Experimental Research of Decoloring Treatment on Vitamin B12 Wastewater

2013 ◽  
Vol 295-298 ◽  
pp. 1209-1214 ◽  
Author(s):  
Si Hang Shan ◽  
Peng Fei Fan ◽  
Yi Xing ◽  
Geng Qiao

Two kinds of vitamin B12 waste water from a pharmaceutical factory were treated separately by methods of combining micro-electrolysis with physiochemical and O3 oxidation. Effects of the reaction conditions on the removal rate of color were investigated. Results showed that the color removal rate of vitamin B12 waste water, which was treated by combined micro-electrolysis and physiochemical treatment reached 71.25%, while the color removal rate of the other waste water which treated by O3 oxidation reached 68.80%. The decolorizing treatment of those different natures of vitamin B12 waste water effectively provides a useful reference for this kind of waste water.

2013 ◽  
Vol 807-809 ◽  
pp. 1362-1367
Author(s):  
Li Li ◽  
Ying Liu ◽  
Yi Fan Li

This study mostly investigated the influences of electrolytic conditions and the structure of electrospinning nanofibers electrodes on the degradation of methylene blue in details. For PAN and Fe/PAN electrodes, was prepared by electrospinning.It was found that the ESF electrodes with higher specific surface area, and higher mesopore percentage could be push the electrochemical degradation. As the same time, adjusted the initial pH, increased the current, and added to electrolyte also could improve the treatment effect of electrochemical degradation. After 90min of electrolysis, the color removal efficiency of methylene blue reached 97.6% at current with 100mA, supporting electrolyte of NaCl with 0.1mol/L and initial pH with 3~5. Under the same current conditions with the Pt-Fe/PAN anodes the color removal rate of degradation were higher efficiency than the other two anodes.


1992 ◽  
Vol 15 (7) ◽  
pp. 408-412 ◽  
Author(s):  
B.K. Krämer ◽  
A. Pickert ◽  
C. Hohmann ◽  
H.M. Liebich ◽  
G.A. Müller ◽  
...  

The handling of low, middle and high molecular weight markers was examined in seven stable dialysis patients during hemofiltration with different membranes. Four membranes were examined in a randomized, crossover order (polysulfone, polyamide, AN69 polyacrylonitrile, Asahi polyacrylonitrile) by measuring plasma and dialysate concentrations of phosphate, creatinine, vitamin B12, β2-microglobulin, furanic acid, hippuric acid, retinolbinding protein, alpha-1-antitrypsin, and albumin. Sieving coefficients and plasma clearances of β-microglobulin or retinol-binding protein were markedly or slightly lower during hemofiltration with the Asahi polyacrylonitrile membrane than with the other membranes (highest removal with polysulfone/AN69 polyacrylonitrile membranes). No differences of obvious clinical relevance could be seen between the four membranes. A high β2-microglobulin removal rate might be important to prevent dialysis-associated amyloidosis.


2015 ◽  
Vol 713-715 ◽  
pp. 2703-2705
Author(s):  
Ying Gang Wang ◽  
Lin Lin ◽  
Teng Fei Liu ◽  
Jin Meng Zhang

Experimental research on the treatment of printing and dyeing wastewater has been carried out. The method of ultrasonic combined Fenton has been used.Separately by using ultrasonic and Fenton oxidation method to treat printing and dyeing wastewater, the hydrogen peroxide dosage, FeSO4•7H2O dosage, shaking time, pH value, ultrasonic time, ultrasonic power and other factors are investigated.The COD and chromaticity removal effect of printing and dyeing wastewater are calculated. The experimental results show that the above factors have a certain impact on the treatment effect. Based on these results, the orthogonal test method is used in this experiment, the optimal conditions of ultrasound combined with Fenton reagent for dealing printing and dyeing wastewater has been determined.The orthogonal experimental results show that the optimal reaction conditions of orthogonal test are below:pH value is 3, the best time for the experiment is 1.5h, hydrogen peroxide dosage is 5mL, seven water ferrous sulfate dosage is 0.7grams, ultrasonic power is 142.5W. Experiments are conducted in accordance with the best reaction conditions. On the optimal process conditions, the removal rate of COD reaches 94.6% and the chroma removal rate reaches 87.5%. The effect of using ultrasonic combined with Fenton reagent to treat printing and dyeing wastewater is better than the use of single method.


2018 ◽  
Vol 120 (1) ◽  
pp. 49-56 ◽  
Author(s):  
Eva Greibe ◽  
Linda S. Kornerup ◽  
Christian B. Juul ◽  
Sergey N. Fedosov ◽  
Christian W. Heegaard ◽  
...  

AbstractRecent rat studies show different tissue distributions of vitamin B12 (B12), administered orally as hydroxo-B12 (HO-B12) (predominant in food) and cyano-B12 (CN-B12) (common in supplements). Here we examine male Wistar rats kept on a low-B12 diet for 4 weeks followed by a 2-week period on diets with HO-B12 (n 9) or CN-B12 (n 9), or maintained on a low-B12 diet (n 9). Plasma B12 was analysed before, during and after the study. The content of B12 and its variants (HO-B12, glutathionyl-B12, CN-B12, 5'-deoxyadenosyl-B12 (ADO-B12), and methyl-B12 (CH3-B12)) were assessed in the tissues at the end of the study. A period of 4 weeks on the low-B12 diet reduced plasma B12 by 58 % (from median 1323 (range 602–1791) to 562 (range 267–865) pmol/l, n 27). After 2 weeks on a high-B12 diet (week 6 v. week 4), plasma B12 increased by 68 % (HO-B12) and 131 % (CN-B12). Total B12 in the tissues accumulated differently: HO-B12>CN-B12 (liver, spleen), HO-B12<CN-B12 (kidneys), and HO-B12≈CN-B12 (brain, heart). Notably, more than half of the administered CN-B12 remained in this form in the kidneys, whereas HO-B12 was largely converted to the bioactive ADO-B12. Only <10 % of the other cofactor, CH3-B12, were found in the tissues. In conclusion, dietary CN-B12 caused a higher increase in plasma and total kidney B12 but provided less than half of the active coenzymes in comparison to dietary HO-B12. These data argue that HO-B12 may provide a better tissue supply of B12 than CN-B12, thereby underscoring the lack of a direct relation between plasma B12 and tissue B12.


