorbents that affected the structural parameters of the adsorption module are revealed. The method of determining the mass of the adsorbent and the volume of the adsorption unit in ventilation systems has been developed. The main factor affecting the volume of adsorbent is confirmed to be maximal adsorption. The advantages of ‘salt in the porous silica gel matrix’ composites are compared with traditional silica gels. On the example of an adsorption regenerator of low-potential heat and moisture, the greater effectiveness of the composites "silica gel-sodium sulphate" is shown in comparison with the composite 'silica gel - sodium acetate'. According to the experimental data on the operation of the adsorption regenerator of heat and moisture on the basis of the composite 'silica gel – CH3COONa', the adequacy of the proposed algorithm for determining the temperature efficiency factor has been confirmed. Suggested algorithm includes the calculation of the air volume passed through the layer of heat-storage material, water concentration in the air at the exit from the heat accumulator, adsorption, heat of adsorption, the final cold air temperature, air temperature after mixing cold air from the street and the warm air in the room at the inlet, the calculation of the concentration of water in the flow at the exit from the heat regenerator, the adsorption and heat of adsorption, the final temperature of the warm air, the air temperature after mixing the cold air from the street and the warm air from the room during the discharge, determination of the temperature efficiency factor, total adsorption and time to achieve the maximal adsorption. The efficiency of the processes of operating adsorption regenerators based on composites 'silica gel - sodium sulphate' and 'silica gel-sodium acetate' in the conditions of the typical ventilation system of housing premises was compared. The parameters that correspond to the maximum value of the temperature efficiency factors: the humid air velocity is about 0.22 - 0.32 m/s and the time of switching of the flows up to 5 minutes. The influence of meteorological conditions on the efficiency of the adsorption regenerator has been confirmed. The higher efficiency of adsorption regenerators based on 'silica gel - sodium sulphate' composites is explained, which is explained by higher values of maximal adsorption, which results in increasing the heat of adsorption. The results of the research can be used for the selection of adsorbents for energy-efficient heat energy converters in ventilation systems for residential and warehouse premises.


2019 ◽  
Vol 2 (83) ◽  
Author(s):  
Олена Анатоліївна Бєляновська ◽  
Григорій Миколайович Pustovoy ◽  
Михайло Порфирович Сухий ◽  
Костянтин Михайлович Сухий ◽  
Роман Дмитрович Литовченко

Abstract. Performance of adsorptive refrigerators based on composite adsorbents  ‘silica gel – sodium sulphate’ and ‘silica gel – sodium acetate’ was evaluated. The main characteristics of adsorbents which affect the structural parameters of the adsorptive chilling device are revealed. The method of determining operational characteristics of adsorptive refrigerator has been developed. The main factors affecting the mass of adsorbent are confirmed to be maximal adsorption and the amount of heat required to be taken from the cold box during the day. The advantages of ‘salt in the porous silica gel matrix’ composites are exhibited as compared with conventional silica gels and zeolites. Operational parameters of adsorptive refrigerators based on the composites ‘silica gel – sodium sulphate’ and 'silica gel – sodium acetate' are compared. The calculation procedure to determine the design and operational characteristics is suggested. Proposed procedure includes the calculation of the amount of heat required to be taken from the cold box during the day, water mass, mass of the adsorbent, heat required for regeneration of the adsorbent, computing the surface area of the solar collector, heat supplied by solar collector and net coefficient of performance. The efficiency of operating processes of adsorptive refrigerators based on composites 'silica gel - sodium sulphate' and 'silica gel-sodium acetate' was compared. The correlation between adsorbent composition and design and operational parameters was stated. The surface area of solar collector is stated to be of 9.46 – 9.93. The highest net coefficients of performance of 0.358 and 0.368 are revealed for devices based on composites containing, wt. %: silica gel – 20 and salt (sodium sulphate or sodium acetate) – 80. The influence of meteorological conditions on the net coefficient of performance of the adsorptive refrigerator has been confirmed. The higher efficiency of adsorptive chilling devices based on composites 'silica gel - sodium acetate' is explained by lower values of regeneration temperature, which leads to the decreasing the heat of regeneration. The results of the research can be used for the development of adsorptive chilling devices for domestic needs and warehouse premises.


Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 137
Author(s):  
Florian Schlosser ◽  
Heinrich Wiebe ◽  
Timothy G. Walmsley ◽  
Martin J. Atkins ◽  
Michael R. W. Walmsley ◽  
...  

Heat pumps are the key technology to decarbonise thermal processes by upgrading industrial surplus heat using renewable electricity. Existing insight-based integration methods refer to the idealised Grand Composite Curve requiring the full exploitation of heat recovery potential but leave the question of how to deal with technical or economic limitations unanswered. In this work, a novel Heat Pump Bridge Analysis (HPBA) is introduced for practically targeting technical and economic heat pump potential by applying Coefficient of Performance curves into the Modified Energy Transfer Diagram (METD). Removing cross-Pinch violations and operating heat exchangers at minimum approach temperatures by combined application of Bridge Analysis increases the heat recovery rate and reduce the temperature lift to be pumped at the same time. The insight-based METD allows the individual matching of heat surpluses and deficits of individual streams with the capabilities and performance of different market-available heat pump concepts. For an illustrative example, the presented modifications based on HPBA increase the economically viable share of the technical heat pump potential from 61% to 79%.


Energies ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 224
Author(s):  
Lucia Cattani ◽  
Anna Magrini ◽  
Paolo Cattani

Water extraction from air, based on reverse cycle systems, is becoming a technology more and more diffused and various models of air to water generators (AWG) are now available, all claiming the best efficiency. To date, there is not a standard indicator stating energy efficiency for AWGs, neither in the literature nor in technical practice. The only evaluation parameter, that can be found is a sort of specific energy consumption (SEC) without any clear indications about the involved calculation terms, definition of hypotheses, or environmental conditions. The current work is a first proposal of an indicator to standardise the AWG efficiency evaluation. The indicator is called WET (Water Energy Transformation); it states water production as a useful effect of an AWG machine and calculates its energy performance with an approach similar to COP (Coefficient of Performance) and EER (Energy Efficiency Ratio) evaluation. The indicator is meant to be a normalised tool that permits comparing different AWG machines, but it is also the first part of a wider study, currently under development that is oriented to obtain a global index formulation that combines WET itself, EER and COP, and it is intended for a comprehensive evaluation of all the useful effects of a reverse cycle in integrated machines, in compliance with the current efficiency evaluation approach. The current paper presents the WET equation, with a discussion about involved terms, a set of normalised calculation conditions and some application examples, including a comparison with SEC.


Energies ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 4360
Author(s):  
Umar Nawaz Bhatti ◽  
Salem Bashmal ◽  
Sikandar Khan ◽  
Rached Ben-Mansour

Thermoacoustic refrigerators have huge potential to replace conventional refrigeration systems as an alternative clean refrigeration technology. These devices utilize conversion of acoustic power and heat energy to generate the desired cooling. The stack plays a pivotal role in the performance of Standing Wave Thermoacoustic Refrigerators (SWTARs), as the heat transfer takes place across it. Performance of stacks can be significantly improved by making an arrangement of different materials inside the stack, resulting in anisotropic thermal properties along the length. In the present numerical study, the effect of multi-layered stack on the refrigeration performance of a SWTAR has been evaluated in terms of temperature drop across the stack, acoustic power consumed and device Coefficient of Performance (COP). Two different aspects of multi-layered stack, namely, different material combinations and different lengths of stacked layers, have been investigated. The combinations of four stack materials and length ratios have been investigated. The numerical results showed that multi-layered stacks produce lower refrigeration temperatures, consume less energy and have higher COP value than their homogeneous counterparts. Among all the material combinations of multi-layered stack investigated, stacks composed of a material layer with low thermal conductivity at the ends, i.e., RVC, produced the best performance with an increase of 26.14% in temperature drop value, reduction in the acoustic power consumption by 4.55% and COP enhancement of 5.12%. The results also showed that, for a constant overall length, an increase in length of side stacked material layer results in an increase in values of both temperature drop and COP.


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