Numerical Study on NO Mechanism during High Temperature Air Combustion of Natural Gas

2012 ◽  
Vol 190-191 ◽  
pp. 609-614
Author(s):  
Ya Xin Su ◽  
Cui Wu Chen

A full nitric oxide mechanism including thermal NO, prompt NO, N2O intermediate model and NO reduction model through reburning was used to calculate the NO formation during high temperature air combustion of natural gas in industrial furnace. The turbulent transportation was simulated by Reynolds stress model (RSM) and a modified Eddy-Break-Up (EBU) combustion model was applied to model the combustion process. A three-step reaction scheme of the natural gas combustion reaction was considered. Experimental data from published literature was adopted to validate the present models. Numerical results showed that thermal NO formation mechanism and reburning NO reduction mechanism were the dominant NO models. Reburning NO reduction could not be ignored. Prompt NO gave a small contribution to NO emission and the N2O intermediate model for NO formation was of little importance.

2008 ◽  
Author(s):  
Xing Li ◽  
Li Jia ◽  
Tiantian Zhang ◽  
Lixin Yang

In this paper, the combustion characteristics of natural gas with high-temperature air combustion technology in a U-type combustion chamber were investigated by the numerical method. The results of the CFD-based mathematical modeling of rated condition were compared with experimental data including the maximum temperature, average temperature and NO emission. The research indicates that the combustion can be well simulated using the suggested numerical model. The temperature distribution, velocity distribution in the combustion chamber and NO emission were attained. In addition, the effects of some parameters such as oxygen concentration, excessive air ratio and combustion air temperature were discussed in detail. It provided primarily theoretic basis for further study of natural gas high temperature air combustion.


2011 ◽  
Vol 354-355 ◽  
pp. 315-318
Author(s):  
Ya Xin Su ◽  
Wen Hui Wang

The high temperature air combustion performance of natural gas in an industrial furnace with a swirling burner was numerically modeled. A Beta function PDF (Probability Density Function) combustion model was selected to simulate the gas combustion combined with the Reynolds Stress Model (RSM) to simulate the turbulent flow. The radiation was simulated by a Discrete Ordinates method. The NO chemistry was simulated by thermal NO model. The simulation was performed at inlet air oxygen fraction 8% and the total air excess ratio 1.1 for natural gas. The effect of preheated air temperature on NO emission, temperature, O2 and CO distribution in the furnace was investigated. Results showed that thermal NO emission increased when the preheated air temperature increased from 1073 K to 1473K. When the preheated air temperature increased, both of the maximum and averaged temperature in the furnace increased. The oxygen was consumed by the formation of thermal NO at higher inlet air temperature and the fuel was not fully burnt out.


2021 ◽  
Vol 11 (4) ◽  
pp. 1441
Author(s):  
Farhad Salek ◽  
Meisam Babaie ◽  
Amin Shakeri ◽  
Seyed Vahid Hosseini ◽  
Timothy Bodisco ◽  
...  

This study aims to investigate the effect of the port injection of ammonia on performance, knock and NOx emission across a range of engine speeds in a gasoline/ethanol dual-fuel engine. An experimentally validated numerical model of a naturally aspirated spark-ignition (SI) engine was developed in AVL BOOST for the purpose of this investigation. The vibe two zone combustion model, which is widely used for the mathematical modeling of spark-ignition engines is employed for the numerical analysis of the combustion process. A significant reduction of ~50% in NOx emissions was observed across the engine speed range. However, the port injection of ammonia imposed some negative impacts on engine equivalent BSFC, CO and HC emissions, increasing these parameters by 3%, 30% and 21%, respectively, at the 10% ammonia injection ratio. Additionally, the minimum octane number of primary fuel required to prevent knock was reduced by up to 3.6% by adding ammonia between 5 and 10%. All in all, the injection of ammonia inside a bio-fueled engine could make it robust and produce less NOx, while having some undesirable effects on BSFC, CO and HC emissions.


Author(s):  
Orlando Ugarte ◽  
Suresh Menon ◽  
Wayne Rattigan ◽  
Paul Winstanley ◽  
Priyank Saxena ◽  
...  

Abstract In recent years, there is a growing interest in blending hydrogen with natural gas fuels to produce low carbon electricity. It is important to evaluate the safety of gas turbine packages under these conditions, such as late-light off and flameout scenarios. However, the assessment of the safety risks by performing experiments in full-scale exhaust ducts is a very expensive and, potentially, risky endeavor. Computational simulations using a high fidelity CFD model provide a cost-effective way of assessing the safety risk. In this study, a computational model is implemented to perform three dimensional, compressible and unsteady simulations of reacting flows in a gas turbine exhaust duct. Computational results were validated against data obtained at the simulated conditions in a representative geometry. Due to the enormous size of the geometry, special attention was given to the discretization of the computational domain and the combustion model. Results show that CFD model predicts main features of the pressure rise driven by the combustion process. The peak pressures obtained computationally and experimentally differed in 20%. This difference increased up to 45% by reducing the preheated inflow conditions. The effects of rig geometry and flow conditions on the accuracy of the CFD model are discussed.