1952 ◽  
Vol 30 (5) ◽  
pp. 521-524 ◽  
Author(s):  
Margaret O. Burton ◽  
A. G. Lochhead

A study was made of the capacity for synthesis of vitamin B12 by 70 strains representing six species of Rhizobium, namely, R. meliloti, R. trifolii, R. leguminosarum, R. japonicum, R. lupini, and R. phaseoli. Rhizobium meliloti was sharply distinguished from the other species by its ability to produce significantly higher quantities of the vitamin, one strain producing, under the experimental conditions, over 1000 mμgm. per ml. of culture liquid. The remaining species did not show significant differences in B12 synthesizing capacity. No correlation was noted between vitamin-producing capacity and effectiveness of the individual strains with respect to nitrogen fixation.


2020 ◽  
Vol 24 ◽  
Author(s):  
Bubun Banerjee ◽  
Gurpreet Kaur ◽  
Navdeep Kaur

: Metal-free organocatalysts are becoming an important tool for the sustainable developments of various bioactive heterocycles. On the other hand, during last two decades, calix[n]arenes have been gaining considerable attention due to their wide range of applicability in the field of supramolecular chemistry. Recently, sulfonic acid functionalized calix[n] arenes are being employed as an efficient alternative catalyst for the synthesis of various bioactive scaffolds. In this review we have summarized the catalytic efficiency of p-sulfonic acid calix[n]arenes for the synthesis of diverse biologically promising scaffolds under various reaction conditions. There is no such review available in the literature showing the catalytic applicability of p-sulfonic acid calix[n]arenes. Therefore, we strongly believe that this review will surely attract those researchers who are interested about this fascinating organocatalyst.


2021 ◽  
Vol 19 (1) ◽  
pp. 806-817
Author(s):  
Muhammad Cholid Djunaidi ◽  
Nabilah Anindita Febriola ◽  
Abdul Haris

Abstract High levels of urea and creatinine in the blood are a sign of decreased kidney function. To remove these substances from the blood, hemodialysis which utilizes membranes could be used. In this study, a molecularly imprinted membrane (MIM) was synthesized for the selective transport of urea. The synthesis is initiated with the polymerization of eugenol into polyeugenol and then into polyeugenoxy acetate (PA). The PA is then contacted with urea and then used as the functional polymer in the synthesis of MIM with polysulfone as the membrane base, and polyethylene glycol as the cross-linking agent. The result was later analyzed with FTIR and SEM-EDX. The membrane is then used in the transport of urea, creatinine, and vitamin B12 and then compared with the non-imprinted membrane (NIM) performance. By using UV-Vis spectrophotometry, the results showed that the membrane with 10 h heating variation is able to transport more urea and is more selective than NIM; this proves that the urea template on the MIM enables it to recognize urea molecules better than creatinine and vitamin B12. The order of transport from the best results is urea > creatinine > vitamin B12.


1954 ◽  
Vol 9 (8) ◽  
pp. 509-513 ◽  
Author(s):  
G. Boehm ◽  
A. Faessler ◽  
G. Rittmayer
Keyword(s):  

Mit einem fokussierenden Spektrographen großer Dispersion wird die Lage der K-Röntgen-absorptionskante des Kobalts in verschiedenen Verbindungen untersucht. Die Ergebnisse zeigen, daß es möglich ist, durch Bestimmung der Kantenlage die Wertigkeit des Kobalts in einer Verbindung zu bestimmen. Die Methode gestattet den eindeutigen Nachweis, daß das Kobalt im Vitamin B12 dreiwertig ist.


2005 ◽  
Vol 28 (10) ◽  
pp. 1018-1024 ◽  
Author(s):  
G. Giannini ◽  
M. Valbonesi ◽  
F. Morelli ◽  
P. Carlier ◽  
M.C. De Luigi ◽  
...  

Patients with extremely high triglyceride levels and associated lipemia are at high risk for acute pancreatitis. Two factors can increase triglyceride-rich lipoproteins; one is overproduction and other is a defect in clearance. Either mechanism can cause hypertriglyceridemia and both may exist simultaneously. Causes can be either primary or secondary. Plasmapheresis is efficacious for severe hypertryceridemia in patients who have not responded to previous therapies. We have treated 15 cases of hypertrygliceridemia complicating the course of patients receiving Cyclosporin A after bone marrow transplantation. Five patients were treated with plasmapheresis, the other ten with cascade filtration. The removal rate for triglycerides was 58.0% for patients treated by cascade filtration and 63.5% for patients treated by plasmapheresis. The removal rates for triglycerides were low possibly as a consequence of early saturation of the filter.


2012 ◽  
Vol 627 ◽  
pp. 378-381
Author(s):  
Bi Rong Wang

Fenton pretreatment has been used for treating dye wastewater. The effects of the dos of H2O2 and FeSO4, reaction time and pH on the removal COD were investigated. It was found that, when the reaction conditions are as follows: COD 2850 mg/L dyeing wastewater, the dosage of H2O2 is 140mmol/L, FeSO4 17.02 mmol/L, pH 7.6, and reaction time 1.0 h, the CODcr of dye wastewater removal rate of up to 70%. Fenton pretreatment process of dye wastewater has a broad prospect.


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