Author(s):  
Usama J. Mizher ◽  
Peter A. Velmisov

Abstract. The search for new solutions in the field of energy, preventing negative impact on the environment, is one of the priority tasks for modern society. Natural gas occupies a stable position in the demand of the UES of Russia for fossil fuel. Biogas is a possible alternative fuel from organic waste. Biogas has an increased content of carbon dioxide, which affects the speed of flame propagation, and a lower content of methane, which reduces its heat of combustion. However, the combined combustion of natural gas and biogas, provided that the mixture of fuel and oxidizer is well mixed, can, on the one hand, reduce the maximum adiabatic temperature in the combustion chamber of power boilers at TPPs, and, on the other, increase the stability of biogas combustion. For the combined combustion of natural gas and biogas in operating power boilers, it is necessary to reconstruct the existing burners. For a high-quality reconstruction of burners capable of providing stable and low-toxic combustion of fuel, it is important to have theoretical data on the combustion effect of combustion of combinations of organic fuels on the temperature distribution in the combustion zone and on its maximum value. In this paper, self-similar solutions of the energy equation for axisymmetric motion of a liquid (gas) in a model of a viscous incompressible medium are obtained. Basing on them, a stationary temperature field in swirling jets is constructed. A set of programs based on the ANSYS Fluent software solver has been developed for modeling and researching of thermal and gas-dynamic processes in the combustion chamber. On the basis of the k - ϵ (realizable) turbulence model, the combustion process of a swirling fuel-air mixture is simulated. The results of an analytical and numerical study of the temperature and carbon dioxide distribution in the jet are presented.


Author(s):  
Long Liu ◽  
Xia Wen ◽  
Qian Xiong ◽  
Xiuzhen Ma

Abstract With energy shortages and increasing environmental problems, natural gas, as a clean energy, has the advantages of cheap price and large reserves and has become one of the main alternative fuels for marine diesel engines. For large bore natural gas engines, pre-chamber spark plug ignition can be used to increase engine efficiency. The engine mainly relies on the flame ejected from the pre-chamber to ignite the mixture of natural gas and air in the main combustion chamber. The ignition flame in the main combustion chamber is the main factor affecting the combustion process. Although the pre-chamber natural gas engines have been extensively studied, the characteristics of combustion in the pre-chamber and the development of ignition flame in the main combustion chamber have not been fully understood. In this study, a two-zone phenomenological combustion model of pre-chamber spark-ignition natural gas engines is established based on the exchange of mass and energy of the gas flow process in the pre-chamber and the main combustion chamber. The basic characteristics of the developed model are: a spherical flame surface is used to describe the combustion state in the pre-chamber, and according to the turbulent jet theory, the influence of turbulence on the state of the pilot flame is considered based on the Reynolds number. According to the phenomenological model, the time when the flame starts to be injected from the pre-chamber to the main combustion chamber, and the parameters such as the length of the pilot flame are analyzed. The model was verified by experimental data, and the results showed that the calculated values were in good agreement with the experimental values. It provides an effective tool for mastering the law of flame development and supporting the optimization of combustion efficiency.


2017 ◽  
Vol 21 (suppl. 3) ◽  
pp. 597-615 ◽  
Author(s):  
Srdjan Belosevic ◽  
Ivan Tomanovic ◽  
Nenad Crnomarkovic ◽  
Aleksandar Milicevic

A cost-effective reduction of NOx emission from utility boilers firing pulverized coal can be achieved by means of combustion modifications in the furnace. It is also essential to provide the pulverized coal diffusion flame control. Mathematical modeling is regularly used for analysis and optimization of complex turbulent reactive flows and mutually dependent processes in coal combustion furnaces. In the numerical study, predictions were performed by an in-house developed comprehensive three-dimensional differential model of flow, combustion and heat/mass transfer with submodel of the fuel- and thermal-NO formation/ destruction reactions. Influence of various operating conditions in the case-study utility boiler tangentially fired furnace, such as distribution of both the fuel and the combustion air over the burners and tiers, fuel-bound nitrogen content and grinding fineness of coal were investigated individually and in combination. Mechanisms of NO formation and depletion were found to be strongly affected by flow, temperature and gas mixture components concentration fields. Proper modifications of combustion process can provide more than 30% of the NOx emission abatement, approaching the corresponding emission limits, with simultaneous control of the flame geometry and position within the furnace. This kind of complex numerical experiments provides conditions for improvements of the power plant furnaces exploitation, with respect to high efficiency, operation flexibility and low emission.


2021 ◽  
Author(s):  
Orlando Ugarte ◽  
Suresh Menon ◽  
Wayne Rattigan ◽  
Paul Winstanley ◽  
Priyank Saxena ◽  
...  

Abstract In recent years, there is a growing interest in blending hydrogen with natural gas fuels to produce low carbon electricity. It is important to evaluate the safety of gas turbine packages under these conditions, such as late-light off and flameout scenarios. However, the assessment of the safety risks by performing experiments in full-scale exhaust ducts is a very expensive and, potentially, risky endeavor. Computational simulations using a high fidelity CFD model provide a cost-effective way of assessing the safety risk. In this study, a computational model is implemented to perform three dimensional, compressible and unsteady simulations of reacting flows in a gas turbine exhaust duct. Computational results were validated against data obtained at the simulated conditions in a representative geometry. Due to the enormous size of the geometry, special attention was given to the discretization of the computational domain and the combustion model. Results show that CFD model predicts main features of the pressure rise driven by the combustion process. The peak pressures obtained computationally and experimentally differed in 20%. This difference increased up to 45% by reducing the preheated inflow conditions. The effects of rig geometry and flow conditions on the accuracy of the CFD model are discussed.


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